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公开(公告)号:EP0584808A2
公开(公告)日:1994-03-02
申请号:EP93113584.2
申请日:1993-08-25
申请人: KURARAY CO., LTD.
CPC分类号: B65D35/10 , Y10T428/1341 , Y10T428/1345 , Y10T428/1383 , Y10T428/1397
摘要: A collapsible tube is obtained by heat bonding a head to a polyolefin sleeve, the head comprising a composition which comprises a polyolefin resin (A), a saponified product of ethylene-vinyl acetate copolymer (B) having a melting point of at least 135°C, and a saponified product ethylene-vinyl acetate copolymer (C) having a melting point of not more than 130°C.
摘要翻译: 通过将头部热熔粘合到聚烯烃套筒上获得可折叠的管,该头部包括一种组合物,该组合物包含聚烯烃树脂(A),熔点至少为135℃的乙烯 - 乙酸乙烯酯共聚物(B)的皂化产物 C和熔点不超过130℃的皂化产物乙烯 - 乙酸乙烯酯共聚物(C)
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公开(公告)号:EP0545312B1
公开(公告)日:1998-07-15
申请号:EP92120303.0
申请日:1992-11-27
申请人: KURARAY CO., LTD.
发明人: Negi, Taichi , Itamura, Sumio , Hirofuji, Satoshi
CPC分类号: B32B27/08 , B32B7/12 , B32B27/22 , B32B27/30 , B32B27/306 , B32B27/32 , B32B2307/736 , C08J5/18 , C08J2323/08 , C08J2329/04 , Y10S428/913 , Y10T428/1328 , Y10T428/1383 , Y10T428/31913 , Y10T428/31928 , Y10T428/31935
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公开(公告)号:EP0425820A3
公开(公告)日:1991-05-15
申请号:EP90118674.2
申请日:1990-09-28
申请人: KURARAY CO., LTD.
发明人: Itamura, Sumio , Moritani, Tohei
CPC分类号: B32B27/08 , B32B27/306 , B32B2307/7242 , B32B2331/04 , C08L23/08 , C08L23/26 , C08L29/04 , Y10T428/31928 , C08L2666/04
摘要: Provided are resin compositions comprising:
(A) 60 to 95% by weight of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol% and a saponification degree of the vinyl acetate component of at least 96%, (B) 4.5 to 39.5% by weight of an ethylene-vinyl acetate copolymer having an ethylene content of 60 to 98 mol%, and (C) at least 0.5% by weight of a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 68 to 98 mol% and a saponification degree of the vinyl acetate component of at least 20%, the incorporation ratio of (C) based on the sum of (B) and (C) being not more than 38% by weight. The resin compositions of the present invention have markedly improved flexibility without deteriorating transparency and gas barrier properties as compared with conventional saponified products of ethylene-vinyl acetate copolymers. Multilayered structures comprising at least one layer of the composition have excellent resistance to falling shock, flexural resistance, prevention of air-back, skin-pack adaptability and shrink-packaging capability and are hence of great value for packaging various goods.-
公开(公告)号:EP0584808B1
公开(公告)日:1996-11-06
申请号:EP93113584.2
申请日:1993-08-25
申请人: KURARAY CO., LTD.
CPC分类号: B65D35/10 , Y10T428/1341 , Y10T428/1345 , Y10T428/1383 , Y10T428/1397
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公开(公告)号:EP0425820A2
公开(公告)日:1991-05-08
申请号:EP90118674.2
申请日:1990-09-28
申请人: KURARAY CO., LTD.
发明人: Itamura, Sumio , Moritani, Tohei
CPC分类号: B32B27/08 , B32B27/306 , B32B2307/7242 , B32B2331/04 , C08L23/08 , C08L23/26 , C08L29/04 , Y10T428/31928 , C08L2666/04
摘要: Provided are resin compositions comprising:
(A) 60 to 95% by weight of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol% and a saponification degree of the vinyl acetate component of at least 96%,
(B) 4.5 to 39.5% by weight of an ethylene-vinyl acetate copolymer having an ethylene content of 60 to 98 mol%, and
(C) at least 0.5% by weight of a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 68 to 98 mol% and a saponification degree of the vinyl acetate component of at least 20%,
the incorporation ratio of (C) based on the sum of (B) and (C) being not more than 38% by weight.
