Resin composition and multilayered structure
    1.
    发明公开
    Resin composition and multilayered structure 失效
    Kunststofformmasse und Mehrschichtstrukturen。

    公开(公告)号:EP0425820A2

    公开(公告)日:1991-05-08

    申请号:EP90118674.2

    申请日:1990-09-28

    申请人: KURARAY CO., LTD.

    IPC分类号: C08L29/04 B32B27/32

    摘要: Provided are resin compositions comprising:

    (A) 60 to 95% by weight of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol% and a saponification degree of the vinyl acetate component of at least 96%,
    (B) 4.5 to 39.5% by weight of an ethylene-vinyl acetate copolymer having an ethylene content of 60 to 98 mol%, and
    (C) at least 0.5% by weight of a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 68 to 98 mol% and a saponification degree of the vinyl acetate component of at least 20%,
    the incorporation ratio of (C) based on the sum of (B) and (C) being not more than 38% by weight.
    The resin compositions of the present invention have markedly improved flexibility without deteriorating transparency and gas barrier properties as compared with conventional saponified products of ethylene-vinyl acetate copolymers. Multilayered structures comprising at least one layer of the composition have excellent resistance to falling shock, flexural resistance, prevention of air-back, skin-pack adaptability and shrink-packaging capability and are hence of great value for packaging various goods.

    摘要翻译: 本发明提供的树脂组合物包含:(A)60〜95重量%的乙烯含量为20〜65摩尔%,乙酸乙烯酯成分皂化度为96%以上的乙烯 - 乙酸乙烯酯共聚物,(B) 4.5至39.5重量%的乙烯含量为60至98摩尔%的乙烯 - 乙酸乙烯酯共聚物,和(C)至少0.5重量%的乙烯 - 乙酸乙烯酯共聚物的皂化产物,其乙烯含量为 68〜98摩尔%,乙酸乙烯酯组分的皂化度为20重量%以上,(C)相对于(B)和(C)之和的合并比例不超过38重量%。 与乙烯 - 乙酸乙烯酯共聚物的常规皂化产物相比,本发明的树脂组合物具有显着改善的柔性,而不会劣化透明性和阻气性。 包含至少一层该组合物的多层结构物具有优异的耐跌落冲击性,抗弯曲性,防止空气回流,皮肤包装适应性和收缩包装能力,因此对于包装各种商品具有重要价值。

    Composition, process for producing the same and multilayer structure
    3.
    发明公开
    Composition, process for producing the same and multilayer structure 失效
    Zusammensetzung,Verfahren zur deren Herstellung und Schichtstoff。

    公开(公告)号:EP0249051A2

    公开(公告)日:1987-12-16

    申请号:EP87107051.2

    申请日:1987-05-15

    申请人: KURARAY CO., LTD.

    发明人: Moritani, Tohei

    摘要: A composition comprises a matrix of an ethylene-vinyl alcohol copolymer having dispersed therein a drying agent in a particulate state. The volume-area average diameter of the grains of the drying agent having a long diameter of not less than 10µm is not greater than 30µm. A multi-layer structure comprises layers of such a composition. Gas barrier property of the multi-layer structure is hardly reduced after a retort treatment and thus, the multi-layer structure is extremely useful for packaging of food, expecially packaging of retorted food.

    摘要翻译: 组合物包含其中分散有颗粒状的干燥剂的乙烯 - 乙烯醇共聚物基质。 长径不小于10微米的干燥剂颗粒的体积面积平均直径不大于30微米。 多层结构包括这种组合物的层。 在蒸煮处理之后,多层结构的气体阻隔性几乎不降低,因此多层结构对于食品的包装,特别是蒸煮食品的包装非常有用。

    Resin composition
    10.
    发明公开
    Resin composition 失效
    KUNSTSTOFF-Zusammensetzung。

    公开(公告)号:EP0401666A2

    公开(公告)日:1990-12-12

    申请号:EP90110260.8

    申请日:1990-05-30

    申请人: KURARAY CO., LTD.

    IPC分类号: C08L23/04 C08L29/04

    摘要: Provided are resin compositions comprising the following (A), (B), (C), which is at least one member selected from (C₁) through (C₃), and (D) :
    (A): a polyolefin,
    (B): a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol% and a saponification degree of vinyl acetate component of at least 96%,
    (C): (C₁): at least one inorganic substance selected from titanium oxide, talc, calcium carbonate, mica and absorptive inorganic materials,
    (C₂): at least one compound selected from the group consisting of metal salts of higher fatty acid having 8 to 22 carbon atoms, metal salts of ethylenediaminetetraacetic acid and hydrotalcite, and
    (C₃): a polyolefin modified with an unsaturated carboxylic acid or derivatives thereof;
    and,
    (D): a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 68 to 98 mol% and a saponification degree of vinyl acetate component of at least 20%.
    The compositions of the present invention have excellent compatibility within themselves and significantly solve the problems, upon molding, of molding instability such as charred resin on screw, generation of lip stain, pressure increase in extruder, abnormal flow and generation of (turbulence) wavy pattern on the surface of molded articles.

    摘要翻译: 提供包含以下(A),(B),(C),其为选自(C1)至(C3)和(D)中的至少一种的树脂组合物:(A):聚烯烃,(B) :乙烯含量为20〜65摩尔%,乙酸乙烯酯成分皂化度为96%以上的乙烯 - 乙酸乙烯酯共聚物的皂化物,(C):(C1):至少一种选自 氧化钛,滑石,碳酸钙,云母和吸收性无机材料,(C2):选自碳原子数8〜22的高级脂肪酸的金属盐,乙二胺四乙酸和水滑石的金属盐中的至少一种化合物,和 (C3):用不饱和羧酸或其衍生物改性的聚烯烃; 和(D):乙烯含量为68〜98摩尔%,乙酸乙烯酯成分皂化度为20%以上的乙烯 - 乙酸乙烯酯共聚物的皂化物。 本发明的组合物本身具有优异的相容性,并且显着地解决了成型时的诸如螺杆上烧焦树脂的模塑不稳定性,产生唇部污染,挤出机压力增加,异常流动和产生(湍流)波纹图案的问题 在模制品的表面上。