CURABLE COMPOSITION, CURED PRODUCT, METHOD FOR USING CURABLE COMPOSITION, PHOTOELEMENT SEALING BODY AND METHOD FOR PRODUCING PHOTOELEMENT SEALING BODY
    1.
    发明公开
    CURABLE COMPOSITION, CURED PRODUCT, METHOD FOR USING CURABLE COMPOSITION, PHOTOELEMENT SEALING BODY AND METHOD FOR PRODUCING PHOTOELEMENT SEALING BODY 审中-公开
    可固化组合物,固化产品,使用可固化组合物的方法,发光密封体和产生光密封体的方法

    公开(公告)号:EP2963088A1

    公开(公告)日:2016-01-06

    申请号:EP14757094.9

    申请日:2014-02-27

    Abstract: The present invention relates to: a curable composition comprising a component (A), a component (B), and a component (C), the curable composition comprising the component (A) and the component (B) in a mass ratio (component (A):component (B)) of 100:0.3 to 100:30, a cured product obtained by curing the curable composition, a method for using the curable composition as an optical device-securing adhesive or an optical device sealing material. The present invention provides a curable composition that produces a cured product that exhibits excellent transparency, excellent heat resistance, excellent crack resistance, and high adhesion, a cured product obtained by curing the curable composition, a method for using the curable composition as an optical device-securing adhesive or an optical device sealing material, a sealed optical device in which an optical device is sealed with a cured product of the curable composition, and a method for producing the same. Component (A): a silane compound copolymer (I) that is represented by a formula (a-1), wherein R 1 is a hydrogen atom or the like, X 0 is a halogen atom, a cyano group, or a group represented by OG (wherein G is a protecting group for a hydroxyl group), D is a single bond or the like, R 2 is an alkyl group having 1-20 carbon atoms or the like, Z is a hydroxyl group, an alkoxy group having 1-10 carbon atoms, or a halogen atom, m and n are a positive integer, and o, p, q, and r are 0 or a positive integer, Component (B): at least one silane coupling agent selected from a silane coupling agent that includes a nitrogen atom in its molecule and a silane coupling agent that includes an epoxy group in its molecule, and Component (C): a silane coupling agent that has an acid anhydride structure.

            (CHR 1 X 0 -D-SiO 3/2 ) m (R 2 SiO 3/2 ) n (CHR 1 X 0 -D-SiZO 2/2 ) o (R 2 SiZO 2/2 ) p (CHR 1 X 0 -D-SiZ 2 O 1/2 ) q (R 2 SiZ 2 O 1/2 ) r      (a-1)

    Abstract translation: (A),成分(B)和成分(C)的固化性组合物,其中,成分(A)和成分(B)的质量比(成分 (A):成分(B))100:0.3〜100:30,使该固化性组合物固化而得到的固化物,使用该固化性组合物作为光学元件固定用粘合剂或光学元件密封材料的方法。 本发明提供一种固化性组合物,其制造显示优异的透明性,优异的耐热性,优异的耐裂纹性和高粘合性的固化物,使该固化性组合物固化而得到的固化物,以及使用该固化性组合物作为光学元件的方法 粘合剂或光学器件密封材料,其中光学器件用固化组合物的固化产物密封的密封光学器件及其制造方法。 组分(A):由式(a-1)表示的硅烷化合物共聚物(I),其中R 1是氢原子等,X 0是卤素原子,氰基或由OG (其中G是羟基的保护基),D是单键等,R 2是具有1-20个碳原子的烷基等,Z是羟基,具有1-10个碳原子的烷氧基 碳原子或卤素原子,m和n为正整数,o,p,q和r为0或正整数。组分(B):至少一种选自硅烷偶联剂的硅烷偶联剂, 在分子内具有氮原子和分子内具有环氧基的硅烷偶联剂,成分(C):具有酸酐结构的硅烷偶联剂。 (CHR1X0-d-SIO3 / 2)M(R2SiO3 / 2)N(CHR1X0-d-SiZO2 / 2)O(R2SiZO2 / 2)P(CHR1X0-d-SiZ2O1 / 2)Q(R2SiZ2O1 / 2)R(一 -1)

