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公开(公告)号：EP2234945A1
公开(公告)日：2010-10-06
申请号：EP09705284.9
申请日：2009-01-07
发明人： MÜLLER, Wofgang , FRITZ, Peter, M. , BÖLT, Heinz , WELLENHOFER, Anton , WINKLER, Florian , ROSENTHAL, Uwe , ZANDER, Hans-Jörg , PEULECKE, Normen , MÜLLER, Bernd, H. , HOFMANN, Karl-Heinz , FRITZ, Helmut , TAUBE, Carsten , MEISWINKEL, Andreas , SCHNEIDER, Richard , WOEHL, Anina , VUGAR, Aliyev , MOSA, Fuad , AL-HAZMI, Mohammed , PALACKAL, Syriac , AL-AYED, Ayed , AL-OTAIBI, Sultan , ZAHOOR, Mohammed
IPC分类号： C07C2/22
CPC分类号： C07C2/30 , C07C2531/025 , C07C2531/04 , C07C2531/14
摘要： The present invention relates to a method for preparing linear alpha-olefins (LAO) by oligomerization of ethylene in the presence of solvent and homogenous catalyst, comprising the steps of: (i) feeding ethylene, solvent and catalyst into an oligomerization reactor, (ii) oligomerizing the ethylene in the reactor, (iii) removing a reactor outlet stream comprising solvent, linear alpha-olefins, ethylene, and catalyst from the reactor via a reactor outlet piping system, (iv) transferring the reactor outlet stream to a catalyst deactivation and removal step, and (v) deactivating and removing the catalyst from the reactor outlet stream, characterized in that at least one organic amine is added into the oligomerization reactor and/or into the reactor outlet piping system.
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公开(公告)号：EP2234945B1
公开(公告)日：2014-08-20
申请号：EP09705284.9
申请日：2009-01-07
发明人： MÜLLER, Wofgang , FRITZ, Peter, M. , BÖLT, Heinz , WELLENHOFER, Anton , WINKLER, Florian , ROSENTHAL, Uwe , ZANDER, Hans-Jörg , PEULECKE, Normen , MÜLLER, Bernd, H. , HOFMANN, Karl-Heinz , FRITZ, Helmut , TAUBE, Carsten , MEISWINKEL, Andreas , SCHNEIDER, Richard , WOEHL, Anina , VUGAR, Aliyev , MOSA, Fuad , AL-HAZMI, Mohammed , PALACKAL, Syriac , AL-AYED, Ayed , AL-OTAIBI, Sultan , ZAHOOR, Mohammed
CPC分类号： C07C2/30 , C07C2531/025 , C07C2531/04 , C07C2531/14
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公开(公告)号：EP2219784A1
公开(公告)日：2010-08-25
申请号：EP08855368.0
申请日：2008-11-05
发明人： ALIYEV, Vugar , AL-HAZMI, Mohammed, Hassan , MOSA, Fuad , FRITZ, Peter, M. , BÖLT, Heinz , WÖHL, Anina , MÜLLER, Wolfgang , WINKLER, Florian , WELLENHOFER, Anton , ROSENTHAL, Uwe , MÜLLER, Bernd, H. , HAPKE, Marko , PEULECKE, Normen
CPC分类号： B01J31/189 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/0258 , B01J2531/62 , C07C2/36 , C07C2531/14 , C07C2531/24
摘要： The present invention relates to a catalyst composition comprising: (a) a binuclear chromium(II) complex; (b) a ligand of the general structure (A) R1R2P-N(R3)-P(R4)-N(R5)-H or (B) R1R2P-N(R3)-P(R4)-N(R5)-PR6R7, wherein R1, R2, R3, R4, R5, R6 and R7 are independently selected from halogen, amino, trimethylsilyl, C1-C10-alkyl, aryl and substituted aryl, wherein the PNPN- or PNPNP-unit is optionally part of a ring system; and (c) an activator or co-catalyst, as well as to a process for oligomerization of ethylene.
