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    PREPARATION METHOD FOR COMPOUND PROVIDED WITH DOUBLE BOND
    2.
    发明公开
    PREPARATION METHOD FOR COMPOUND PROVIDED WITH DOUBLE BOND 审中-公开
    HERSTELLUNGSVERFAHRENFÜREINE MIT EINER DOPPELBINDUNG AUSGESTATTETE VERBINDUNG

    公开(公告)号：EP2479159A1

    公开(公告)日：2012-07-25

    申请号：EP10817311.3

    申请日：2010-09-14

    申请人： Sumitomo Chemical Co., Ltd

    发明人： YOSHII, Masayuki ,  NAKAYAMA, Toshio ,  FUKUNAKA, Tadashi

    IPC分类号： C07C1/24 ,  B01J21/00 ,  B01J23/46 ,  C07C11/113 ,  C07C13/19 ,  C07B61/00

    CPC分类号： C07C1/24 ,  B01J21/066 ,  B01J23/462 ,  C07C29/145 ,  C07C29/76 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2531/08 ,  C07C2601/14 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/113 ,  C07C31/125 ,  C07C33/22 ,  C07C13/19 ,  C07C11/06 ,  C07C11/08 ,  C07C11/10 ,  C07C11/107

    摘要： A method for highly selectively producing a compound with a double bond represented by the following formula (III), the method comprising the following steps (A), (B), and (C):
    step (A): a step of reacting a compound represented by the following formula (I) and/or a compound represented by the following formula (II) with hydrogen in the presence of 0.1 parts by weight or more of a hydrogenation catalyst, thereby obtaining a reaction liquid,
    step (B): a step of removing the hydrogenation catalyst until the amount of the hydrogenation catalyst contained in the reaction liquid obtained in step (A) becomes 0.0010 parts by weight or less, thereby obtaining a hydrogenation catalyst-removed liquid,
    step (C): a step of obtaining a compound with a double bond represented by the following formula (III) in the presence of a dehydration catalyst from the hydrogenation catalyst-removed liquid obtained in step (B),

    wherein R 1 represents a hydrocarbon group,

    wherein R 2 represents a hydrocarbon group containing an aromatic ring,

            R 3 -CH=CH 2 (III)

    wherein R 3 represents an alkyl group, or the like.

    摘要翻译： 一种高选择性地制备由下式（III）表示的双键的化合物的方法，该方法包括以下步骤（A），（B）和（C）：步骤（A）：使 在下述通式（I）表示的化合物和/或下式（II）表示的化合物与氢气在0.1重量份以上的氢化催化剂的存在下反应，得到反应液，工序（B）： 除去氢化催化剂直到步骤（A）中得到的反应液中所含的氢化催化剂的量为0.0010重量份以下，从而得到氢化催化剂除去液，从工序（C） 在步骤（B）中得到的加氢催化剂去除液中，在脱水催化剂存在下，由下式（III）表示的双键化合物，其中R 1表示烃基，其中R 2表示烃 GROU p含有芳香环，ƒ€ƒ€ƒ€ƒ€ƒ€ƒR3 -CH = CH 2（III）其中R 3表示烷基等。

    Method of catalytic cracking, isomerizing or reforming hydrocarbons
    4.
    发明公开
    Method of catalytic cracking, isomerizing or reforming hydrocarbons 失效
    一种用于催化裂化，异构化或烃的重整过程。

    公开(公告)号：EP0341023A2

    公开(公告)日：1989-11-08

    申请号：EP89304403.2

    申请日：1989-05-02

    申请人： EXXON RESEARCH AND ENGINEERING COMPANY

    发明人： Brody, John Francis ,  Johnson, Jack Wayne ,  McVicker, Gary Brice

    IPC分类号： B01J29/02 ,  C10G11/04 ,  C10G35/06 ,  C07C5/23

    CPC分类号： B01J29/049 ,  C07C5/2213 ,  C07C5/2512 ,  C07C5/2772 ,  C07C5/417 ,  C07C2527/06 ,  C10G11/04 ,  C10G35/06 ,  C07C11/113 ,  C07C11/107