    CURABLE COMPOSITION, CURING PRODUCT, AND METHOD FOR USING CURABLE COMPOSITION
    2.
    发明公开
    CURABLE COMPOSITION, CURING PRODUCT, AND METHOD FOR USING CURABLE COMPOSITION 审中-公开
    可固化组合物,固化产品和使用可固化组合物的方法

    公开(公告)号:EP3034543A1

    公开(公告)日:2016-06-22

    申请号:EP14846283.1

    申请日:2014-09-19

    Abstract: The present invention is : a curable composition comprising a component (A) and a component (B) in a mass ratio (component (A):component (B)) of 100:0.1 to 100:50; a cured product obtained by curing the curable composition; and a method for using the curable composition as an optical device-securing adhesive or an optical device sealing material. The component (A) is a silane compound polymer that is represented by a formula (a-1)(where in the formula: R 1 is a group selected from an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, and a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, Z is a hydroxyl group, an alkoxy group having 1 to 10 carbon atoms, or a halogen atom, m is a positive integer, and n and o are independently 0 or a positive integer, provided that a plurality of R 1 are either identical or different, and a plurality of Z are either identical or different.), and the component (B) is a silane coupling agent that comprises a sulfur atom-containing functional group in its molecule.

            (R 1 SiO 3/2 ) m (R 1 SiZO 2/2 ) n (R 1 SiZ 2 O 1/2 ) o ···     (a-1)

    Abstract translation: 本发明是含有成分(A)和成分(B)的质量比(成分(A):成分(B))为100:0.1〜100:50的固化性组合物, 通过固化可固化组合物获得的固化产物; 以及使用该可固化组合物作为光学器件固定粘合剂或光学器件密封材料的方法。 (A)成分是由式(a-1)表示的硅烷化合物聚合物(式中,R 1为选自碳原子数1〜20的烷基,碳原子数3〜10的环烷基 碳原子和取代或未取代的碳原子数为6〜20的芳基,Z为羟基,碳原子数为1〜10的烷氧基或卤素原子,m为正整数,n及o独立地为 0或正整数,条件是多个R 1可以相同或不同,并且多个Z可以相同或不同),并且组分(B)是硅烷偶联剂,其包含含硫原子的官能团 组在其分子中。 (R1SiO3 / 2)m(R1SiZO2 / 2)n(R1SiZ2O1 / 2)○...(a-1)

    CURABLE POLYSILSESQUIOXANE COMPOUND, METHOD FOR PRODUCING SAME, CURABLE COMPOSITION, CURED PRODUCT, AND METHOD FOR USING CURABLE COMPOSITION OR LIKE
    3.
    发明公开
    CURABLE POLYSILSESQUIOXANE COMPOUND, METHOD FOR PRODUCING SAME, CURABLE COMPOSITION, CURED PRODUCT, AND METHOD FOR USING CURABLE COMPOSITION OR LIKE 审中-公开
    可固化POLYSILSESQUIOXANVERBINDUNG,制造及其方法,固化组合物,固化物及使用固化性组合物等方法

    公开(公告)号:EP2915834A1

    公开(公告)日:2015-09-09

    申请号:EP13851442.7

    申请日:2013-10-30

    CPC classification number: C08G77/04 C08G77/38 C08G77/80 C08K5/5415 C08L83/04

    Abstract: The present invention provides: a curable polysilsesquioxane compound comprising at least one structural unit represented by R 1 SiO 3/2 (wherein R 1 is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group), a 29 Si nuclear magnetic resonance spectrum of the curable polysilsesquioxane compound having a first peak top within a range of -65 ppm or more and less than -55 ppm, having a second peak top within a range of -73 ppm or more and less than -65 ppm, and having a third peak top within a range of -82 ppm or more and less than -73 ppm, and the ratio of an integral value (P1) of a first peak to the total of the integral value (P1) of the first peak, an integral value (P2) of a second peak, and an integral value (P3) of a third peak being more than 0% and less than 10%; a method for producing the same; a curable composition; a cured product; and a method for using curable composition or the like as an optical device-securing material. According to the present invention, there can be provided: a curable compound that produce a cured product that exhibits excellent heat resistance, and exhibits high adhesion even at a high temperature; a method for producing a curable compound; a cured product obtained by curing the curable composition; and a method for using the curable compound or the curable composition.

