摘要:
A hydrogen generating apparatus is provided that further suppresses deterioration in capability of a modification catalyst in raw material purge in a shutdown operation. The hydrogen generating apparatus contains a raw material supplying device 101 that supplies a raw material; a reforming device 111 that contains a reformation catalyst and generates a hydrogen-containing gas from the raw material through reformation reaction with the reformation catalyst; a modifying device 121 that contains a modification catalyst and decreases carbon monoxide in the hydrogen-containing gas through shift reaction with the modification catalyst; a first temperature detector 123 that detects a temperature of the modification catalyst; and a controlling device 200, and the controlling device 200 controls the raw material supplying device 101 to purge an interior of the modifying device 121 with the raw material when a detected temperature of the first temperature detector 123 becomes a first threshold value, at which deterioration of the modification catalyst with the raw material is suppressed, or lower in a shutdown operation.
摘要:
A hydrogen generation apparatus according to the present invention includes: a first desulfurizer (1); a second desulfurizer (2); a reformer (3) configured to generate a hydrogen-containing reformed gas from a raw material gas from which sulfur has been removed by at least one of the first desulfurizer (1) and the second desulfurizer (2); and a recycle passage (6) through which a part of the reformed gas generated by the reformer (3) is mixed into the raw material gas that is to be supplied to the second desulfurizer (2). The hydrogen generation apparatus is configured such that after installation or maintenance of the hydrogen generation apparatus, the raw material gas is supplied to the reformer (3) through the first desulfurizer (1) until a catalyst in the second desulfurizer (2) is activated by a mixed gas of the reformed gas supplied through the recycle passage (6) and the raw material gas, and after the catalyst in the second desulfurizer (2) is activated, the raw material gas is supplied to the reformer (3) through the second desulfurizer (2).
摘要:
A hydrogen generation apparatus (150) includes: a first desulfurizer (13) configured to remove, through adsorption, a sulfur compound in a raw material gas that is to be supplied to a reformer; a second desulfurizer (21) configured to hydrodesulfurize a sulfur compound in the raw material gas that is to be supplied to the reformer; a first passage (16) through which the raw material gas is supplied to the reformer through the first desulfurizer (13); a second passage (17) through which the raw material gas is supplied to the reformer through the second desulfurizer (21), without passing through the first desulfurizer (13); a switch configured to switch a passage through which the raw material gas flows between the first passage (16) and the second passage (17); and a controller. The controller controls the switch such that the raw material gas flows through the first passage (16) in at least one of a pressure compensation operation and a raw material gas purge operation, the pressure compensation operation being an operation of supplying the raw material gas in order to compensate for an internal pressure drop that occurs after an operation of generating a hydrogen-containing gas is stopped, and the raw material gas purge operation being an operation of purging the inside of the hydrogen generation apparatus with the raw material gas.
摘要:
Conventional hydrogen purification apparatuses cannot be used satisfactorily for applications in which much time is required for startup of the apparatus, and the apparatus is repeatedly started and stopped at frequent intervals because of complicated handling. In a hydrogen purification apparatus comprising at least a catalysis body 1 removing carbon monoxide from a reformed gas containing hydrogen, carbon monoxide and steam, the catalyst body 1 is constituted by a carrier comprised of a complex oxide in which at least one of Mo, W and Re is compounded with Zr, or comprised of an oxide of one of Mo, W, Re and Zr, and at least one of Pt, Pd, Rh and Ru carried on the surface of the carrier.
摘要:
A hydrogen generation device of the present invention comprises a first path (31) used to supply a raw material to a reformer (1) through at least a first desulfurization unit (2); a second path (32) used to supply the raw material to the reformer (1) through only the second desulfurization unit (3); a switch unit (6); a flow control unit (8) which selectively enables or inhibits a flow of the hydrogen-containing gas generated in the reformer 1 toward the second desulfurization unit (3); and a controller (12) configured to execute processing in such a manner that in at least either a time point before generation of the hydrogen-containing gas is stopped, or start-up, the switch unit 6 performs switching to select the first path (31), and the flow control unit (8) enables the flow of the hydrogen-containing gas, while the reformer 1 is generating the hydrogen-containing gas.