POLYMER ELECTROLYTE TYPE FUEL CELL
    2.
    发明公开
    POLYMER ELECTROLYTE TYPE FUEL CELL 审中-公开
    聚合物-ELEKTROLYTTYP-BRENNSTOFFZELLE

    公开(公告)号:EP1357618A1

    公开(公告)日:2003-10-29

    申请号:EP02702771.3

    申请日:2002-03-06

    Abstract: In a polymer electrolyte fuel cell of the present invention, at least one of electrodes comprises conductive carbon carrying a platinum group metal catalyst, conductive carbon carrying no catalyst metal and a hydrogen ion-conductive polymer electrolyte. The preferable amount of the conductive carbon carrying no catalyst metal is equivalent to 5 to 50 wt% of the conductive carbon carrying the catalyst metal. Incorporation of the conductive carbon carrying no catalyst metal to the catalyst layer enables reduction in potential concentration on part of electron conduction channels in an electrode, whereby an electrode for a polymer electrolyte fuel cell having an excellent life characteristic can be provided.

    Abstract translation: 在本发明的高分子电解质型燃料电池中,电极中至少有一方含有携带铂族金属催化剂的导电性碳,不含催化剂金属的导电性碳和氢离子导电性高分子电解质。 不含催化剂金属的导电性碳的优选量相当于携带催化剂金属的导电性碳的5〜50重量%。 将不含催化剂金属的导电性碳引入到催化剂层中能够减少电极中的一部分电子传导通道的电位浓度,由此可以提供具有优异的寿命特性的固体高分子型燃料电池用电极。

    GAS SENSOR, AND PRODUCTION METHOD FOR GAS SENSOR
    3.
    发明公开
    GAS SENSOR, AND PRODUCTION METHOD FOR GAS SENSOR 审中-公开
    GERSENSOR UND HERSTELLUNGSVERFAHRENDAFÜR

    公开(公告)号:EP1452855A1

    公开(公告)日:2004-09-01

    申请号:EP02785934.7

    申请日:2002-11-13

    CPC classification number: G01N33/025 G01N27/125

    Abstract: The judgment about the freshness of food and drink has been made subjectively, and hence often not clear-cut; therefore, investigation has been actively made of the technology to use a semiconductor gas sensor to sense the freshness of food and drink. However, the gas sensors of the prior art have not been capable of sensing gases of, for example, ethylene, ethanol, aldehydes, mercaptans and amines, which are important in sensing the freshness of vegetables and fruits, with satisfactory responsiveness and excellent durability.
    The gas sensor of the present invention includes: an insulating substrate 1; a pair of thin film electrodes 2 provided on the insulating substrate 1 in such a manner as to leave a fixed space between them; a gas sensitive film 3 including a metallic oxide which is provided in such a manner as to substantially fill at least the fixed space left between the electrodes; and a catalytically active protective layer 5 formed in such a manner as to cover the surface of the metallic oxide exposed to the outside.

    Abstract translation: 关于食物和饮料的新鲜度的判断是主观的,因此经常不明确; 因此,积极研究了使用半导体气体传感器感测食物和饮料的新鲜度的技术。 然而,现有技术的气体传感器不能感测例如乙烯,乙醇,醛,硫醇和胺的气体,这些气体在感测蔬菜和水果的新鲜度方面是重要的,具有令人满意的响应性和优异的耐久性。 本发明的气体传感器包括:绝缘基板1; 设置在绝缘基板1上的一对薄膜电极2,以便在它们之间留下固定的空间; 包括金属氧化物的气体敏感膜3,其以基本上填充至少留在电极之间的固定空间的方式设置; 以及以覆盖暴露于外部的金属氧化物的表面的方式形成的催化活性保护层5。

