公开(公告)号：EP0597965A4

公开(公告)日：1994-08-17

申请号：EP92916884

申请日：1992-07-23

申请人： MOBIL OIL CORP

发明人： DEGNAN THOMAS FRANCIS JR ,  DWYER FRANCIS GERARD ,  KEVILLE KATHLEEN MARIE ,  KRESGE CHARLES THEODORE ,  LANDIS MICHAEL EUGENE ,  LEONOWICZ MICHAEL EDWARD ,  ROTH WIESLAW JERZY ,  SHIH STUART SHAN-SAN ,  VARTULI JAMES CLARKE

IPC分类号： B01J29/06 ,  B01D53/86 ,  B01J20/02 ,  B01J29/03 ,  B01J29/04 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  B01J37/00 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G45/08 ,  C10G45/12 ,  C10G47/16 ,  C10G45/04

CPC分类号： C10G45/12 ,  B01D53/8628 ,  B01J20/02 ,  B01J20/041 ,  B01J20/06 ,  B01J20/08 ,  B01J20/103 ,  B01J20/12 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  B01J37/0009 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16

摘要： There is provided a process for demetallizing hydrocarbon feedstocks, such as resids or shale oil. The process uses a catalyst comprising at least one hydrogenation metal, such as nickel and molybdenum, and an ultra-large pore oxide material. This ultra-large pore oxide material may have uniformly large pores, e.g., having a size of 40 nm in diameter.

公开(公告)号：EP0597954A4

公开(公告)日：1994-12-28

申请号：EP92916692

申请日：1992-07-22

申请人： MOBIL OIL CORP

发明人： KRESGE CHARLES THEODORE ,  LEONOWICZ MICHAEL EDWARD ,  ROTH WIESLAW JERZY ,  SCHMITT KIRK DOUGLAS ,  VARTULI JAMES CLARKE

IPC分类号： C01B39/04 ,  B01D53/86 ,  B01J20/02 ,  B01J20/06 ,  B01J29/03 ,  B01J29/035 ,  B01J29/04 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/02 ,  C10G11/05 ,  C10G11/06 ,  C10G47/16 ,  C01B33/033 ,  C10G11/00

CPC分类号： B01D53/8628 ,  B01J20/06 ,  B01J29/0308 ,  B01J29/035 ,  B01J29/04 ,  B01J29/041 ,  B01J29/40 ,  B01J29/70 ,  B01J29/82 ,  B01J29/83 ,  B01J29/85 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42 ,  C01B37/00 ,  C01B37/02 ,  C01B37/08 ,  C01B39/00 ,  C10G11/05 ,  C10G47/16 ,  Y10S423/30

摘要： This invention relates to a new synthetic porous crystalline material and its use thereof as a sorbent and a catalyst for the conversion of organic and inorganic compounds. The new crystalline material exhibits a large sorption capacity demonstrated by a benzene adsorption capacity of greater than about 10 grams benzene/100 grams at 50 torr and 25 °C and a particular, unique X-ray diffraction pattern.

公开(公告)号：EP0641257A4

公开(公告)日：1994-07-05

申请号：EP92916832

申请日：1992-07-23

申请人： MOBIL OIL CORP

发明人： APELIAN MINAS ROBERT ,  DEGNAN THOMAS FRANCIS JR ,  LEONOWICZ MICHAEL EDWARD ,  KRESGE CHARLES THEODORE ,  MARLER DAVID OWEN ,  MAZZONE DOMINICK NICHOLAS ,  ROTH WIESLAW JERZY ,  VARTULI JAMES CLARKE

IPC分类号： B01J29/06 ,  B01J29/03 ,  B01J29/04 ,  B01J29/068 ,  B01J29/076 ,  B01J29/08 ,  B01J29/10 ,  B01J29/83 ,  B01J29/85 ,  C10G45/12 ,  C10G47/16 ,  C10G47/20 ,  C10G11/05

CPC分类号： C10G47/16 ,  B01J29/041 ,  B01J29/043 ,  B01J29/044 ,  B01J29/045 ,  B01J29/084 ,  B01J29/10 ,  B01J29/83 ,  B01J29/85 ,  B01J2229/42

摘要： A catalytic composition comprises a metal hydrogenation-dehydrogenation component supported on a support material comprising an ultra-large pore crystalline material of high surface area and porosity. The crystalline material exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25 °C, and has uniformly sized pores with a maximum perpendicular cross section of at least about 13 Å. In a preferred form, the support material, which is preferably a metallosilicate such as an aluminosilicate, has the pores in a hexagonal arrangement, giving rise to a hexagonal electron diffraction pattern that can be indexed with a d100 value greater than about 18 Å. The catalytic composition is useful in petroleum refining, e.g. hydrocracking of mineral oil feedstocks.

公开(公告)号：EP0914308A4

公开(公告)日：2000-03-29

申请号：EP97931077

申请日：1997-06-09

申请人： MOBIL OIL CORP

发明人： CHESTER ARTHUR WARREN ,  FUNG SHIU LUN ANTHONY ,  KRESGE CHARLES THEODORE ,  ROTH WIESLAW JERZY

IPC分类号： B01J20/10 ,  B01J29/04 ,  B01J29/80 ,  C01B33/38 ,  C01B39/00 ,  C01B39/02 ,  C01B39/46 ,  C07C2/58 ,  C07C2/66 ,  C07C15/00 ,  C07C15/02 ,  C10G11/02 ,  C10G11/05 ,  C10G35/06 ,  C10G35/095

CPC分类号： B01J29/80 ,  B01J29/084 ,  B01J29/70 ,  B01J29/7038 ,  B01J2229/12 ,  B01J2229/42 ,  C01B33/38 ,  C07C2/58 ,  C07C2/66 ,  C07C2529/70 ,  C10G11/05

摘要： A layered composition of matter, MCM-56, has an X-ray diffraction including the lines listed in Table (II) and has been selectively modified so that the ratio of the number of active acid sites at its external surface to the number of internal active acid sites is greater than that of the unmodified material. When used as an additive to a large pore zeolite catalyst in the catalytic cracking of a petroleum feedstock, the modified MCM-56 gives an improved gasoline yield/octane relationship, an improved coke selectivity and a higher combined gasoline and potential alkylate yield than an identical catalyst containing unmodified MCM-56.