Abstract:
The present invention relates to: a curable composition comprising a component (A), a component (B), and a component (C), the curable composition comprising the component (A) and the component (B) in a mass ratio (component (A):component (B)) of 100:0.3 to 100:30, a cured product obtained by curing the curable composition, a method for using the curable composition as an optical device-securing adhesive or an optical device sealing material. The present invention provides a curable composition that produces a cured product that exhibits excellent transparency, excellent heat resistance, excellent crack resistance, and high adhesion, a cured product obtained by curing the curable composition, a method for using the curable composition as an optical device-securing adhesive or an optical device sealing material, a sealed optical device in which an optical device is sealed with a cured product of the curable composition, and a method for producing the same. Component (A): a silane compound copolymer (I) that is represented by a formula (a-1), wherein R 1 is a hydrogen atom or the like, X 0 is a halogen atom, a cyano group, or a group represented by OG (wherein G is a protecting group for a hydroxyl group), D is a single bond or the like, R 2 is an alkyl group having 1-20 carbon atoms or the like, Z is a hydroxyl group, an alkoxy group having 1-10 carbon atoms, or a halogen atom, m and n are a positive integer, and o, p, q, and r are 0 or a positive integer, Component (B): at least one silane coupling agent selected from a silane coupling agent that includes a nitrogen atom in its molecule and a silane coupling agent that includes an epoxy group in its molecule, and Component (C): a silane coupling agent that has an acid anhydride structure.
(CHR 1 X 0 -D-SiO 3/2 ) m (R 2 SiO 3/2 ) n (CHR 1 X 0 -D-SiZO 2/2 ) o (R 2 SiZO 2/2 ) p (CHR 1 X 0 -D-SiZ 2 O 1/2 ) q (R 2 SiZ 2 O 1/2 ) r (a-1)
Abstract:
The present invention is : a curable composition comprising a component (A) and a component (B) in a mass ratio (component (A):component (B)) of 100:0.1 to 100:50; a cured product obtained by curing the curable composition; and a method for using the curable composition as an optical device-securing adhesive or an optical device sealing material. The component (A) is a silane compound polymer that is represented by a formula (a-1)(where in the formula: R 1 is a group selected from an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, and a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, Z is a hydroxyl group, an alkoxy group having 1 to 10 carbon atoms, or a halogen atom, m is a positive integer, and n and o are independently 0 or a positive integer, provided that a plurality of R 1 are either identical or different, and a plurality of Z are either identical or different.), and the component (B) is a silane coupling agent that comprises a sulfur atom-containing functional group in its molecule.
(R 1 SiO 3/2 ) m (R 1 SiZO 2/2 ) n (R 1 SiZ 2 O 1/2 ) o ··· (a-1)
Abstract:
The present invention provides: a curable polysilsesquioxane compound comprising at least one structural unit represented by R 1 SiO 3/2 (wherein R 1 is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group), a 29 Si nuclear magnetic resonance spectrum of the curable polysilsesquioxane compound having a first peak top within a range of -65 ppm or more and less than -55 ppm, having a second peak top within a range of -73 ppm or more and less than -65 ppm, and having a third peak top within a range of -82 ppm or more and less than -73 ppm, and the ratio of an integral value (P1) of a first peak to the total of the integral value (P1) of the first peak, an integral value (P2) of a second peak, and an integral value (P3) of a third peak being more than 0% and less than 10%; a method for producing the same; a curable composition; a cured product; and a method for using curable composition or the like as an optical device-securing material. According to the present invention, there can be provided: a curable compound that produce a cured product that exhibits excellent heat resistance, and exhibits high adhesion even at a high temperature; a method for producing a curable compound; a cured product obtained by curing the curable composition; and a method for using the curable compound or the curable composition.
