公开(公告)号：EP3092204A4

公开(公告)日：2017-12-20

申请号：EP15735525

申请日：2015-01-12

Applicant: MATERIA INC

Inventor： STEPHEN ANTHONY R ,  CRUCE CHRISTOPHER J ,  TRIMMER MARK S ,  GIARDELLO MICHAEL A

IPC: C03C25/30 ,  C08G61/08 ,  C08J5/04 ,  C08J5/08 ,  C08J5/22 ,  C08J5/24 ,  C08K3/36 ,  C08K3/40 ,  C08K5/14 ,  C08K5/5419 ,  C08K5/5425 ,  C08K7/14 ,  C08K7/28 ,  C08L65/00

CPC classification number: C08G61/02 ,  B29B15/122 ,  B29K2309/08 ,  C03C17/328 ,  C03C25/30 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/964 ,  C08J5/043 ,  C08J2323/20 ,  C08K3/36 ,  C08K3/40 ,  C08K5/14 ,  C08K5/5419 ,  C08K5/5425 ,  C08K7/14 ,  C08K7/28 ,  C08L65/00 ,  C09D165/00

Abstract: A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter.

公开(公告)号：EP2970522A4

公开(公告)日：2016-11-16

申请号：EP14762532

申请日：2014-03-14

Applicant: MATERIA INC

Inventor： STEPHEN ANTHONY R ,  CRUCE CHRISTOPHER J ,  TRIMMER MARK S ,  GIARDELLO MICHAEL A

IPC: B29C37/00 ,  C08F4/80 ,  C08G61/08

CPC classification number: C08G61/08 ,  B29C37/0032 ,  B29C41/00 ,  B29C41/22 ,  B29K2075/00 ,  C08G2261/3325 ,  C08G2261/418 ,  C08K5/05 ,  C08K5/053 ,  C08K5/101 ,  C08L65/00 ,  Y10T428/31938

公开(公告)号：EP2961778A4

公开(公告)日：2016-10-05

申请号：EP14757631

申请日：2014-02-27

Applicant: MATERIA INC

Inventor： STEPHEN ANTHONY R ,  CRUCE CHRISTOPHER J ,  GIARDELLO MICHAEL A

IPC: C08F4/80 ,  C08F132/08 ,  C08G61/08 ,  C08K9/06 ,  C08L65/00

CPC classification number: C08F32/00 ,  C08F4/80 ,  C08F132/08 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418

Abstract: This invention relates to olefin metathesis catalysts and methods for controlling olefin metathesis reactions. More particularly, the present invention relates to methods and compositions for catalyzing and controlling ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. This invention also relates to olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a ROMP composition comprising a resin composition comprising at least one cyclic olefin, and an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a method of making an article comprising combining an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts with a resin composition comprising at least one cyclic olefin, thereby forming a ROMP composition, and subjecting the ROMP composition to conditions effective to polymerize the ROMP composition. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

公开(公告)号：EP1196455A4

公开(公告)日：2005-06-08

申请号：EP00919265

申请日：2000-02-04

Applicant: MATERIA INC

Inventor： GIARDELLO MICHAEL A ,  HAAR CHRISTOPHER M

IPC: C08F4/80 ,  C08F263/04 ,  C08G61/08 ,  C09J4/00 ,  C09J151/00 ,  C09J151/06 ,  C09J151/10 ,  C09J165/00 ,  C08F4/06 ,  C08K3/14 ,  C08K3/22

CPC classification number: C09J4/00 ,  C08F263/04 ,  C08G61/08 ,  C08L2666/02 ,  C09J151/003 ,  C09J151/06 ,  C09J151/10 ,  Y10T428/31536 ,  Y10T428/31855

Abstract: The invention discloses an adhesion agent composition comprising at least one C3-C200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.

