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    PRODUCTION OF HYDROCRACKED LUBRICANTS
    3.
    发明公开
    PRODUCTION OF HYDROCRACKED LUBRICANTS 失效
    生产水泥润滑剂

    公开(公告)号：EP0596022A4

    公开(公告)日：1994-08-17

    申请号：EP92917029

    申请日：1992-07-23

    申请人： MOBIL OIL CORP

    发明人： APELIAN MINAS ROBERT ,  DEGNAN THOMAS FRANCIS JR ,  MARLER DAVID OWEN ,  MAZZONE DOMINICK NICHOLAS

    IPC分类号： B01J29/06 ,  B01J29/04 ,  C10G45/64 ,  C10G47/16 ,  C10G47/20 ,  C10G65/12

    CPC分类号： C10G47/16 ,  B01J29/042 ,  B01J29/044 ,  B01J29/045 ,  B01J2229/42

    摘要： A process for producing high quality lubricants by hydrocracking a high boiling hydrocarbon feed in the presence of hydrogen and a bifunctional hydrocracking catalyst based on an ultra-large pore crystalline material. The crystalline material exhibits unusually large pores of at least 13 Å diameter and a high sorption capacity demonstrated by its benzene adsorption capacity of greater than 15 grams benzene/100 grams at 6.7 kPa (50 Torr) and 25 °C. The crystalline material is characterized by an X-ray diffraction pattern with at least one d-spacing greater than 18 Å and in a particularly preferred form, a hexagonal arrangement of pores of at least 13 Å diameter which can be indexed with a d100 value greater than 18 Å. The hydrocracking catalysts based on these materials are capable of producing hydrocracked lube products of good viscosity index in high yields without the use of fluorine or other promoters. Petroleum waxes may be used as the feed and is hydrocracked and hydroisomerized to form the lube products.

    WAX HYDROISOMERIZATION PROCESS
    4.
    发明公开
    WAX HYDROISOMERIZATION PROCESS 失效
    WACHSHYDROISOMERISIERVERFAHREN

    公开(公告)号：EP0788533A4

    公开(公告)日：1998-08-05

    申请号：EP95935723

    申请日：1995-10-13

    申请人： MOBIL OIL CORP

    发明人： APELIAN MINAS ROBERT ,  DOUGHERTY RICHARD CHARLES ,  RUBIN MAE KOENIG

    IPC分类号： B01J29/74 ,  C10G45/64 ,  C10G73/00 ,  C10G73/38

    CPC分类号： C10G73/00 ,  C10G2400/10

    摘要： This invention discloses a process for producing a high Viscosity Index lubricant having a viscosity of at least 125 from a waxy hydrocarbon feed having a wax content of at least 40 wt.%. The process comprises catalytically dewaxing waxy paraffins present in the feed primarily by isomerization, in the presence of hydrogen and in the presence of a low acidity large pore zeolite molecular sieve having a crystal size of less than 0.1 micron, an alpha value of not more than 30 and containing a noble metal hydrogenation component. The large pore zeolite is preferably zeolite beta loaded with 0.3 to 2 wt.% Pt. The feed may be hydrocracked prior to dewaxing with the large pore zeolite. The effluent of the process may also be further dewaxed by either solvent or catalytic means in order to achieve target pour point.

    摘要翻译： 本发明公开了由蜡含量至少为40重量％的含蜡烃进料生产粘度至少为125的高粘度指数润滑剂的方法。 该方法包括主要通过异构化在存在氢气的情况下并且在具有小于0.1微米的晶体尺寸的低酸度大孔沸石分子筛的存在下催化脱蜡进料中存在的蜡状链烷烃，α值不超过 30并含有贵金属氢化组分。 大孔沸石优选负载有0.3至2重量％Pt的沸石β。 进料可以在用大孔沸石脱蜡之前进行加氢裂化。 该方法的流出物也可以通过溶剂或催化剂进一步脱蜡以达到目标倾点。