    摘要： A process for catalytic cracking, isomerizing of reforming of a hydrocarbon feed stock comprises the step of passing said hydrocarbon feed stock through a catalyst bed at cracking, isomerizing or reforming conditions to crack, isomerize or reform said hydrocarbon feed stock, wherein the catalyst composition in the catalyst bed, comprises a pillared fluorotetrasilicic mica, wherein said pillared fluorotetrasilicic mica has a specific surface area exceeding 75 m²/gm, wherein the mica is pillared by alumina, zirconia or chromia, and the aluminum, zirconium or chromium content is at least 8% by weight. In the catalytic cracking process, there is less carbon and hydrogen formed than in comparative processes, and the cracked product contains a relatively high proportion of C₃ and C₄ olefins.

    摘要翻译： 一种用于催化裂化过程中，烃原料的重整的异构化包括通过催化剂床在裂化使所述烃原料，异构化或重整条件裂纹的工序中，异构化或改革所述烃原料，worin在催化剂组合物 催化剂床，包括柱撑氟四硅云母，worin上述柱形氟四硅云母具有特定的表面积超过75米<2> /克，worin云母是由氧化铝，氧化锆或氧化铬，和铝，锆或铬含量柱是 按重量计至少8％。 在催化裂解过程中，存在较少的碳和氢形成为比在比较过程和裂化产物含有C 3和C 4烯烃的比例比较高。

    Process for propylene dimerization
    9.
    发明公开
    Process for propylene dimerization 失效
    Verfahren zur Dimerisierung von Propylen。

    公开(公告)号：EP0258973A2

    公开(公告)日：1988-03-09

    申请号：EP87305744.2

    申请日：1987-06-29

    申请人： THE DOW CHEMICAL COMPANY

    发明人： Stevens, James C. ,  Fordyce, William A.

    IPC分类号： C07C11/113 ,  C07C2/34 ,  B01J31/22

    CPC分类号： C07C2/34 ,  C07C2531/22 ,  Y02P20/52 ,  C07C11/113

    摘要： 4-methyl-1-pentene is produced via the catalyst dimerization of propylene.
    Using a catalyst comprising at least one element selected from uranium and the rare earth metals. The selectivity to 4-methyl-1-pentene usually is at least 94 mole percent. The preferred catalysts are uranium and rare earth di(poly-substituted cyclopentadienyl) hydride complexes especially uranium (pentahaptopenta methyl cyclopentadienyl) hydride complexes.

    摘要翻译： 通过丙烯的催化剂二聚制备4-甲基-1-戊烯。 使用包含至少一种选自铀和稀土金属的元素的催化剂。 4-甲基-1-戊烯的选择性通常为94摩尔％以上。 优选的催化剂是铀和稀土二（多取代的环戊二烯基）氢化物络合物，特别是铀（五五氟甲基环戊二烯基）氢化物络合物。

    Process for preparing 4-methyl-1-pentene
    10.
    发明公开
    Process for preparing 4-methyl-1-pentene 失效
    一种用于4-甲基-1-戊烯的制备方法。

    公开(公告)号：EP0143334A1

    公开(公告)日：1985-06-05

    申请号：EP84112864.8

    申请日：1984-10-25

    申请人： NIPPON OIL CO. LTD.

    发明人： Matsuno, Mitsuo ,  Kudoh, Michio ,  Imai, Hirosuke

    IPC分类号： C07C11/113 ,  C07C2/08

    CPC分类号： C07C2/10 ,  B01J23/04 ,  C07C2/26 ,  C07C2521/04 ,  C07C2523/04 ,  C07C2527/232 ,  C07C2531/02 ,  C07C11/113

    摘要： A process for preparing 4-methyl-1-pentene comprising dimerizing propylene in the presence of a catalyst, characterized in that the catalyst is composed from the treatment of precatalyst by at least one oxygen-containing compound selected from oxygen, alcohols, ethers, acetals, orthocarboxylates and esters. The precatalyst is composed of element or compound selected from sodium, potassium, sodium amide and potassium amide supported on a carrier principally represented by the following formula (1):
    wherein x has a value in the range of 0.5≦
    The use of above mentioned catalyst so remarkably increases the rate of reaction and the selectivity of 4-methyl-1-pentene and allows the reaction rate and selectivity to be kept high for a long period of time.