Abstract:
The present invention is: a curable composition comprising a component (A) and a component (B) in a mass ratio (component (A):component (B)) of 100:0.3 to 100:40, the component (A) being a silane compound copolymer that is represented by a formula (a-1), and has a weight average molecular weight of 800 to 30,000,
(CHR 1 X 0 -D-SiO 3/2 ) m (R 2 SiO 3/2 ) n CHR 1 X 0 -D-SiZO 2/2 ) o (R 2 SiZO 2/2 ) p (CHR 1 X 0 -D-SiZ 2 O 1/2 ) q (R 2 SiZ 2 O 1/2 ) r (a - 1)
wherein R 1 is a hydrogen atom, etc., X 0 is a halogen atom, etc., D is a single bond, etc., R 2 is a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, etc., Z is a hydroxyl group, etc., m and n are independently a positive integer, and o, p, q, and r are independently 0 or a positive integer, and the component (B) being a silane coupling agent that includes a nitrogen atom in its molecule. With the invention, it is possible to provide: a curable composition that produces a cured product that exhibits excellent heat resistance, excellent transparency, and high adhesion; a cured product obtained by curing the curable composition; and a method for using the curable composition as an optical device adhesive, etc.
Abstract translation:本发明是:一种可固化组合物中的质量比包含组分(A)和组分(B)((A成分):成分(B))的100:0.3〜100:40,组分(A)是 的硅烷化合物共聚物确实是由式(a-1)表示,并且具有800的重均分子量为30,000,€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(CHR 1 X 0 - D-的SiO 3/2)M(R 2的SiO 3/2)N CHR 1 X 0 D-SIZO 2/2)O(R 2 SIZO 2/2)p(CHR 1 X 0 D-SIZ 2 O 1/2)●(R 2 2 SIZ O 1/2)R€€ƒƒƒ€€€ƒƒ(A - 1)其中R 1是氢原子等,X 0是卤素原子等。 。,D为单键等,R 2是具有1至20个碳原子等一substituiertem奥德unsubstituiertem烷基,Z是羟基等,m和n独立地为正整数,且o ,p,qunabhängig,和r是0或正整数,和组分(B)为硅烷偶联剂没有包括在其分子中的氮原子。 通过本发明,能够提供:可固化组合物没有产生一个固化productsthat表现出优异的耐热性,优异的透明性,和高的附着力; 通过固化可固化组合物获得的固化产物; 和使用该固化性组合物作为光学元件用粘合剂等的方法
Abstract:
The present invention is : a curable composition comprising a component (A), a component (B), and a component (C), the curable composition comprising the component (A) and the component (B) in a mass ratio (component (A):component (B)) of 100:0.3 to 100:50, the component (A) being a curable polysilsesquioxane compound that comprises a repeating unit represented by a formula (a-1),
R 1 S i O 3/2 (a-1)
wherein R 1 is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group, the component (B) being fine particles having an average primary particle size of 5 to 40 nm, and the component (C) being a silane coupling agent that comprises a nitrogen atom in its molecule. This invention provides: a curable composition that produces a cured product that exhibits excellent adhesion, excellent delamination resistance, and excellent heat resistance, and exhibits excellent workability during the application step, a method for producing the same, a cured product obtained by curing the curable composition, a method for using the curable composition as an optical element-securing adhesive or an optical element sealing material, and an optical device.
Abstract translation:本发明是一种固化性组合物,其含有成分(A),成分(B)和成分(C),所述固化性组合物以质量比(成分(A) (A)成分为含有式(a-1)所示的重复单元的固化性聚硅倍半氧烷化合物,R 1 S 10 O 3/2(A):成分(B))100:0.3〜100: (a-1)(式中,R 1为取代或未取代的碳原子数为1〜10的烷基或取代或未取代的芳基,成分(B)为平均一次粒径为5〜40nm的微粒, 组分(C)是在其分子中包含氮原子的硅烷偶联剂。 本发明提供一种固化性组合物,该固化性组合物能够得到显示出优异的密合性,优异的耐层间剥离性和优异的耐热性,在涂布工序中显示出优异的加工性的固化物,其制造方法,固化前述固化物 组合物,使用该固化性组合物作为光学元件固定粘合剂或光学元件密封材料的方法,以及光学装置。
Abstract:
The present invention is: a curable composition comprising a component (A) and a component (B) in a mass ratio (component (A):component (B)) of 100:0.3 to 100:90, the component (A) being a silane compound polymer that is represented by a formula (a-1), wherein R 1 is a group selected from an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, and a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, Z is a hydroxyl group, an alkoxy group having 1 to 10 carbon atoms, or a halogen atom, m is a positive integer, and n and o are independently 0 or a positive integer, provided that a plurality of R 1 are either identical or different, and a plurality of Z are either identical or different, and the component (B) being a silane coupling agent that comprises an isocyanurate skeleton in its molecule.