公开(公告)号：EP3016991A4

公开(公告)日：2017-01-04

申请号：EP14820242

申请日：2014-07-03

Applicant: MATERIA INC

Inventor： CRUCE CHRISTOPHER J ,  GIARDELLO MICHAEL A ,  TRIMMER MARK S ,  STEPHEN ANTHONY R ,  BOOTHE PAUL W ,  EDGECOMBE BRIAN ,  MOORE JASON L

IPC: C08F4/80 ,  C08G61/08 ,  C08J5/04 ,  C08K7/14 ,  C08L65/00

CPC classification number: C08G61/08 ,  C07C13/38 ,  C07C13/61 ,  C08F4/80 ,  C08G2261/3325 ,  C08G2261/418 ,  C08J5/043 ,  C08J2323/20 ,  C08K7/14 ,  C08L65/00

公开(公告)号：EP2721106A4

公开(公告)日：2015-09-23

申请号：EP12801260

申请日：2012-06-17

Applicant: MATERIA INC

Inventor： WANG LI-SHENG ,  STEPHEN ANTHONY R ,  BOOTHE PAUL W ,  SCHULZE TESSA ,  GIARDELLO MICHAEL A ,  TRIMMER MARK S ,  CRUCE CHRISTOPHER J ,  MOTAMEDI FARSHAD J ,  EDGECOMBE BRIAN

IPC: C08G61/08 ,  C08F32/02 ,  C08K5/00 ,  C08K5/14 ,  C08K5/16 ,  C08K5/29 ,  C08L45/00 ,  C08L65/00

CPC classification number: C03C25/30 ,  C08F32/02 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418 ,  C08K5/0025 ,  C08K5/14 ,  C08K5/29 ,  C08K2201/014 ,  C08L65/00

Abstract: This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials, pre-treating substrate materials to improve the adhesion of resin compositions to the substrate materials, and/or controlling gel formation of resin compositions. More particularly, the invention relates to compositions and methods for improving the adhesion of ring opening metathesis polymerization (ROMP) compositions to substrate materials using adhesion promoters containing isocyariate groups in a resin composition. The invention also relates to methods for improving the adhesion of resin compositions to substrate materials by pre-treating substrate materials with adhesion promoters containing isocyanate groups. The invention further relates to a method of providing a gel-modified ROMP composition, in which a hydroperoxide is added to a ROMP polymerizable resin composition in order to control gel formation of the polymerizing resin. An improved ROMP composition is further disclosed, comprising a cyclic olefin, a ROMP metathesis catalyst, an adhesion promoter, and an added hydroperoxide gel modifier. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

公开(公告)号：EP1088000A4

公开(公告)日：2002-03-06

申请号：EP99923165

申请日：1999-05-18

Applicant: MATERIA INC

Inventor： GIARDELLO MICHAEL A ,  LASCH JONATHAN G ,  CRUCE CHRISTOPHER J ,  MACLEOD JESSIE G

IPC: A63B53/04 ,  A63B53/12 ,  C08F4/20 ,  C08F4/42 ,  C08G61/08 ,  C08K5/13 ,  C08F32/04 ,  C08F32/08

CPC classification number: C08K5/13 ,  A63B53/04 ,  A63B53/12 ,  A63B2209/00 ,  C08G61/08

Abstract: The present invention provides novel polyolefin compositions having variable hardness and/or toughness properties. The polyolefin compositions include: a polyolefin prepared by the metathesis of an olefin monomer using a ruthenium or osmium carbene catalyst; and one or more hardness and/or toughness modulators. The polyolefin is preferably poly(dicyclopentadiene), or poly-DCPD. Also provided are articles of manufacture, such as molded parts, produced from the polyolefin compositions. The disclosed compositions are useful in marine, recreational and sports products.

