摘要:
There are provided an etching mask which has a superior thermal imprinting characteristic and also a good anti-etching characteristic, a base material with the etching mask, a microfabricated product to which those etching mask and base material are applied, and a production method of the microfabricated product. The etching mask formed of a thermoplastic resin containing at least one kind of skeleton expressed by a chemical formula (1) or a chemical formula (2) in a main chain (R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 in the formulae (1), (2) can be different or same one another, each of which is a hydrogen atom, a deuterium atom, a hydrocarbon group having a carbon number of 1 to 15, a halogen atom, or a substituent group containing a hetero atom like oxygen or sulfur, and may form a ring structure one another. m and n are integers equal to or greater than 0).
摘要:
There are provided a thermal-imprinting resin which has a good heat-deterioration tolerability and a low resin elastic modulus at the time of fluidization in order to suppress any production of particle-like materials in microfabrication by thermal imprinting, and has a good fine-pattern transfer characteristic, a thermal-imprinting-resin solution using the same, a thermal-imprinting injection-molded body using the same, a thermal-imprinting thin film using the same and a production method thereof. The thermal-imprinting resin has an exothermic onset temperature (oxidation onset temperature) of an exothermic peak due to oxidation greater than or equal to + 35 °C to the glass transition temperature of the resin in differential scanning calorimetric measurement at a temperature rise rate of 5 °C/min in air, and has a complex modulus less than 0.24 MPa at the glass transition temperature of the resin + 35 °C in a dynamic viscoelastic modulus measurement at a frequency of 1 rad/sec in nitrogen stream. The thermal-imprinting-resin solution, the thermal-imprinting injection-molded body, the thermal-imprinting thin film and the production method thereof use the foregoing resin.
摘要:
A resin for thermal imprint comprised of a cycloolefin thermoplastic resin containing in its main chain at least one of skeletons of the following formula 1 or formula 2 for use in the production of injection molding, which resin has glass transition temperature, Tg(°C), and value of MFR at 260°C, [M], satisfying the following inequality (1), provided that [M]>10. Consequently, there can be attained excellence in thermal imprint performance (transferability, mold release property, etc.) and contribution toward enhancement of productivity (through-put, etc.). Formula 1: Formula 2: Inequality (1): Tg(°C)
摘要:
A cycloolefin thermoplastic resin for thermal imprinting to be used in the production of sheets or films which contains in the backbone chain at least one kind of skeletons represented by [Chemical formula 1] or [Chemical formula 2], characterized in that the glass transition temperature Tg(°C) of the resin and MFR ([M]) thereof at 260°C satisfy the relationship (1) and [M] is less than 30. This resin is excellent in thermal imprintability (such as transfer property and mold release property) and contributes to improvement in the productivity (such as throughput): Tg(°C) > 219 × log[M] - 160 ... relationship (1)