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1.发明授权Process for preparing a Methacrylic resin composition having a high solar radiant energy absorbing property 失效制备具有高太阳辐射能量吸收性能的甲基丙烯酸树脂组合物的方法
公开(公告)号：EP0019097B1
公开(公告)日：1984-08-15
申请号：EP80102114.8
申请日：1980-04-18
发明人： Kamada, Kazumasa , Nakai, Yoshio , Abe, Kazunori
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2.发明公开Process for producing a light-diffusible methacrylic resin, and formed articles having a delustered surface 失效一种用于制造光漫射性能的树脂制品的方法，和由其与面向DEKA表面制成。
公开(公告)号：EP0073450A2
公开(公告)日：1983-03-09
申请号：EP82107722.9
申请日：1982-08-23
发明人： Kamada, Kazumasa , Tamai, Katsumi , Abe, Kazunori
IPC分类号： C08L33/12
CPC分类号： C08F265/06 , C08F2/02
摘要： A light-diffusible methacrylic resin composed of 80 to 99.9% by weight of a polymer (A) forming a continuous phase and 20 to 0.1 % by weight of a polymer (B) forming a dispersed phase is disclosed. Polymer (A) is a polymer prepared from methyl methacrylate by itself or a polymerizable unsaturated monomer mixture containing at least 80% by weight of methyl methacrylate; polymer (B) is a polymer prepared from at least one polymerizable unsaturated monomer represented by the general formula [I]:
in which R 1 is a hydrogen atom or a methyl group and R 2 is a hydrocarbon radical having at least 2 carbon atoms or a derivative thereof. Alternatively polymer (B) may be a polymerizable unsaturated monomer mixture containing at least 50% by weight of at least one polymerizable unsaturated monomer represented by the general formula [I]. The polymer components A and B are selected such that the ratio of the refractive index n B of the polymer (B) to the refractive index n A of the polymer (A) is in the range of 0.950 ≦ n B /n A摘要翻译： 一种光扩散性的甲基丙烯酸系树脂组成的80〜99.9％（重量）的聚合物（A）的（重量）的聚合物（B）的形成连续相和20〜0.1％形成分散相游离缺失盘。 聚合物（A）是其本身或以重量计的甲基丙烯酸甲酯的含有至少80％的可聚合不饱和单体混合物由甲基丙烯酸甲酯制得的聚合物; 聚合物（B）是由通式[I]表示从至少一种可聚合的不饱和单体制备的聚合物：
其中R1是氢原子或甲基，R 2为具有至少2个碳原子的烃基 或其衍生物。 可选地聚合物（B）可以是按重量计由通式[I]表示的至少一种聚合性不饱和单体的含有至少50％的可聚合的不饱和单体混合物。 将聚合物组分A和B被选择检查没有所述聚合物（B）与聚合物（A）的折射率nA的的折射率n B的比是在0.950 -
3.发明公开Process for preparing a Methacrylic resin composition having a high solar radiant energy absorbing property 失效Verfahren zur Herstellung von Methacrylatharz mit hoher Sonnenstrahlenenergie-Absorption。
公开(公告)号：EP0019097A1
公开(公告)日：1980-11-26
申请号：EP80102114.8
申请日：1980-04-18
发明人： Kamada, Kazumasa , Nakai, Yoshio , Abe, Kazunori
摘要： An organic compound (A) containing cupric ion and a compound (B) having at least one P-O-H bond in a molecule are contained into the methacrylic resin selected from poly(methyl methacrylate) or methacrylic polymers containing at least 50% by weight of a methyl methacrylate unit.
摘要翻译： 含有铜离子的有机化合物（A）和分子中具有至少一个POH键的化合物（B）被包含在选自聚（甲基丙烯酸甲酯）或含有至少50重量％甲基 甲基丙烯酸酯单元。
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4.发明授权Process for producing a light-diffusible methacrylic resin, and formed articles having a delustered surface 失效用于生产轻质甲基丙烯酸树脂的方法，以及具有脉冲表面的成型制品
公开(公告)号：EP0073450B1
公开(公告)日：1988-10-26
申请号：EP82107722.9
申请日：1982-08-23
发明人： Kamada, Kazumasa , Tamai, Katsumi , Abe, Kazunori
IPC分类号： C08L33/12
CPC分类号： C08F265/06 , C08F2/02
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公开(公告)号：EP0097948A2
公开(公告)日：1984-01-11
申请号：EP83106256.7
申请日：1983-06-27
IPC分类号： C08F220/14 , G02B1/04 , G11B7/24
CPC分类号： G11B23/0092 , C08F220/14 , G02B1/04 , G02B1/041 , C08L33/10
摘要： A methacrylic resin having reduced water absorption properties is produced by polymerizing a mixture consisting of (A) 50 to 85% by weight of a methyl methacrylate, (B) 15 to 50 by weight of a cyclohexyl methacrylate and (C) 0 to 30% by weight of the other copolymerizable with said monomer (A) and (B),
or partially polymerized product thereof.