    Abstract translation: 本发明提供了:一种可固化化合物包括聚倍半硅氧烷作为R 1的SiO 3/2表示的至少一种结构单元(worin R 1为具有1至10个碳原子,或一个substituiertem奥德unsubstituiertem芳基的substituiertem奥德unsubstituiertem烷基), 可固化的聚倍半硅氧烷化合物的具有一定范围的-65 ppm以上且小于-55 ppm的范围内的第一峰顶部,具有一定范围的-73 10ppm或大于和以下的范围内的第二峰顶部的29 Si核磁共振谱 -65 ppm,且具有第三峰顶部的范围-82 ppm以上且小于-73 ppm的范围内,和一个积分值的第一峰的总积分值的(P1)的比率(P1) 第一峰的,一体值的第二峰值的(P2),并且在第三峰值是大于0%且小于10%的积分值(P3); 其制造的方法; 可固化组合物; 固化产物; 和使用可固化组合物等作为光学元件固定材料的方法。 。根据本发明,可以提供:一种可固化化合物确实产生的固化productsthat表现出优异的耐热性,并且甚至在高温下显示出高的粘合性; 用于制备可固化的化合物的方法; 通过固化可固化组合物获得的固化产物; 和使用该可固化的化合物或可固化组合物的方法。

    CURABLE COMPOSITION, CURED PRODUCT, AND METHOD FOR USING CURABLE COMPOSITION
    4.
    发明公开
    CURABLE COMPOSITION, CURED PRODUCT, AND METHOD FOR USING CURABLE COMPOSITION 审中-公开
    固化组合物,固化物及其使用方法可固化组合物

    公开(公告)号:EP2829579A1

    公开(公告)日:2015-01-28

    申请号:EP13763711.2

    申请日:2013-03-22

    Abstract: The present invention is: a curable composition comprising a component (A) and a component (B) in a mass ratio (component (A):component (B)) of 100:0.3 to 100:40, the component (A) being a silane compound copolymer that is represented by a formula (a-1), and has a weight average molecular weight of 800 to 30,000,

            (CHR 1 X 0 -D-SiO 3/2 ) m (R 2 SiO 3/2 ) n CHR 1 X 0 -D-SiZO 2/2 ) o (R 2 SiZO 2/2 ) p (CHR 1 X 0 -D-SiZ 2 O 1/2 ) q (R 2 SiZ 2 O 1/2 ) r      (a - 1)

    wherein R 1 is a hydrogen atom, etc., X 0 is a halogen atom, etc., D is a single bond, etc., R 2 is a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, etc., Z is a hydroxyl group, etc., m and n are independently a positive integer, and o, p, q, and r are independently 0 or a positive integer, and the component (B) being a silane coupling agent that includes a nitrogen atom in its molecule. With the invention, it is possible to provide: a curable composition that produces a cured product that exhibits excellent heat resistance, excellent transparency, and high adhesion; a cured product obtained by curing the curable composition; and a method for using the curable composition as an optical device adhesive, etc.

    Abstract translation: 本发明是:一种可固化组合物中的质量比包含组分(A)和组分(B)((A成分):成分(B))的100:0.3〜100:40,组分(A)是 的硅烷化合物共聚物确实是由式(a-1)表示,并且具有800的重均分子量为30,000,€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(CHR 1 X 0 - D-的SiO 3/2)M(R 2的SiO 3/2)N CHR 1 X 0 D-SIZO 2/2)O(R 2 SIZO 2/2)p(CHR 1 X 0 D-SIZ 2 O 1/2)●(R 2 2 SIZ O 1/2)R€€ƒƒƒ€€€ƒƒ(A - 1)其中R 1是氢原子等,X 0是卤素原子等。 。,D为单键等,R 2是具有1至20个碳原子等一substituiertem奥德unsubstituiertem烷基,Z是羟基等,m和n独立地为正整数,且o ,p,qunabhängig,和r是0或正整数,和组分(B)为硅烷偶联剂没有包括在其分子中的氮原子。 通过本发明,能够提供:可固化组合物没有产生一个固化productsthat表现出优异的耐热性,优异的透明性,和高的附着力; 通过固化可固化组合物获得的固化产物; 和使用该固化性组合物作为光学元件用粘合剂等的方法

