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    HYDRODESULFURIZATION CATALYST FOR HYDROCARBON OIL, PRODUCTION METHOD FOR SAME, AND HYDROREFINING METHOD FOR HYDROCARBON OIL
    1.
    发明公开
    HYDRODESULFURIZATION CATALYST FOR HYDROCARBON OIL, PRODUCTION METHOD FOR SAME, AND HYDROREFINING METHOD FOR HYDROCARBON OIL 审中-公开
    加氢脱硫催化剂的烃油，加工为油气石油生产国和HYDRO精炼过程

    公开(公告)号：EP2586529A1

    公开(公告)日：2013-05-01

    申请号：EP11798112.6

    申请日：2011-06-21

    申请人： JX Nippon Oil & Energy Corporation ,  JGC Catalysts And Chemicals Ltd.

    发明人： SEKI, Hiroyuki ,  YOSHIDA, Masanori ,  TAGAWA, Shogo ,  KAGAWA, Tomoyasu

    IPC分类号： B01J27/051 ,  B01J37/02 ,  B01J37/04 ,  B01J37/08 ,  B01J37/20 ,  C10G45/08

    CPC分类号： B01J27/051 ,  B01J21/063 ,  B01J21/12 ,  B01J23/882 ,  B01J27/19 ,  B01J35/0013 ,  B01J37/0045 ,  B01J37/0203 ,  B01J37/20 ,  C10G45/08 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/4018

    摘要： The present invention provides a hydrodesulfurization catalyst exhibiting a high desulfurization activity when used for hydrotreating a hydrocarbon oil, particularly straight-run gas oil. The hydrodesulfurization catalyst is a catalyst produced by pre-sulfurizing a hydrodesulfurization catalyst Y comprising a support containing silica, alumina and titania and at least one type of metal component supported thereon and selected from VIA and VIII groups of the periodic table (comprising at least Mo), in which the total area of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes in the support, measured by X-ray diffraction analysis being 1/4 or less of the alumina diffraction peak area assigned to γ-alumina (400) planes, the molybdenum is formed into molybdenum disulfide crystal and disposed in layers on the support by the pre-sulfurization, and the molybdenum disulfide crystal layers having an average length of longer than 3.5 nm and 7 nm or shorter in the plane direction and an average number of laminated layers of more than 1.0 and 1.9 or fewer.

    摘要翻译： 本发明提供了一种加氢脱硫催化剂具有高的脱硫活性当用于加氢处理烃油，特别是直馏瓦斯油。 加氢脱硫催化剂通过硫化预加氢脱硫催化剂Y包含载体包含二氧化硅，氧化铝和二氧化钛和至少一种类型的在其上的金属组分的载体的和从VIA选择和VIII组周期表的制备的催化剂（至少含有Mo ），其中，所述衍射峰面积的指示锐钛矿二氧化钛（101）面的晶体结构和衍射峰面积指示金红石二氧化钛（110）面的在载体上的晶体结构，通过X射线衍射分析测得的总面积 为1/4或更小分配给³氧化铝氧化铝衍射峰面积（400）晶面，所述钼形成为二硫化钼晶体和在层布置在由预硫化的支撑，并且具有二硫化钼晶体层 上在平面方向上和在平均数目大于1.0和1.9或叠层的长于3.5 nm和7纳米或更短的平均长度 少。

    HYDRODESULFURIZATION CATALYST FOR A HYDROCARBON OIL, MANUFACTURING METHOD THEREFOR, AND HYDROREFINING METHOD
    3.
    发明公开
    HYDRODESULFURIZATION CATALYST FOR A HYDROCARBON OIL, MANUFACTURING METHOD THEREFOR, AND HYDROREFINING METHOD 审中-公开
    HYDROENTSCHWEFELUNGSKATALYSATORFÜRKOHLENWASSERSTOFFÖL，HERSTELLUNGSVERFAHRENDAFÜRUND HYDRORAFFINATIONSVERFAHREN

    公开(公告)号：EP2484745A1

    公开(公告)日：2012-08-08

    申请号：EP10820343.1

    申请日：2010-09-14

    申请人： JX Nippon Oil & Energy Corporation ,  JGC Catalysts And Chemicals Ltd.

    发明人： SEKI, Hiroyuki ,  FUKUI, Yoshiaki ,  YOSHIDA, Masanori ,  TAGAWA, Shogo ,  KAGAWA, Tomoyasu

    IPC分类号： C10G45/04 ,  B01J21/06 ,  B01J27/19

    CPC分类号： B01J21/063 ,  B01J21/08 ,  B01J21/12 ,  B01J23/24 ,  B01J23/74 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/28 ,  C10G45/04 ,  C10G45/06 ,  C10G45/08 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/70

    摘要： The present invention provides a hydrodesulfurization catalyst that exhibits a high desulfurization activity when used in hydrotreatment of hydrocarbon oil, in particular straight-run gas oil. The catalyst comprising at least one type of metal component selected from Groups VIA and VIII in the periodic table, supported on a silica-titania-alumina support where the total of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes is 1/4 or less of the diffraction peak area indicating the aluminum crystal structure ascribed to y-alumina (400) planes, as measured by X-ray diffraction analysis, the catalyst having (a) a specific surface area (SA) of 150 m 2 /g or greater, (b) a total pore volume (PVo) of 0.30 ml/g or greater, (c) an average pore diameter (PD) of 6 to 15 nm (60 to 150 Å), and (d) the ratio of the pore volume (PVp) of pores having diameters within ±30 percent of the average pore diameter (PD) being 70 percent or greater of the total pore volume (PVo).