The resin compositions of the present invention have markedly improved flexibility without deteriorating transparency and gas barrier properties as compared with conventional saponified products of ethylene-vinyl acetate copolymers. Multilayered structures comprising at least one layer of the composition have excellent resistance to falling shock, flexural resistance, prevention of air-back, skin-pack adaptability and shrink-packaging capability and are hence of great value for packaging various goods.摘要翻译: 本发明提供的树脂组合物包含:(A)60〜95重量%的乙烯含量为20〜65摩尔%,乙酸乙烯酯成分皂化度为96%以上的乙烯 - 乙酸乙烯酯共聚物,(B) 4.5至39.5重量%的乙烯含量为60至98摩尔%的乙烯 - 乙酸乙烯酯共聚物,和(C)至少0.5重量%的乙烯 - 乙酸乙烯酯共聚物的皂化产物,其乙烯含量为 68〜98摩尔%,乙酸乙烯酯组分的皂化度为20重量%以上,(C)相对于(B)和(C)之和的合并比例不超过38重量%。 与乙烯 - 乙酸乙烯酯共聚物的常规皂化产物相比,本发明的树脂组合物具有显着改善的柔性,而不会劣化透明性和阻气性。 包含至少一层该组合物的多层结构物具有优异的耐跌落冲击性,抗弯曲性,防止空气回流,皮肤包装适应性和收缩包装能力,因此对于包装各种商品具有重要价值。
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公开(公告)号:EP0400604A2
公开(公告)日:1990-12-05
申请号:EP90110262.4
申请日:1990-05-30
申请人: KURARAY CO., LTD.
发明人: Itamura, Sumio , Moritani, Tohei , Sato, Toshiaki , Negi, Taichi
CPC分类号: B32B27/08 , B32B27/302 , B32B27/304 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2307/7242 , B32B2325/00 , B32B2327/06 , B32B2367/00 , B32B2377/00 , C08L23/02 , C08L23/08 , C08L23/26 , C08L25/06 , C08L27/06 , C08L29/04 , C08L67/00 , C08L77/00 , C08L101/00 , C08L2205/02 , Y10T428/3175 , Y10T428/31797 , Y10T428/31917 , Y10T428/3192 , Y10T428/31928 , Y10T428/31931 , Y10T428/31935 , C08L2666/02 , C08L2666/04
摘要: Provided are multilayered structures comprising at least 2 layers of a layer which comprises a resin composition comprising:
(A) a thermoplastic resin,
(B) a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol% and a saponification degree of vinyl acetate component of at least 96%, and
(C) a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 68 to 98 mol% and a saponification degree of vinyl acetate component of at least 20%, and
a layer which comprises a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol% and a saponification degree of vinyl acetate component of at least 96%.
These multilayered structures have excellent gas barrier properties and resistance to intralayer delamination, and the resin composition layer thereof has neat appearance.摘要翻译: 提供包括至少2层的包含树脂组合物的层的多层结构,所述树脂组合物包含:(A)热塑性树脂,(B)乙烯含量为20至65摩尔%的乙烯 - 乙酸乙烯酯共聚物的皂化产物和 乙酸乙烯酯成分皂化度为96%以上,(C)乙烯含量为68〜98摩尔%,乙酸乙烯酯成分皂化度为20重量%以上的乙烯 - 乙酸乙烯酯共聚物的皂化物, 以及包含乙烯含量为20〜65摩尔%,乙酸乙烯酯成分皂化度为96%以上的乙烯 - 乙酸乙烯酯共聚物的皂化物的层。 这些多层结构具有优异的阻气性和层内分层性,其树脂组合物层具有整洁的外观。
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公开(公告)号:EP0401666B1
公开(公告)日:1995-02-22
申请号:EP90110260.8
申请日:1990-05-30
申请人: KURARAY CO., LTD.
发明人: Itamura, Sumio , Moritani, Tohei , Sato, Toshiaki , Negi, Taichi
CPC分类号: C08K5/098 , C08K3/013 , C08K3/22 , C08K3/26 , C08K3/34 , C08K3/36 , C08L23/02 , C08L23/06 , C08L23/08 , C08L23/0861 , C08L23/10 , C08L23/26 , C08L29/04 , C08L51/06 , C08L2205/035 , C08L2205/08 , C08L2207/066 , C08L2666/04 , C08L2666/24
摘要: Provided are resin compositions comprising the following (A), (B), (C), which is at least one member selected from (C1) through (C3), and (D) : (A): a polyolefin, (B): a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol% and a saponification degree of vinyl acetate component of at least 96%, (C): (C1): at least one inorganic substance selected from titanium oxide, talc, calcium carbonate, mica and absorptive inorganic materials, (C2): at least one compound selected from the group consisting of metal salts of higher fatty acid having 8 to 22 carbon atoms, metal salts of ethylenediaminetetraacetic acid and hydrotalcite, and (C3): a polyolefin modified with an unsaturated carboxylic acid or derivatives thereof; and, (D): a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 68 to 98 mol% and a saponification degree of vinyl acetate component of at least 20%. The compositions of the present invention have excellent compatibility within themselves and significantly solve the problems, upon molding, of molding instability such as charred resin on screw, generation of lip stain, pressure increase in extruder, abnormal flow and generation of (turbulence) wavy pattern on the surface of molded articles.
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公开(公告)号:EP0400604A3
公开(公告)日:1991-05-22
申请号:EP90110262.4
申请日:1990-05-30
申请人: KURARAY CO., LTD.
