摘要:
A photorefractive device (100) and method of manufacture are disclosed. The device (100) comprises a layered structure in which one or more polymer layers (110) are interposed between a photorefractive material (106) and at least one transparent electrode layer (104). The layered structure is further interposed between a plurality of substrates (102). When a bias is applied to the device (100), the device (100) exhibits an increase in signal efficiency of approximately three to four times that of similar, but non-buffered, devices. Concurrently, the device (100) of the present disclosure utilizes approximately half the biased voltage, advantageously resulting in a longer device lifetime.
摘要:
A photorefractive device (100) and method of manufacture are disclosed. The device (100) comprises a layered structure in which one or more polymer layers (110) are interposed between a photorefractive material (106) and at least one transparent electrode layer (104). The layered structure is further interposed between a plurality of substrates (102). When a bias is applied to the device (100), the device (100) exhibits an increase in signal efficiency of approximately three to four times that of similar, but non-buffered, devices. Concurrently, the device (100) of the present disclosure utilizes approximately half the biased voltage, advantageously resulting in a longer device lifetime.
摘要:
A photorefractive composition comprising a polymer prepared by living radical polymerization, wherein: the living radical polymerization is carried out using a monomer, a polymerization initiator, transition metal catalyst and a ligand capable of reversibly forming a complex with the transition metal catalyst, and the polymer comprises at least one of a repeat unit including a moiety having charge transport ability and a repeat unit including a moiety having non-linear-optical ability.
摘要:
Described herein are compositions that are photorefractive upon irradiation by multiple laser wavelengths across the visible light spectrum. Embodiments of the photorefractive composition comprise a polymer, a chromophore, and a sensitizer, wherein the polymer comprises a repeating unit including at least a moiety selected from the group consisting of the formulae (Ia), (Ib) and (Ic), as defined herein. The photorefractive composition can be used in optical devices.
摘要:
The invention provides highly fluorescent materials comprising a single (n=0) or a series (n=1, 2, etc.) of benzo heterocyclic systems. The photo-stable highly luminescent chromophores are useful in various applications, including in wavelength conversion films. Wavelength conversion films have the potential to significantly enhance the solar harvesting efficiency of photovoltaic or solar cell devices.
摘要:
A photorefractive device (100) and method of manufacture are disclosed. The device (100) comprises a layered structure in which one or more polymer layers (110) are interposed between a photorefractive material (106) and at least one transparent electrode layer (104). One or more electrolytes are dispersed into the one or more polymer layers (110). When a bias is applied to the device (100), the device (100) exhibits an increase in signal efficiency compared to a similar device without electrolyte. Both grating decay time and grating response time are greatly reduced by dispersing electrolytes into one or more polymer layers in the photorefractive device. The grating decay time can be adjusted by dispersing different kinds of the electrolytes and/or different concentration of the electrolytes, which can be fitted into all kinds of applications with different requirements for grating response and decay time.
摘要:
A non-linear optical device comprising a polymer configured to provide a grating holding ratio of 20% or higher after about four minutes, wherein the polymer comprises a first repeating unit comprising a first moiety having formula (M-1) and a second repeating unit comprising a second moiety having formula (M-2), as defined herein.
摘要:
Photorefractive compositions are described. The compositions exhibit the following performances: a) Response time is less than 100 msec.; b) Initial diffraction efficiency is higher than 30%; and c) Grating holding ratio which is defined as [η (4 min.) / η (initial)] × 100 is higher than 10%, wherein the η (4 min.) is a diffraction efficiency after 4 minutes and the η (initial) is an initial diffraction efficiency.
摘要:
Described herein are wavelength conversion films which utilize photostable organic chromophores. In some embodiments, wavelength conversion films and chromophores exhibit improved photostability. In some embodiments, a wavelength conversion film comprising luminescent compounds is useful for improving the solar harvesting efficiency of solar cells, solar panels, or photovoltaic devices. In some embodiments, a wavelength conversion film comprising multiple luminescent compounds is useful for greenhouse roofs. Some embodiments provide an improved solar light wavelength profile for improved plant nutrition and/or growth.
摘要:
The invention provides highly fluorescent materials comprising a single (i=0) or a series (i=1, 2, etc.) of heterocyclic systems. The chromophores are particularly useful for absorption and emission of photons in the visible and near infrared wavelength range. The photo-stable highly luminescent chromophores are useful in various applications, including in wavelength conversion films. Wavelength conversion films have the potential to significantly enhance the solar harvesting efficiency of photovoltaic or solar cell devices.