摘要:
An optical recording medium capable of improving uniformity of thickness of a protective film and suppressing warping. The medium is configured to comprise a substrate, an optical recording film formed on the substrate, and a light transmitting protective film formed above the optical recording layer, wherein the protective film comprises a polymer sheet produced by melt casting, and an adhesive layer for bonding the polymer sheet to the optical recording layer. As the polymer sheet, a polycarbonate sheet, a cyclic polyolefin sheet, etc. can be used. As the adhesive layer, an ultraviolet curing resin, a heat curing resin, an epoxy resin-based adhesive agent or a pressure-sensitive tackiness agent may be used alone or mixed or stacked.
摘要:
In an optical recording medium (optical disk recording medium) on which information can be optically written, read and erased by use of a laser light and which comprises a transparent substrate of a synthetic resin and an information-recording layer provided on the surface of the substrate, said synthetic resin consists of an epoxy resin composition comprising an alicyclic epoxy resin or a mixture of an alicyclic epoxy resin and an aromatic epoxy resin; an organic polybasic acid anhydride; a curing accelerator; and an anti-discoloring (anti-oxidizing) agent, the above substrate is a cured product of a cast article of the epoxy resin composition and has a Si0 2 or SiO layer or a hard coat layer of a synthetic resin which may have a Si0 2 or SiO layer on its surface, whereby the substrate has thermal resistance and abrasion or scratch resistance, and on said layer there is provided an information-recording layer made of a low melting point metal such as Te, Se, Bi or the like or a complex material of said metal and an organic material or a rare earth metal and transition metal series magnetic alloy such as Td-Gd-Fe or the like. Said transparent substrate can easily be obtained by forming a thin film of MgF 2 , CaF 2 or SiC on the inner surface of a casting mold by an ion-plating method, a spattering method or the like in order to facilitate the release of the molded article of the epoxy resin composition from the casting mold, and casting the epoxy resin composition into the mold. The Si 2 0 or SiO layer or the hard coat of synthetic resin is applied on the thus obtained substrate and the information-recording layer is then applied thereto in a conventional manner. The hard coat of synthetic resin can easily be formed by first applying the hard coat layer on the inner surface of the casting mold, then casting the epoxy resin composition into the casting mold and curing the same to transfer the hard coat onto the cured molded article of the epoxy resin composition.
摘要:
In an optical recording medium (optical disk recording medium) on which information can be optically written, read and erased by use of a laser light and which comprises a transparent substrate of a synthetic resin and an information-recording layer provided on the surface of the substrate, said synthetic resin consists of an epoxy resin composition comprising an alicyclic epoxy resin or a mixture of an alicyclic epoxy resin and an aromatic epoxy resin; an organic polybasic acid anhydride; a curing accelerator; and an anti-discoloring (anti-oxidizing) agent, the above substrate is a cured product of a cast article of the epoxy resin composition and has a Si0 2 or SiO layer or a hard coat layer of a synthetic resin which may have a Si0 2 or SiO layer on its surface, whereby the substrate has thermal resistance and abrasion or scratch resistance, and on said layer there is provided an information-recording layer made of a low melting point metal such as Te, Se, Bi or the like or a complex material of said metal and an organic material or a rare earth metal and transition metal series magnetic alloy such as Td-Gd-Fe or the like. Said transparent substrate can easily be obtained by forming a thin film of MgF 2 , CaF 2 or SiC on the inner surface of a casting mold by an ion-plating method, a spattering method or the like in order to facilitate the release of the molded article of the epoxy resin composition from the casting mold, and casting the epoxy resin composition into the mold. The Si 2 0 or SiO layer or the hard coat of synthetic resin is applied on the thus obtained substrate and the information-recording layer is then applied thereto in a conventional manner. The hard coat of synthetic resin can easily be formed by first applying the hard coat layer on the inner surface of the casting mold, then casting the epoxy resin composition into the casting mold and curing the same to transfer the hard coat onto the cured molded article of the epoxy resin composition.
摘要:
A methacrylate resin composition for optical information recording medium, excellent in releasability from mold, comprising (A) 100 parts by weight of a methacrylate resin and (B) 0.1 to 3.0 parts by weight of a surface active agent having a fluoroalkyl group.
摘要:
A methacrylic resin having reduced water absorption properties is produced by polymerizing a mixture consisting of (A) 50 to 85% by weight of a methyl methacrylate, (B) 15 to 50 by weight of a cyclohexyl methacrylate and (C) 0 to 30% by weight of the other copolymerizable with said monomer (A) and (B), or partially polymerized product thereof. The methacrylic resin can suitably be used to various optical equipments, information recording substrates and so on.
摘要:
An optical recording medium capable of improving uniformity of thickness of a protective film and suppressing warping. The medium is configured to comprise a substrate, an optical recording film formed on the substrate, and a light transmitting protective film formed above the optical recording layer, wherein the protective film comprises a polymer sheet produced by melt casting, and an adhesive layer for bonding the polymer sheet to the optical recording layer. As the polymer sheet, a polycarbonate sheet, a cyclic polyolefin sheet, etc. can be used. As the adhesive layer, an ultraviolet curing resin, a heat curing resin, an epoxy resin-based adhesive agent or a pressure-sensitive tackiness agent may be used alone or mixed or stacked.