    摘要翻译： 本发明提供一种加氢脱硫催化剂，其在用于烃油，特别是直馏瓦斯油的加氢处理中表现出高的脱硫活性。 催化剂包含至少一种选自元素周期表VIA和VIII族的金属组分，负载在二氧化硅 - 二氧化钛 - 氧化铝载体上，其中表示锐钛型二氧化钛（101）晶体的晶体结构的衍射峰面积的总和为 表示金红石型二氧化钛（110）面的晶体结构的衍射峰面积，通过X射线衍射分析测定，表示归属于γ-氧化铝（400）面的铝结晶结构的衍射峰面积的1/4以下， （a）比表面积（SA）为150m 2 / g以上，（b）总孔容积（PVo）为0.30ml / g以上的催化剂，（c）平均孔径（PD） 6〜15nm（60〜150）的孔体积（PVp）为70nm以上，（d）直径在平均孔径（PD）的±30％以内的孔的孔体积（PVp） 体积（PVo）。

    HYDROREFINING CATALYST, METHOD FOR PRODUCING SAME, AND PROCESS FOR HYDROREFINING HYDROCARBON OIL
    5.
    发明公开
    HYDROREFINING CATALYST, METHOD FOR PRODUCING SAME, AND PROCESS FOR HYDROREFINING HYDROCARBON OIL 有权
    HYDRO精制催化剂，方法的水电油气精制石油生产和方法

    公开(公告)号：EP2412438A1

    公开(公告)日：2012-02-01

    申请号：EP10755626.8

    申请日：2010-03-18

    申请人： JX Nippon Oil & Energy Corporation

    发明人： SEKI, Hiroyuki ,  FUKUI, Yoshiaki ,  YOSHIDA, Masanori

    IPC分类号： B01J23/88 ,  B01J27/051 ,  B01J37/20 ,  C10G45/06

    CPC分类号： B01J23/883 ,  B01J21/12 ,  B01J23/882 ,  B01J27/18 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0203 ,  B01J37/031 ,  B01J37/20 ,  C10G45/08 ,  C10G2300/207

    摘要： A hydrotreating catalyst that exhibits excellent levels of both desulfurization activity and denitrification activity. The hydrotreating catalyst is prepared by supporting molybdenum, cobalt and nickel on a carrier comprising aluminum, silicon, phosphorus and boron, and then performing a presulfiding treatment, and has an average stacking number for molybdenum sulfide slab that is greater than 1.0 but not more than 1.9. Also, a process for producing a hydrotreating catalyst that enables a hydrotreating catalyst having excellent levels of both desulfurization activity and denitrification activity to be produced with comparative ease. The process includes a first step of mixing an acidic aluminum salt aqueous solution and a basic aluminum salt aqueous solution in the presence of phosphate ions and silicate ions to achieve a pH of 6.5 to 9.5, thereby obtaining a hydrate, a second step of adding boron to the hydrate to prepare a carrier-forming material, a third step of molding and calcining the carrier-forming material to obtain a carrier, a fourth step of supporting molybdenum, cobalt and nickel on the carrier to obtain a catalyst precursor, and a fifth step of performing a presulfiding treatment by bringing the catalyst precursor into contact with a mixed gas containing hydrogen and hydrogen sulfide under conditions including a pressure of not less than 2.0 MPa and a maximum temperature of 240 to 380°C.

    摘要翻译： 加氢处理催化剂都没有脱硫活性及脱氮活性的具有出色的水平。 加氢处理催化剂是通过钼，钴和镍在载体上的包含铝，硅，磷和硼，然后进行预硫化处理而制得，并具有平均层叠数硫化钼所做的是大于1.0但不超过 1.9。 因此，对于生产加氢处理催化剂做了方法能够同时具有脱硫活性和脱氮活性的优良水平，以比较容易地制造的加氢处理催化剂。 该方法包括酸性铝盐wässrige溶液和磷酸根离子和硅酸根离子的存在下，碱性铝盐wässrige溶液混合以达到pH为6.5至9.5，从而获得水合物，添加硼的第二步骤的第一步骤 到水合物以制备载体成型用材料，成型的第三步骤和煅烧该载体成型用材料，以获得一种载体，支撑钼，钴和镍在载体上获得的催化剂前体的第四步骤和第五 通过使催化剂前体接触于包含条件下氢气和硫化氢包含不小于2.0兆帕的压力和240的最高温度至380℃的混合气体进行预硫化处理的步骤