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公开(公告)号：EP2219784B1
公开(公告)日：2012-10-24
申请号：EP08855368.0
申请日：2008-11-05
发明人： ALIYEV, Vugar , AL-HAZMI, Mohammed, Hassan , MOSA, Fuad , FRITZ, Peter, M. , BÖLT, Heinz , WÖHL, Anina , MÜLLER, Wolfgang , WINKLER, Florian , WELLENHOFER, Anton , ROSENTHAL, Uwe , MÜLLER, Bernd, H. , HAPKE, Marko , PEULECKE, Normen
CPC分类号： B01J31/189 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/0258 , B01J2531/62 , C07C2/36 , C07C2531/14 , C07C2531/24
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5.发明公开
公开(公告)号：EP2225033A1
公开(公告)日：2010-09-08
申请号：EP08858446.1
申请日：2008-11-13
发明人： ALIYEV, Vugar , MOSA, Fuad , AL-HAZMI, Mohammed
CPC分类号： B01J31/04 , B01J31/128 , B01J31/143 , B01J2231/20 , C07C2/30 , C07C2531/04 , C07C2531/14 , Y02P20/52
摘要： Catalyst composition for the oligomerization of ethylene, comprising (i) an at least partially hydrolyzed transition metal compound, obtainable by controlled addition of water to a transition metal compound having the general formula MXm(OR')4-m or MXm(OOCR')4-m, wherein R' is an alkyl, alkenyl, aryl, aralkyl or cycloalkyl group, X is halogen, preferably Cl or Br, and m is from 0 to 4; preferably 0-3; and (ii) an organoaluminum compound as a cocatalyst, wherein the molar ratio of water and transition metal compound is within a range of between about (0.01-3): 1; a process for oligomerization of ethylene and a method for preparing the catalyst composition.
摘要翻译： 用于乙烯低聚的催化剂组合物，其包含（i）至少部分水解的过渡金属化合物，通过受控加入水到具有通式MXM（OR“）4-m的或MXM（OOCR”）的过渡金属化合物获得的甲 4-M，worin R“是烷基，链烯基，芳基，芳烷基或环烷基，X是卤素，优选Cl或Br，m是0至4; 优选0-3; 和（ii）以有机铝化合物作为助催化剂，水和worin过渡金属化合物的摩尔比的范围内大约之间（0.01-3）：1; 用于乙烯的低聚反应和用于制备催化剂组合物的方法的过程。
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公开(公告)号：EP1786755A1
公开(公告)日：2007-05-23
申请号：EP05772212.6
申请日：2005-08-10
发明人： FRITZ, Peter , BÖLT, Heinz , MOSA, Fuad , ALI, Talal, K. , AL-OTAIBI, Sultan , SCHERSCHLICHT, Karl-Heinz
IPC分类号： C07C51/41 , C07C51/60 , C07C53/00 , C07C53/10 , C07C53/122 , C07C53/124 , C07C53/126 , C07C53/134 , C07C57/30 , C07C53/38 , C07C53/40 , C07C53/42 , C07C53/44 , C07C57/72
CPC分类号： C07C51/412 , C07C51/60 , C07C53/10 , C07C57/30 , C07C57/72 , C07C53/126 , C07C53/40 , C07C53/134 , C07C53/42 , C07C53/44 , C07C53/124 , C07C53/00 , C07C53/122 , C07C53/38
摘要： The invention relates to a novel process for the synthesis of zirconium carboxylates. In order to overcome the disadvantageous characteristics of the currently used production process (highly corrosive starting substances and products, complex removal of HCI), it is proposed to suspend ZrCI4 in an apolar solvent and react it with the anhydride of an acid. The sole products to arise are the slightly corrosive Zr carboxylate and an acid chloride, which is a valuable basic chemical in the chemicals and pharmaceuticals industry. The reactors required for the synthesis need not necessarily consist of glass and/or enamel, but may instead be manufactured from stainless steel, which is cheaper. Apparatuses for the removal and treatment of hydrochloric acid are not necessary.
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7.发明授权
公开(公告)号：EP2225033B1
公开(公告)日：2017-10-04
申请号：EP08858446.1
申请日：2008-11-13
发明人： ALIYEV, Vugar , MOSA, Fuad , AL-HAZMI, Mohammed
CPC分类号： B01J31/04 , B01J31/128 , B01J31/143 , B01J2231/20 , C07C2/30 , C07C2531/04 , C07C2531/14 , Y02P20/52
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