    CURABLE COMPOSITION, METHOD FOR PRODUCING CURABLE COMPOSITION, CURED OBJECT, METHOD FOR USING CURABLE COMPOSITION, AND OPTICAL DEVICE
    5.
    发明公开
    CURABLE COMPOSITION, METHOD FOR PRODUCING CURABLE COMPOSITION, CURED OBJECT, METHOD FOR USING CURABLE COMPOSITION, AND OPTICAL DEVICE 审中-公开
    可固化组合物,生产可固化组合物的方法,固化物体,使用可固化组合物的方法和光学装置

    公开(公告)号:EP3187545A1

    公开(公告)日:2017-07-05

    申请号:EP15835843.2

    申请日:2015-08-21

    Abstract: The present invention is : a curable composition comprising a component (A), a component (B), and a component (C), the curable composition comprising the component (A) and the component (B) in a mass ratio (component (A):component (B)) of 100:0.3 to 100:50, the component (A) being a curable polysilsesquioxane compound that comprises a repeating unit represented by a formula (a-1),

            R 1 S i O 3/2      (a-1)

    wherein R 1 is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group, the component (B) being fine particles having an average primary particle size of 5 to 40 nm, and the component (C) being a silane coupling agent that comprises a nitrogen atom in its molecule. This invention provides: a curable composition that produces a cured product that exhibits excellent adhesion, excellent delamination resistance, and excellent heat resistance, and exhibits excellent workability during the application step, a method for producing the same, a cured product obtained by curing the curable composition, a method for using the curable composition as an optical element-securing adhesive or an optical element sealing material, and an optical device.

    Abstract translation: 本发明是一种固化性组合物,其含有成分(A),成分(B)和成分(C),所述固化性组合物以质量比(成分(A) (A)成分为含有式(a-1)所示的重复单元的固化性聚硅倍半氧烷化合物,R 1 S 10 O 3/2(A):成分(B))100:0.3〜100: (a-1)(式中,R 1为取代或未取代的碳原子数为1〜10的烷基或取代或未取代的芳基,成分(B)为平均一次粒径为5〜40nm的微粒, 组分(C)是在其分子中包含氮原子的硅烷偶联剂。 本发明提供一种固化性组合物,该固化性组合物能够得到显示出优异的密合性,优异的耐层间剥离性和优异的耐热性,在涂布工序中显示出优异的加工性的固化物,其制造方法,固化前述固化物 组合物,使用该固化性组合物作为光学元件固定粘合剂或光学元件密封材料的方法,以及光学装置。

    CURABLE COMPOSITION, CURING PRODUCT, AND METHOD FOR USING CURABLE COMPOSITION
    6.
    发明公开
    CURABLE COMPOSITION, CURING PRODUCT, AND METHOD FOR USING CURABLE COMPOSITION 审中-公开
    固化组合物,固化物及其使用方法可固化组合物

    公开(公告)号:EP3034560A1

    公开(公告)日:2016-06-22

    申请号:EP14845548.8

    申请日:2014-09-19

    Abstract: The present invention is: a curable composition comprising a component (A) and a component (B) in a mass ratio (component (A):component (B)) of 100:0.3 to 100:90, the component (A) being a silane compound polymer that is represented by a formula (a-1), wherein R 1 is a group selected from an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, and a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, Z is a hydroxyl group, an alkoxy group having 1 to 10 carbon atoms, or a halogen atom, m is a positive integer, and n and o are independently 0 or a positive integer, provided that a plurality of R 1 are either identical or different, and a plurality of Z are either identical or different, and the component (B) being a silane coupling agent that comprises an isocyanurate skeleton in its molecule.