The methacrylic resin can suitably be used to various optical equipments, information recording substrates and so on.-
6.发明公开Process for producing a methacrylic resin shaped article having a mat surface 失效一种用于生产甲基丙烯酸系树脂成型体与无光泽的表面处理。
公开(公告)号：EP0096368A1
公开(公告)日：1983-12-21
申请号：EP83105459.8
申请日：1983-06-01
IPC分类号： C08L33/12 , C08F265/06 , C08J5/18
CPC分类号： C08J5/18 , B29C55/00 , B29C59/005 , B29K2033/04 , B29K2995/0024 , C08F265/06 , C08J2333/12 , C08L33/06 , C08L33/12 , C08L2205/22 , C08F2/02 , C08L2666/04
摘要： A novel methacrylic resin shaped article is made of novel compositions comprising (A) 80 to 99.9% by weight of methyl methacrylate polymer or copolymer, which forms continuous phase, and (B) 0.1 to 20% by weight of a polymer obtained from at least one unsaturated monomer of the general formula
wherein R 1 is H or methyl group and R 2 is a hydrocarbon radical of at least two carbon atoms, a derivative or monomer mixture thereof, the respective refractive indexes (n A ) and (n B ) of said (A) and (B) polymers satisfying the relation of 0.998 s n B /n A ≤ 1.002. The above shaped article has a latent mat surface, which therefore may be converted to a mat surface merely by means of stretching at a temperature above heat distortion temperature.-
7.发明公开
公开(公告)号：EP0012948A1
公开(公告)日：1980-07-09
申请号：EP79105152.7
申请日：1979-12-13
发明人： Kamada, Kazumasa , Sasaki, Isao , Kushi, Kenji
IPC分类号： C09D3/80
CPC分类号： C09D4/00 , Y10T428/31507 , Y10T428/31928 , C08F222/1006
摘要： Coating compositions comprising a polyfunctional monomer of a mono or polypentaerythritol poly(meth)acrylate, a bifunctional (meth)acrylate having specific monomer structure, an additional (meth)acrylate containing not more than 2 (meth)acryloyloxy groups, a phosphoric acid ester and an ethanolamine all blended together in a suitable organic solvent system together with a photosensitizer are disclosed. The compositions provide a scratch-resistant, hard cross-linked film surface that is dyeable and resists static and fogging to a synthetic resin article, such as polymethyl methacrylate, to which they are applied.
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公开(公告)号：EP0097948B2
公开(公告)日：1995-02-22
申请号：EP83106256.7
申请日：1983-06-27
IPC分类号： C08F220/14 , G02B1/04 , G11B7/24
CPC分类号： G11B23/0092 , C08F220/14 , G02B1/04 , G02B1/041 , C08L33/10
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公开(公告)号：EP0097948B1
公开(公告)日：1989-09-27
申请号：EP83106256.7
申请日：1983-06-27
IPC分类号： C08F220/14 , G02B1/04 , G11B7/24
CPC分类号： G11B23/0092 , C08F220/14 , G02B1/04 , G02B1/041 , C08L33/10
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10.发明公开Light-diffusible methacrylic resin, process for producing same and formed articles having a delustered surface 失效光可分散甲基丙烯酸树脂，其生产方法和具有抛光表面的成型制品
公开(公告)号：EP0073450A3
公开(公告)日：1984-10-03
申请号：EP82107722
申请日：1982-08-23
发明人： Kamada, Kazumasa , Tamai, Katsumi , Abe, Kazunori
IPC分类号： C08L33/12 , C08F265/06
CPC分类号： C08F265/06 , C08F2/02
摘要： A light-diffusible methacrylic resin composed of 80 to 99.9% by weight of a polymer (A) forming a continuous phase and 20 to 0.1 % by weight of a polymer (B) forming a dispersed phase is disclosed. Polymer (A) is a polymer prepared from methyl methacrylate by itself or a polymerizable unsaturated monomer mixture containing at least 80% by weight of methyl methacrylate; polymer (B) is a polymer prepared from at least one polymerizable unsaturated monomer represented by the general formula [I]:
in which R 1 is a hydrogen atom or a methyl group and R 2 is a hydrocarbon radical having at least 2 carbon atoms or a derivative thereof. Alternatively polymer (B) may be a polymerizable unsaturated monomer mixture containing at least 50% by weight of at least one polymerizable unsaturated monomer represented by the general formula [I]. The polymer components A and B are selected such that the ratio of the refractive index n B of the polymer (B) to the refractive index n A of the polymer (A) is in the range of 0.950 ≦ n B /n A
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