公开(公告)号：EP3013886A4

公开(公告)日：2016-08-31

申请号：EP14818063

申请日：2014-06-24

Applicant: MATERIA INC

Inventor： CRUCE CHRISTOPHER J ,  GIARDELLO MICHAEL A ,  CONLEY BRAIN L ,  STEPHEN ANTHONY R

IPC: C08G61/08 ,  B05D7/14 ,  F16L58/10 ,  F16L58/18

CPC classification number: C08G61/02 ,  B05D7/222 ,  C08G61/08 ,  C08G2261/122 ,  C08G2261/135 ,  C08G2261/1412 ,  C08G2261/3324 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/58 ,  C08G2261/592 ,  C08G2261/596 ,  C08G2261/62 ,  C08G2261/76 ,  C08G2261/90 ,  C08L65/00 ,  C09D165/00 ,  F16L58/1054 ,  F16L58/181 ,  F16L59/028 ,  F16L59/14 ,  F16L59/143 ,  F16L59/20

公开(公告)号：EP2756112A4

公开(公告)日：2015-05-27

申请号：EP12831557

申请日：2012-09-14

Applicant: MATERIA INC

Inventor： GIARDELLO MICHAEL A ,  TRIMMER MARK S ,  CRUCE CHRISTOPHER J ,  STEPHEN ANTHONY R ,  TONER STUART A M ,  PAPPANO ALBERT E

IPC: C25B9/00 ,  B29C67/24 ,  B29K23/00 ,  C08J5/00 ,  C25B1/34 ,  G12B9/04

CPC classification number: C25B9/00 ,  B29C39/003 ,  B29C67/246 ,  B29K2023/00 ,  B29K2023/38 ,  B29K2105/0014 ,  B29K2995/0029 ,  B29L2031/7146 ,  C08G61/02 ,  C08G2120/00 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/58 ,  C25B1/34

Abstract: Articles of manufacture possessing corrosion resistance characteristics are described, in particular for use in the chlor-alkali and other industries. The articles are formed from a resin composition, e.g., a cyclic olefin composition, polymerized with a Group 8 olefin metathesis catalyst. In particular aspects, an electrolytic cell component, such as a cell cover for use in the electrolysis of brine, may be formed from the resin composition. Among other benefits, such articles provide improved corrosion resistance compared to articles molded from other resin compositions, such as Fiberglass reinforced polyesters and vinyl esters, and two-component dicyclopentadiene (DCPD) resins comprising molybdenum or tungsten pre-catalysts.

Abstract translation: 制造波塞物品唱耐蚀性特征进行了描述，特别是用于在氯 - 碱等行业中使用。 该制品由树脂组合物形成，E. G.，环烯烃组合物中，聚合用第8族烯烃复分解催化剂。 在具体的方面，以电解池组分，经测试为在盐水电解中使用的电池盖，可以从树脂组合物形成。 除了其他优点，求制品提供改善的抗腐蚀性相比从其它树脂的组合物，：诸如玻璃纤维增​​强的聚酯和乙烯基酯，和双组分的二环戊二烯（DCPD）树脂包含钼或钨预催化剂模制品。

公开(公告)号：EP1446284A4

公开(公告)日：2005-12-07

申请号：EP02766184

申请日：2002-08-30

Applicant: MATERIA INC

Inventor： CRUCE CHRISTOPHER J ,  FILICE GARY W ,  GIARDELLO MICHAEL A ,  STEPHEN ANTHONY R ,  TRIMMER MARK S

IPC: B27K3/15 ,  C04B41/48 ,  C04B41/63 ,  C08K3/00 ,  C08L23/02 ,  C08L65/00 ,  C08L97/02 ,  B32B3/26 ,  C08J5/24

CPC classification number: C08L65/00 ,  C04B41/009 ,  C04B41/4857 ,  C04B41/63 ,  C04B2111/27 ,  C08J9/42 ,  C08J2423/00 ,  C08K3/01 ,  C08K5/098 ,  C08K5/5425 ,  C08L23/02 ,  C08L79/02 ,  C08L97/02 ,  Y10T428/249925 ,  C04B41/4521 ,  C04B28/02 ,  C08L2666/26 ,  C08L2666/02 ,  C08L2666/22 ,  C08L2666/06

Abstract: The present invention relates to novel compositions comprising porous materials infused with polymers obtained from metathesis reactions, for example ROMP derived polymers and ADMET derived polymers. The invention further relates to cyclic olefin monomer formulations, including ruthenium or osmium carbene metathesis catalysts, useful for the infusion of porous materials. Also disclosed are methods for preparing the porous materials infused with cyclic olefin resin formulations.