            (R 1 SiO 3/2 ) m (R 1 SiZO 2/2 ) n (R 1 SiZ 2 O 1/2 ) o      (a-1)

    Abstract translation: 本发明是:一种可固化组合物中的质量比包含组分(A)和组分(B)((A成分):成分(B))的100:0.3〜100:90,组分(A)是 这是通过一个式(a-1)表示的硅烷化合物的聚合物,worin R 1是具有1至20个碳原子,具有3至10个碳原子的环烷基,和substituiertem奥德unsubstituiertem芳烷基中的基团 具有6至20个碳原子基团,Z是羟基,具有1至10个碳原子的烷氧基,或卤素原子的整数,m为正,且n和o独立地为0或一正整数,只要实际上一个 的R 1的多个相同或不同要么,和Z的多个相同的任一个或不同的,并且所述成分(B)为硅烷偶联剂没有异氰脲酸酯骨架的包括在其分子中。 €€ƒƒƒ€€€ƒƒƒ€€€ƒƒ(R 1的SiO 3/2)M(R 1 SIZO 2/2)N(R 1 SIZ 2 O 1/2)O€ƒƒ€€ ƒ€ƒ€ƒ(A-1)

    CURABLE COMPOSITION, METHOD OF PRODUCING CURABLE COMPOSITION, CURED MATERIAL, METHOD OF USING CURABLE COMPOSITION, AND OPTICAL DEVICE
    7.
    发明公开
    CURABLE COMPOSITION, METHOD OF PRODUCING CURABLE COMPOSITION, CURED MATERIAL, METHOD OF USING CURABLE COMPOSITION, AND OPTICAL DEVICE 审中-公开
    可固化组合物,生产可固化组合物的方法,固化材料,使用可固化组合物的方法和光学装置

    公开(公告)号:EP3196254A1

    公开(公告)日:2017-07-26

    申请号:EP15834932.4

    申请日:2015-08-21

    Abstract: The present invention is : a curable composition comprising a component (A), a component (B), and a component (C), the curable composition comprising the component (A) and the component (B) in a mass ratio (component (A):component (B)) of 100:0.3 to 100:50, the component (A) being a curable polysilsesquioxane compound that comprises a repeating unit represented by a formula (a-1),

            R 1 SiO 3/2      (a-1)

    wherein R 1 is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group, the component (B) being fine particles having an average primary particle size of 5 to 40 nm, and the component (C) being a silane coupling agent that comprises a sulfur atom in its molecule. This invention provides: a curable composition that produces a cured product that exhibits excellent adhesion, excellent delamination resistance, and excellent heat resistance, and exhibits excellent workability during the application step, a method for producing the same, a cured product obtained by curing the curable composition, a method for using the curable composition as an optical element-securing adhesive or an optical element sealing material, and an optical device.

    Abstract translation: 本发明是一种固化性组合物,其含有成分(A),成分(B)和成分(C),所述固化性组合物以质量比(成分(A) (a-1)表示的重复单元,R1SiO3 / 2(a-1)表示的可固化的聚倍半硅氧烷化合物的组分(A):100:0.3- (B)成分为平均一次粒径为5〜40nm的微粒,成分(C)为具有1〜10个碳原子的取代或未取代的烷基或取代或未取代的芳基, 是在其分子中包含硫原子的硅烷偶联剂。 本发明提供一种固化性组合物,该固化性组合物能够得到显示出优异的密合性,优异的耐层间剥离性和优异的耐热性,在涂布工序中显示出优异的加工性的固化物,其制造方法,固化前述固化物 组合物,使用该固化性组合物作为光学元件固定粘合剂或光学元件密封材料的方法,以及光学装置。

    CURABLE COMPOSITION, METHOD FOR MANUFACTURING CURABLE COMPOSITION, CURED PRODUCT, METHOD FOR USING CURABLE COMPOSITION, AND OPTICAL DEVICE
    8.
    发明公开
    CURABLE COMPOSITION, METHOD FOR MANUFACTURING CURABLE COMPOSITION, CURED PRODUCT, METHOD FOR USING CURABLE COMPOSITION, AND OPTICAL DEVICE 审中-公开
    固化组合物,用于生产可固化组合物,固化物的方法,用固化组合物和光学器件的方法

