Novel coated membranes and other articles
    1.
    发明公开
    Novel coated membranes and other articles 有权
    Neue beschichtete Membranen und andere Artikel

    公开(公告)号:EP1779922A1

    公开(公告)日:2007-05-02

    申请号:EP07100634.0

    申请日:2002-04-26

    摘要: There is provided a polymer membrane having a surface coating comprising at least one hydroxymethyldiacetoneacrylamide (HMDAA) monomer of formula:

    wherein R 1 and R 2 are each independently H or CH 2 OH.
    There is also provided a method of preparing a coated polymer membrane comprising the steps of:
    a. providing a porous membrane substrate;
    b. optionally washing said porous membrane substrate with a wetting liquid to wet the surfaces thereof;
    c. optionally washing said wet porous membrane substrate with a second wetting liquid to replace said first wetting liquid, leaving said porous membrane substrate wetted with said second liquid;
    d. contacting the surfaces of said porous membrane substrate with a solution containing:
    one or more monofunctional monomers, and
    at least one monomer hydroxymethyldiacetoneacrylamide (HMDAA) monomer of formula:

    wherein R 1 and R 2 are each independently H or CH 2 OH; and
    e. polymerizing said monomers to form said coated membrane.

    摘要翻译: 提供一种聚合物膜,其具有包含至少一种下式的羟甲基二丙酮丙烯酰胺(HMDAA)单体的表面涂层:其中R 1和R 2各自独立地为H或CH 2 OH。 还提供了一种制备涂覆聚合物膜的方法,包括以下步骤:a。 提供多孔膜基材; 湾 任选地用润湿液洗涤所述多孔膜基底以润湿其表面; C。 任选地用第二润湿液体洗涤所述湿多孔膜基材以取代所述第一润湿液体,使所述多孔膜基材用所述第二液体润湿; 天。 使所述多孔膜基材的表面与含有一种或多种单官能单体和至少一种下式的单体羟甲基二丙酮丙烯酰胺(HMDAA)单体的溶液接触:其中R 1和R 2各自独立地为H或CH 2 OH; 和e。 聚合所述单体以形成所述涂覆的膜。

    Epoxide-crosslinked, charged cellulosic membrane
    3.
    发明公开
    Epoxide-crosslinked, charged cellulosic membrane 无效
    DURCH EPOXID VERNETZTE,ELEKTRISCH GELADENE CELLULOSE-MEMBRAN

    公开(公告)号:EP1470854A1

    公开(公告)日:2004-10-27

    申请号:EP04009163.9

    申请日:2004-04-16

    发明人: Charkoudian, John

    IPC分类号: B01D67/00 B01D71/10

    摘要: A porous synthetic membrane suitable for conducting macromolecular fluid separations ( e . g ., protein filtration) is described. The ultraporous membrane comprises a surface-charge layer of crosslinked polymer, the crosslinked polymer being formed from a cellulosic polymer and a crosslinking reagent. The cellulosic polymer has substantial crosslinkable hydroxyl moiety content. The crosslinking reagent is a bi- or multi-functional epoxide capable of reacting with and binding to the cellulosic polymer's hydroxyl moieties and has the formula X(CH 2 )nY, wherein: n is an integer from 1 to 5; X is H 2 COCH or H 2 COCHCH 2 O; and Y is a halogen, H 2 COCH, or H 2 COCHCH 2 O. The porous synthetic membrane has good durability and good protein binding characteristics. Surface charge is provided by covalently binding a charged moiety onto a surface of said layer of crosslinked polymer.

    摘要翻译: 多孔合成膜(I)包含交联聚合物(A)的多孔层(由能够结合羟基部分的纤维素聚合物(可交联的羟基部分)和交联试剂(a)形成)和带电部分(B )(共价结合到(A)的层的表面上)。 多孔合成膜(I)包含交联聚合物(A)的多孔层(由纤维素聚合物(可交联的羟基部分)形成)和式(X(CH 2)n Y)的交联试剂(a),其能够结合 羟基部分)和带电部分(B)(共价结合到(A)的层的表面上)。 n:1-5; X:H 2 COCH或H 2 COCHCH 2 O和Y:卤素,H 2 COCH或H 2 COCHCH 2 O。

    Crosslinked cellulosic nanofiltration membranes
    5.
    发明授权
    Crosslinked cellulosic nanofiltration membranes 无效
    Vernetzte CellulosemembranenfürNanofiltration

    公开(公告)号:EP1889653B1

    公开(公告)日:2011-06-22

    申请号:EP07114167.5

    申请日:2007-08-10

    IPC分类号: B01D71/10 B01D71/12 C08B15/00

    摘要: The present invention relates to a nanofilter formed by using a porous ultrafiltration membrane as a precursor, and carefully controlling reaction conditions so as to maintain sufficient hydrophilic nature of the membrane while causing the pore structure to close to a nanofilter range (less than 400Daltons), This produces a solvent stable cellulose nanofiltration membrane capable of operating at satisfactory flux in aqueous solutions, and being low binding to organic biomaterials.

    摘要翻译: 本发明涉及通过使用多孔超滤膜作为前体形成的纳米过滤器,并仔细控制反应条件,以便在使孔结构接近纳滤器范围(小于400道尔顿)的同时保持膜的充分的亲水性质, 这产生了能够在水溶液中以令人满意的助熔剂操作并且与有机生物材料结合低的溶剂稳定的纤维素纳米过滤膜。

    Spatially-controlled modified porous membrane
    8.
    发明公开
    Spatially-controlled modified porous membrane 有权
    Räumlichkontrolliert modifizierteporöseMembran

    公开(公告)号:EP1464380A1

    公开(公告)日:2004-10-06

    申请号:EP04006566.6

    申请日:2004-03-18

    IPC分类号: B01D67/00 B01D69/12

    摘要: This invention relates to a general method to surface modify porous membranes with a free radical polymerized polymer coating in a layer which is less than the thickness of the membrane. Another object of this invention relates to a general method to surface modify porous membranes with a free radical polymerized polymer coating to a predetermined and controlled depth from a first facial surface. Another object of this invention is to provide a general method to surface modify porous membranes with a free radical polymerized polymer coating into a pattern on one or both facial surfaces, the pattern maintaining its form to a controlled depth into the membrane. Membrane modification is spatially controlled through the use of a polymerization preventing agent (PPA), which prevents modification from occurring in defined spatially volumes of the membrane. The invention relates to porous membranes surface modified by the methods described.

    摘要翻译: 本发明涉及一种在低于膜厚度的层中用自由基聚合聚合物涂层表面改性多孔膜的一般方法。 本发明的另一个目的涉及一种用自由基聚合的聚合物涂层将多孔膜表面修饰到从第一面部表面预定和受控深度的一般方法。 本发明的另一个目的是提供一种通过自由基聚合聚合物涂层将多孔膜表面修饰成一个或两个面部表面上的图案的一般方法,该图案将其形式保持在受控的深度进入膜。 通过使用聚合防止剂(PPA)在空间上控制膜修饰,其防止在限定的空间体积的膜中发生修饰。 本发明涉及通过所述方法表面改性的多孔膜。