(R 1 SiO 3/2 ) m (R 1 SiZO 2/2 ) n (R 1 SiZ 2 O 1/2 ) o (a-1)
Abstract translation:本发明是:一种可固化组合物中的质量比包含组分(A)和组分(B)((A成分):成分(B))的100:0.3〜100:90,组分(A)是 这是通过一个式(a-1)表示的硅烷化合物的聚合物,worin R 1是具有1至20个碳原子,具有3至10个碳原子的环烷基,和substituiertem奥德unsubstituiertem芳烷基中的基团 具有6至20个碳原子基团,Z是羟基,具有1至10个碳原子的烷氧基,或卤素原子的整数,m为正,且n和o独立地为0或一正整数,只要实际上一个 的R 1的多个相同或不同要么,和Z的多个相同的任一个或不同的,并且所述成分(B)为硅烷偶联剂没有异氰脲酸酯骨架的包括在其分子中。 €€ƒƒƒ€€€ƒƒƒ€€€ƒƒ(R 1的SiO 3/2)M(R 1 SIZO 2/2)N(R 1 SIZ 2 O 1/2)O€ƒƒ€€ ƒ€ƒ€ƒ(A-1)
Abstract:
The present invention is : a curable composition comprising a component (A), a component (B), and a component (C), the curable composition comprising the component (A) and the component (B) in a mass ratio (component (A):component (B)) of 100:0.3 to 100:50, the component (A) being a curable polysilsesquioxane compound that comprises a repeating unit represented by a formula (a-1),
R 1 SiO 3/2 (a-1)
wherein R 1 is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group, the component (B) being fine particles having an average primary particle size of 5 to 40 nm, and the component (C) being a silane coupling agent that comprises a sulfur atom in its molecule. This invention provides: a curable composition that produces a cured product that exhibits excellent adhesion, excellent delamination resistance, and excellent heat resistance, and exhibits excellent workability during the application step, a method for producing the same, a cured product obtained by curing the curable composition, a method for using the curable composition as an optical element-securing adhesive or an optical element sealing material, and an optical device.
Abstract:
The present invention is a curable composition comprising a component (A) and a component (B), the curable composition producing a cured product that has a solid-state Si nuclear magnetic resonance spectrum in which a peak is observed within a range from -80 ppm or more to less than -40 ppm, and a half-width of the peak is 500 to 900 Hz, the component (A) being a curable polysilsesquioxane compound that comprises a repeating unit represented by a formula (a-1),
R 1 SiO 3/2 (a-1)
the component (B) being at least one silane coupling agent selected from a group consisting of a silane coupling agent that comprises a nitrogen atom in its molecule, and a silane coupling agent that comprises an acid anhydride structure in its molecule, and a method for producing the curable composition, and a cured product, and a method for using the curable composition, and an optical device.
Abstract:
The present invention is a curable polysilsesquioxane compound comprising one structural unit or two or more structural units represented by R 1 SiO 3/2 , the curable polysilsesquioxane compound having a 29 Si nuclear magnetic resonance spectrum that has a first peak top within a range of -60 ppm or more and less than -54 ppm, has a second peak top within a range of -70 ppm or more and less than -61 ppm, and substantially does not have a peak within a range of -53 ppm or more and less than -45 ppm, and a method for producing the curable polysilsesquioxane compound, and a curable composition comprising the curable polysilsesquioxane compound and a silane coupling agent, and a cured product obtained by heating the curable composition, and a method for using the curable polysilsesquioxane compound or the curable composition, as an optical device-securing material.