    公开(公告)号:EP3173445A1

    公开(公告)日:2017-05-31

    申请号:EP15825257.7

    申请日:2015-07-23

    Abstract: The present invention is a curable composition comprising a component (A) and a component (B),
    the curable composition producing a cured product that has a solid-state Si nuclear magnetic resonance spectrum in which a peak is observed within a range from -80 ppm or more to less than -40 ppm, and a half-width of the peak is 500 to 900 Hz,
    the component (A) being a curable polysilsesquioxane compound that comprises a repeating unit represented by a formula (a-1),

            R 1 SiO 3/2      (a-1)

    the component (B) being at least one silane coupling agent selected from a group consisting of a silane coupling agent that comprises a nitrogen atom in its molecule, and a silane coupling agent that comprises an acid anhydride structure in its molecule, and
    a method for producing the curable composition, and
    a cured product, and
    a method for using the curable composition, and
    an optical device.

    Abstract translation: 本发明是可固化组合物,包括组分(A)和组分(B),固化性组合物生产的固化productsthat具有其中峰观察-内的范围从-80固体Si核磁共振谱 10ppm或更高至低于-40 ppm,且峰的半宽度为500至900赫兹,作为固化性化合物聚倍半硅氧烷做了组分(A)包括由式(a-1),€表示的重复单元 ƒƒ€€€ƒƒƒ€€€ƒƒ€ƒR1的SiO 3/2€€ƒƒƒ€€€ƒƒ(A-1)至少一种硅烷偶联剂组分(B)从所选择的 硅烷偶联剂由......组成并基团包括在其分子中具有氮原子和硅烷偶联剂没有酸酐结构在其分子中,以及用于生产所述可固化组合物的方法,以及固化物,以及使用的方法包括 可固化组合物,以及光学装置。

    CURABLE POLYSILSESQUIOXANE COMPOUND, PRODUCTION METHOD THEREOF, CURABLE COMPOSITION, CURED PRODUCT AND USE METHOD OF CURABLE COMPOSITION
    9.
    发明公开
    CURABLE POLYSILSESQUIOXANE COMPOUND, PRODUCTION METHOD THEREOF, CURABLE COMPOSITION, CURED PRODUCT AND USE METHOD OF CURABLE COMPOSITION 审中-公开
    可固化POLYSILSESQUIOXANVERBINDUNG,工艺制作,可固化组合物,固化物和使用可固化组合物的方法

    公开(公告)号:EP3141572A1

    公开(公告)日:2017-03-15

    申请号:EP15789000.5

    申请日:2015-05-07

    Abstract: The present invention is a curable polysilsesquioxane compound comprising one structural unit or two or more structural units represented by R 1 SiO 3/2 , the curable polysilsesquioxane compound having a 29 Si nuclear magnetic resonance spectrum that has a first peak top within a range of -60 ppm or more and less than -54 ppm, has a second peak top within a range of -70 ppm or more and less than -61 ppm, and substantially does not have a peak within a range of -53 ppm or more and less than -45 ppm, and
    a method for producing the curable polysilsesquioxane compound, and
    a curable composition comprising the curable polysilsesquioxane compound and a silane coupling agent, and
    a cured product obtained by heating the curable composition, and
    a method for using the curable polysilsesquioxane compound or the curable composition, as an optical device-securing material.

    Abstract translation: 本发明是一种可固化的化合物包括聚倍半硅氧烷作为R 1的SiO 3/2表示的一个结构单元或两个或更多个结构单元,具有29的Si核磁共振光谱中的可固化的聚倍半硅氧烷化合物确实具有的范围内的第一峰顶部 - 为60ppm或以上,且小于-54 ppm时,有一系列-70 ppm以上且小于-61 ppm的范围内的第二峰顶部,大致范围-53 ppm以上和以下的范围内不具有峰 比-45 ppm,且用于制备可固化的聚倍半硅氧烷化合物的方法,和可固化组合物,包括可固化的聚倍半硅氧烷化合物和硅烷偶联剂,和通过加热所述可固化组合物获得的固化产物,和使用该可固化的聚倍半硅氧烷化合物的方法 或可固化组合物,如在光学元件固定材料。

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