    MEMBRANE CATALYST LAYER ASSEMBLY, MEMBRANE ELECTRODE ASSEMBLY, FUEL CELL AND FUEL CELL STACK
    5.
    发明公开
    MEMBRANE CATALYST LAYER ASSEMBLY, MEMBRANE ELECTRODE ASSEMBLY, FUEL CELL AND FUEL CELL STACK 有权
    KATALYSATORBESCHICHTETE膜,膜 - ELEKTRODEN-EINHEIT,BRENNSTOFFZELLE BRENNSTOFFZELLENSTAPEL

    公开(公告)号:EP1953853A1

    公开(公告)日:2008-08-06

    申请号:EP06833281.6

    申请日:2006-11-24

    Abstract: The present invention provides a catalyst-coated membrane and a membrane-electrode assembly that can easily and surely achieve a polymer electrolyte fuel cell having excellent durability, in which the decomposition/degradation of a polymer electrolyte membrane can be suppressed, and a decrease in initial characteristics can be prevented sufficiently for a long period of time even when the polymer electrolyte fuel cell is frequently started and stopped. In the catalyst-coated membrane that includes an anode catalyst layer, a cathode catalyst layer, and a hydrogen ion conductive polymer electrolyte membrane interposed between the anode catalyst layer and the cathode catalyst layer, a peripheral area of at least one of the anode catalyst layer and the cathode catalyst layer is provided with a decrease portion in which the mass of the electrode catalyst per unit area of the catalyst layer decreases from the inner side toward the outer side.

    Abstract translation: 本发明提供一种能够容易且可靠地实现耐久性优异的聚合物电解质型燃料电池的催化剂被覆膜和膜电极接合体,能够抑制聚合物电解质膜的分解/降解, 即使高分子电解质型燃料电池经常开始停止,也能够长时间充分地防止特性。 在介于阳极催化剂层和阴极催化剂层之间的包括阳极催化剂层,阴极催化剂层和氢离子导电聚合物电解质膜的催化剂涂覆膜中,阳极催化剂层中的至少一个的周边区域 并且阴极催化剂层设置有减少部分,其中催化剂层的每单位面积的电极催化剂的质量从内侧朝向外侧减小。

    MEMBRANE CATALYST LAYER ASSEMBLY, MEMBRANE ELECTRODE ASSEMBLY, AND POLYMER ELECTROLYTE FUEL CELL
    6.
    发明公开
    MEMBRANE CATALYST LAYER ASSEMBLY, MEMBRANE ELECTRODE ASSEMBLY, AND POLYMER ELECTROLYTE FUEL CELL 有权
    聚乙烯醇缩丁醛薄膜 - 薄膜 - 薄膜

    公开(公告)号:EP1705737A1

    公开(公告)日:2006-09-27

    申请号:EP05709329.6

    申请日:2005-01-25

    Abstract: An object of the present invention is to provide a catalyst-coated membrane suitable for achieving a polymer electrolyte fuel cell that sufficiently prevents a decrease in the initial characteristics and also exhibits sufficient cell performance for a long period of time and has excellent durability. In at least the cathode catalyst layer, the ratio (W P /W Cat-C ) of the weight of the polymer electrolyte (W P ) to the weight of the catalyst-carrying carbon (W Cat-C ) is decreased from an innermost layer positioned closest to the polymer electrolyte membrane toward an outermost layer positioned farthest from the polymer electrolyte membrane. The ratio (W P /W Cat-C ) in the innermost layer is 0.8 to 3.0, and the ratio (W P /W Cat-C ) in the outermost layer is 0.2 to 0.6.

    Abstract translation: 本发明的目的是提供一种适用于实现充分防止初始特性降低的聚合物电解质燃料电池的催化剂涂覆膜,并且长时间表现出充分的电池性能并且具有优异的耐久性。 在至少阴极催化剂层中,聚合物电解质(WP)的重量与催化剂载体碳重量(W Cat-C)的重量比(WP / W Cat-C)从位于 最靠近聚合物电解质膜朝向离聚合物电解质膜最远的最外层。 最内层的比例(W P / W Cat-C)为0.8〜3.0,最外层的比(W P / W Cat-C)为0.2〜0.6。