发明人: Itamura, Sumio , Moritani, Tohei , Sato, Toshiaki , Negi, Taichi
CPC分类号: B32B27/08 , B32B27/302 , B32B27/304 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2307/7242 , B32B2325/00 , B32B2327/06 , B32B2367/00 , B32B2377/00 , C08L23/02 , C08L23/08 , C08L23/26 , C08L25/06 , C08L27/06 , C08L29/04 , C08L67/00 , C08L77/00 , C08L101/00 , C08L2205/02 , Y10T428/3175 , Y10T428/31797 , Y10T428/31917 , Y10T428/3192 , Y10T428/31928 , Y10T428/31931 , Y10T428/31935 , C08L2666/02 , C08L2666/04
摘要: Provided are multilayered structures comprising at least 2 layers of a layer which comprises a resin composition comprising:
(A) a thermoplastic resin, (B) a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol% and a saponification degree of vinyl acetate component of at least 96%, and (C) a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 68 to 98 mol% and a saponification degree of vinyl acetate component of at least 20%, and a layer which comprises a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol% and a saponification degree of vinyl acetate component of at least 96%. These multilayered structures have excellent gas barrier properties and resistance to intralayer delamination, and the resin composition layer thereof has neat appearance.-
公开(公告)号:EP0401666A3
公开(公告)日:1991-05-02
申请号:EP90110260.8
申请日:1990-05-30
申请人: KURARAY CO., LTD.
发明人: Itamura, Sumio , Moritani, Tohei , Sato, Toshiaki , Negi, Taichi
CPC分类号: C08K5/098 , C08K3/013 , C08K3/22 , C08K3/26 , C08K3/34 , C08K3/36 , C08L23/02 , C08L23/06 , C08L23/08 , C08L23/0861 , C08L23/10 , C08L23/26 , C08L29/04 , C08L51/06 , C08L2205/035 , C08L2205/08 , C08L2207/066 , C08L2666/04 , C08L2666/24
摘要: Provided are resin compositions comprising the following (A), (B), (C), which is at least one member selected from (C₁) through (C₃), and (D) :
(A): a polyolefin,
(B): a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol% and a saponification degree of vinyl acetate component of at least 96%,
(C): (C₁): at least one inorganic substance selected from titanium oxide, talc, calcium carbonate, mica and absorptive inorganic materials,
(C₂): at least one compound selected from the group consisting of metal salts of higher fatty acid having 8 to 22 carbon atoms, metal salts of ethylenediaminetetraacetic acid and hydrotalcite, and
(C₃): a polyolefin modified with an unsaturated carboxylic acid or derivatives thereof;
and,
(D): a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 68 to 98 mol% and a saponification degree of vinyl acetate component of at least 20%. The compositions of the present invention have excellent compatibility within themselves and significantly solve the problems, upon molding, of molding instability such as charred resin on screw, generation of lip stain, pressure increase in extruder, abnormal flow and generation of (turbulence) wavy pattern on the surface of molded articles.摘要翻译: (A),(B),(C)是选自(C 1)至(C 3)中的至少一种,和(D):(A):聚烯烃,(B) :乙烯含量为20〜65摩尔%,乙酸乙烯酯成分的皂化度为96%以上的乙烯 - 乙酸乙烯酯共聚物的皂化物,(C):( C 1):选自 氧化钛,滑石,碳酸钙,云母和吸收性无机材料,(C 2):选自具有8-22个碳原子的高级脂肪酸的金属盐,乙二胺四乙酸的金属盐和水滑石组成的组中的至少一种化合物,和 (C 3):用不饱和羧酸或其衍生物改性的聚烯烃; (D):乙烯含量为68〜98摩尔%,乙酸乙烯酯成分的皂化度为20%以上的乙烯 - 乙酸乙烯酯共聚物的皂化物。 本发明的组合物本身具有优异的相容性,并且显着地解决了模塑时成型不稳定性,如螺杆上烧焦的树脂,唇污染的产生,挤出机中的压力增加,异常流动和(湍流)波状图案的产生 在模塑制品的表面上。
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公开(公告)号:EP0400604B1
公开(公告)日:1996-01-24
申请号:EP90110262.4
申请日:1990-05-30
申请人: KURARAY CO., LTD.
发明人: Itamura, Sumio , Moritani, Tohei , Sato, Toshiaki , Negi, Taichi
IPC分类号: B32B27/00
CPC分类号: B32B27/08 , B32B27/302 , B32B27/304 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2307/7242 , B32B2325/00 , B32B2327/06 , B32B2367/00 , B32B2377/00 , C08L23/02 , C08L23/08 , C08L23/26 , C08L25/06 , C08L27/06 , C08L29/04 , C08L67/00 , C08L77/00 , C08L101/00 , C08L2205/02 , Y10T428/3175 , Y10T428/31797 , Y10T428/31917 , Y10T428/3192 , Y10T428/31928 , Y10T428/31931 , Y10T428/31935 , C08L2666/02 , C08L2666/04
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