CATALYST FOR PRODUCTION OF CHLORINE AND PROCESS FOR PRODUCTION OF CHLORINE USING THE CATALYST
    6.
    发明公开
    CATALYST FOR PRODUCTION OF CHLORINE AND PROCESS FOR PRODUCTION OF CHLORINE USING THE CATALYST 有权
    KATALYSATOR ZUR CHLORHERSTELLUNG UND VERFAHREN ZUR CHLORHERSTELLUNG MITHILFE DES KATALYSATORS

    公开(公告)号:EP2418016A1

    公开(公告)日:2012-02-15

    申请号:EP10756188.8

    申请日:2010-03-25

    IPC分类号: B01J23/78 B01J35/08 C01B7/04

    摘要: The invention provides a chlorine production catalyst that shows excellent reaction activity in the oxidation reaction of hydrogen chloride with oxygen into chlorine, is inexpensive and can be supplied stably, and is suited for use in a fluidized-bed reactor. The invention also provides a chlorine production process using the catalyst. The chlorine production catalyst of the invention includes spherical particles containing copper element (A), an alkali metal element (B) and a lanthanoid element (C) and having an average sphericity of not less than 0.80. The lanthanoid element (C) has a bond dissociation energy with oxygen at 298 K of 100 to 185 kcal/mol. The content of the copper element (A) in the catalyst is 0.3 wt% to 4.5 wt%.

    摘要翻译: 本发明提供了一种在氯化氢与氧气与氯气的氧化反应中显示出优异的反应活性的氯生产催化剂,价格便宜,可稳定供应,适用于流化床反应器。 本发明还提供了使用该催化剂的氯生产方法。 本发明的氯生产催化剂包括含有铜元素(A),碱金属元素(B)和镧系元素(C)的球形颗粒,其平均球形度不小于0.80。 镧系元素(C)具有与298K的氧在100〜185kcal / mol的键解离能。 催化剂中的铜元素(A)的含量为0.3重量%〜4.5重量%。