    METHOD OF MANUFACTURING ELECTROLYTIC FILM ELECTRODE CONNECTION BODY FOR FUEL CELL
    7.
    发明公开
    METHOD OF MANUFACTURING ELECTROLYTIC FILM ELECTRODE CONNECTION BODY FOR FUEL CELL 审中-公开
    VERFAHREN ZUR HERSTELLUNG EINES ELEKTROLYTISCHEN FILM-ELEKTRODENVERBINDUNGSSTÜCKESFÜREINE BRENNSTOFFZELLE

    公开(公告)号:EP1357620A1

    公开(公告)日:2003-10-29

    申请号:EP02702919.8

    申请日:2002-03-12

    Abstract: A method for producing an electrolyte membrane electrode assembly for a fuel cell according to this invention comprises the steps of: laminating a hydrogen-ion conductive polymer membrane on one face of a first shape-retaining film; forming a first catalyst layer on the hydrogen-ion conductive polymer membrane; joining a shape-retaining member to the first catalyst layer side of the hydrogen-ion conductive polymer membrane; removing the first shape-retaining film from the hydrogen-ion conductive polymer membrane; and forming a second catalyst layer on a face of the hydrogen-ion conductive polymer membrane exposed by the removal, so that the hydrogen-ion conductive polymer membrane and the catalyst layers are not damaged even when a thin hydrogen-ion conductive polymer membrane is used.

    Abstract translation: 根据本发明的用于燃料电池的电解质膜电极组件的制造方法包括以下步骤:在第一保形膜的一个面上层叠氢离子导电聚合物膜; 在氢离子导电聚合物膜上形成第一催化剂层; 将形状保持构件连接到氢离子导电聚合物膜的第一催化剂层侧; 从氢离子导电聚合物膜中除去第一形状保持膜; 在通过除去而露出的氢离子导电聚合物膜的表面上形成第二催化剂层,使得即使使用薄的氢离子导电聚合物膜也不会损坏氢离子导电聚合物膜和催化剂层 。

    POLYMER ELECTROLYTIC FUEL CELL
    9.
    发明公开
    POLYMER ELECTROLYTIC FUEL CELL 审中-公开
    POLYMER-ELEKTROLYTISCHE BRENNSTOFFZELLE

    公开(公告)号:EP1244166A1

    公开(公告)日:2002-09-25

    申请号:EP00964762.9

    申请日:2000-10-10

    Abstract: A polymer electrolyte fuel cell comprises a hydrogen-ion-conductive polymer electrolyte membrane, a pair of electrodes sandwiching the membrane, a conductive separator plate having a gas passage for supplying a fuel to one of the electrodes, and a conductive separator plate having a gas passage for supplying an oxidant to the other electrode. Conventionally, a conductive separator plate is made of a carbonaceous material, and therefore the costs such as the fabrication cost are difficult to reduce, and a metallic plate is used on trial instead of a carbonaceous plate. However the metallic plate is exposed to a hot oxidizing atmosphere, and as a result the metallic plate is corroded after a long use, lowering the power generation efficiency gradually. According to the invention, the metallic conductive separator plate is a type in which a conductive coat comprising conductive particles and glass is formed on a surface having a gas passage. Thus, the corrosion of the metallic plate is suppressed and the degradation of the power generation efficiency after long use is also suppressed.

    Abstract translation: 聚合物电解质燃料电池包括氢离子传导性聚合物电解质膜,夹着膜的一对电极,具有用于向一个电极供给燃料的气体通道的导电性隔板,以及具有气体的导电性隔板 用于向另一个电极供应氧化剂的通道。 通常,导电性隔板由碳质材料构成,因此难以降低制造成本等成本,在试制中使用金属板代替碳质板。 然而,金属板暴露于热氧化气氛,结果金属板在长时间使用后被腐蚀,逐渐降低发电效率。 根据本发明,金属导电隔板是在具有气体通道的表面上形成包含导电颗粒和玻璃的导电涂层的类型。 因此,抑制了金属板的腐蚀,并且也抑制了长时间使用后发电效率的劣化。

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