摘要:
A methacrylate resin composition containing a methacrylate resin and a phenoxy resin and a film consisting of the same, each having high transparency, small phase differences in a thickness direction, low heat shrinkage rate, high strength and good adhesion properties are provided. The methacrylate resin composition contains a methacrylate resin with a triad syndiotacticity (rr) of equal to or more than 58% and a phenoxy resin, and the content of the phenoxy resin per 100 parts by mass of the methacrylate resin is in a range of 0.1 to 8 parts by mass, and the total content of the methacrylate resin and phenoxy resin is 80 mass% or more.
摘要:
A methacrylic resin composition comprises not less than 90% by mass and not more than 100% by mass of a methacrylic resin [A] having: the total content of a structural unit derived from methyl methacrylate of not less than 90% by mass; a molecular weight M A of not less than 30000 and not more than 100000 in terms of polystyrene corresponding to the retention time indicating the value of the maximum strength in a chromatogram obtained by gel permeation chromatography; the area S gA of a region enclosed by an approximate curve obtained by fitting the data of a range indicating the strength of not less than 70% relative to the value of the maximum strength to a Gaussian function by the method of nonlinear least squares and the base line of the chromatogram of 45 to 80% of the area S A enclosed by the chromatogram and its base line; and the ratio Mw gA /Mn gA of a weight average molecular weight Mw gA to a number average molecular weight Mn gA of not less than 1.01 and not more than 1.20 in terms of polystyrene computed based on an approximate curve obtained by the above fitting.
摘要:
A copolymer comprising a structural unit (I) derived from a phosphonate monomer (1) such as diethyl methacryloyloxymethyl phosphonate, diethyl 2-methacryloyloxyethyl phosphonate and the like, and a structural unit (II) derived from a radical polymerizable monomer (2) such as methacrylic acid, acrylic acid, 8-tricyclo[5.2.1.0 2,6 ]decanyl methacrylate, t-butyl methacrylate and the like, wherein the content of phosphorus atoms from the phosphonate monomer (1) is 2.0 to 6.0 % by mass relative to the mass of the copolymer. A formed article comprising the copolymer.
摘要:
Provided are a break-resistant copolymer having high transparency and heat resistance and also having a high tensile strain at break, and a molded article. A copolymer contains 80% by mass to 98% by mass of structural units derived from a methacrylic ester monomer and 2% to 10% by mass of ester structural units derived from a cyclic ketene acetal monomer. The copolymer has a weight average molecular weight of 80, 000 or more and a molecular weight distribution of 1. 75 to 3.80.
摘要:
An acrylic resin film is obtained by a method comprising bulk-polymerizing methyl methacrylate and an alkyl acrylate ester to obtain an acrylic thermoplastic resin component comprising more than 99% by mass of a methyl methacrylate unit and not more than 1% by mass of an alkyl acrylate ester unit, extruding, through a T-die, a resin composition comprising 70 to 95% by mass of the acrylic thermoplastic resin component and 5 to 30% by mass of a crosslinked rubber particle component, and forming the resultant into a thickness of 20 to 300 µm with no bank.
摘要:
A gas barrier layered product and a method for producing the same are provided. The gas barrier layered product exhibits a high oxygen barrier property regardless of humidity, exhibits a high oxygen barrier property even after being subjected to retort processing, and is excellent in strength and transparency. In order to provide the gas barrier layered product, the gas barrier layered product includes a base material and a layer stacked on at least one surface of the base material. The layer is formed of a composition that includes: a hydrolyzed and condensed product of at least one compound (L) containing a metal atom to which at least one characteristic group selected from a halogen atom and an alkoxy group has been bonded; and a neutralized product of a polymer containing at least one functional group selected from a carboxyl group and a carboxylic anhydride group. At least a part of the ۥCOOۥ group contained in the at least one functional group has been neutralized with metal ions having a valence of two or more.
摘要:
A methacrylic resin composition comprises not less than 90% by mass and not more than 100% by mass of a methacrylic resin [A] having: the total content of a structural unit derived from methyl methacrylate of not less than 90% by mass; a molecular weight M A of not less than 30000 and not more than 100000 in terms of polystyrene corresponding to the retention time indicating the value of the maximum strength in a chromatogram obtained by gel permeation chromatography; the area S gA of a region enclosed by an approximate curve obtained by fitting the data of a range indicating the strength of not less than 70% relative to the value of the maximum strength to a Gaussian function by the method of nonlinear least squares and the base line of the chromatogram of 45 to 80% of the area S A enclosed by the chromatogram and its base line; and the ratio Mw gA /Mn gA of a weight average molecular weight Mw gA to a number average molecular weight Mn gA of not less than 1.01 and not more than 1.20 in terms of polystyrene computed based on an approximate curve obtained by the above fitting.
摘要:
A film is obtained by forming a methacrylic resin composition conmprising 100 parts by mass of a methacrylic resin (A) and preferably 1 to 10 parts by mass of a polycarbonate resin, the methacrylic resin (A) having a triad syndiotacticity (rr) of not less than 58%, a weight average molecular weight of 50000 to 150000, a content of fraction having a molecular weight of not less than 200000 of 0.1 to 10 % by mass and a content of fraction having a molecular weight of less than 15000 of 0.2 to 5 % by mass. A polarizer protective film comprising the above film is obtained.