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公开(公告)号：EP3401010A1
公开(公告)日：2018-11-14
申请号：EP17173130.0
申请日：2008-03-26
申请人： PQ Corporation
发明人： LI, Hong-Xin , MODEN, Bjorn , CORMIER, William E
CPC分类号： B01D53/9418 , B01D2251/2062 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01J29/85 , B01J2229/18
摘要： There is disclosed a hydrothermally stable microporous crystalline material comprising a molecular sieve or zeolite having an 8-ring pore opening structure, such as SAPO-34 or aluminosilicate zeolite, able to retain a specific percentage of its surface area and micro pore volume after treatment with heat and moisture, such as at least 80% of its surface area and micropore volume after exposure to temperatures of up to 900 °C in the presence of up to 10 volume percent water vapor for a time ranging from 1 to 16 hours. Methods of using the disclosed crystalline material, such as in the SCR of NO x in exhaust gas are also disclosed, as are methods of making such materials.
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公开(公告)号：EP2571604A2
公开(公告)日：2013-03-27
申请号：EP11721964.2
申请日：2011-05-18
申请人： PQ Corporation
发明人： LI, Hong-xin , CORMIER, William, E. , MODEN, Bjorn
IPC分类号： B01D53/94
CPC分类号： B01D53/9418 , B01D2251/2062 , B01D2255/20738 , B01D2255/20761 , B01D2255/502 , B01J29/7615 , B01J2229/18 , C01B39/46
摘要： There is disclosed an organic-free, metal-containing zeolite Beta with a silica-to-alumina ratio (SAR) ranging from 5 and 20, and a metal content of at least 0.5 wt.%. There is also disclosed a method of making such a zeolite Beta without organic structure directing agent (SDA). The metal, which may comprise Fe or Cu, can be found in amounts ranging from 1-10 wt.%. A method of selective catalytic reduction of nitrogen oxides in exhaust gases using the disclosed zeolite is also disclosed.
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3.发明公开NOVEL IRON-CONTAINING ALUMINOSILICATE ZEOLITES AND METHODS OF MAKING AND USING SAME 审中-公开新铁硅铝分子筛及其制备方法和用途
公开(公告)号：EP2192982A2
公开(公告)日：2010-06-09
申请号：EP08795258.6
申请日：2008-08-13
申请人： PQ Corporation
发明人： LI, Hong-Xin , MODEN, Bjorn , CORMIER, William, E.
CPC分类号： B01D53/8628 , B01D53/9418 , B01D2255/20738 , B01D2255/50 , B01D2258/012 , B01J29/146 , B01J29/166 , B01J29/24 , B01J29/26 , B01J29/46 , B01J29/48 , B01J29/68 , B01J29/69 , B01J29/7215 , B01J29/7615 , B01J29/7815 , B01J29/88 , B01J35/04 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J37/0246 , F01N3/0222 , Y02A50/2325 , Y02T10/20
摘要： There is disclosed a method of using iron-containing aluminosilicate zeolite having both framework iron and iron cations on the ion-exchange sites in a selective catalytic reduction reaction, typically in the presence of ammonia, to reduce or remove nitric oxides from exhaust emissions.
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公开(公告)号：EP3788007A1
公开(公告)日：2021-03-10
申请号：EP19727168.7
申请日：2019-04-30
申请人： PQ Corporation
发明人： LI, Hong-Xin , PETUSHKOV, Anton , WANG, Lifeng , MODEN, Bjorn
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5.发明公开STABILIZED MICROPOROUS CRYSTALLINE MATERIAL, THE METHOD OF MAKING THE SAME, AND THE USE FOR SELECTIVE CATALYTIC REDUCTION OF NOX 审中-公开受规管微孔晶体物质，用于生产并使用选择性催化NOx还原
公开(公告)号：EP2785644A1
公开(公告)日：2014-10-08
申请号：EP12801688.8
申请日：2012-11-30
申请人： PQ Corporation
发明人： LI, Hong-Xin , CORMIER, William E. , MODEN, Bjorn
CPC分类号： B01J29/88 , B01D53/58 , B01D53/9418 , B01D2251/2062 , B01D2251/2067 , B01D2251/208 , B01D2253/1085 , B01D2255/202 , B01D2255/2022 , B01D2255/204 , B01D2255/2042 , B01D2255/2045 , B01D2255/2047 , B01D2255/2063 , B01D2255/2065 , B01D2255/2066 , B01D2255/2068 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9205 , B01D2255/9207 , B01J29/0356 , B01J29/072 , B01J29/7065 , B01J29/763 , B01J29/83 , B01J29/85 , B01J35/023 , B01J2229/183 , B01J2229/186 , B01J2229/36 , C01B37/08 , C01B39/02 , C01B39/026 , C01B39/46 , C01B39/54
摘要： There is disclosed a microporous crystalline material having pore opening ranging from 3 to 5 Angstroms, where the material comprises a first metal chosen from alkali earth group, rare earth group, alkali group, or mixtures thereof, and a second metal chosen from iron, copper or mixtures thereof; and has a molar silica to alumina ratio (SAR) from 3 to 10. The microporous crystalline material disclosed herein may comprise a crystal structure having building units of double-6-rings (d6r) and pore opening of 8-rings as exemplified with framework types defined by the Structure Commission of the International Zeolite Association having structural codes of CHA, LEV, AEI, AFT, AFX, EAB, ERI, KFI, SAT, TSC, and SAV. There is also disclosed a method of selective catalytic reduction of nitrogen oxides in exhaust gas, comprising at least partially contacting the exhaust gases with an article comprising the disclosed microporous crystalline material.
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公开(公告)号：EP2785644B1
公开(公告)日：2019-05-01
申请号：EP12801688.8
申请日：2012-11-30
申请人： PQ Corporation
发明人： LI, Hong-Xin , CORMIER, William E. , MODEN, Bjorn
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公开(公告)号：EP2694208A1
公开(公告)日：2014-02-12
申请号：EP12716161.0
申请日：2012-04-03
申请人： PQ Corporation
发明人： LI, Hong-xin , CORMIER, William, E. , MODEN, Bjorn
CPC分类号： B01J29/85 , B01D53/9418 , B01D2251/2062 , B01D2251/2067 , B01D2255/20738 , B01D2255/50
摘要： There is disclosed a method of making, through direct synthesis, a catalyst comprising an Fe-SAPO-34 molecular sieve. There is also disclosed an Fe-SAPO-34 molecular sieve made according to the disclosed method herein, wherein the molecular sieve contains both framework iron and iron cations at ion-exchange sites. In addition, there is disclosed a method of using the Fe-SAPO-34 disclosed herein in a selective catalytic reduction reaction, typically in the presence of ammonia or urea, to reduce or remove nitric oxides from exhaust emissions.
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8.发明公开NOVEL MICROPOROUS CRYSTALLINE MATERIAL COMPRISING A MOLECULAR SIEVE OR ZEOLITE HAVING AN 8-RING PORE OPENING STRUCTURE AND METHODS OF MAKING AND USING SAME 审中-公开包含具有8-环孔开口结构的分子筛或沸石的新颖微孔结晶材料及其制备和使用方法
公开(公告)号：EP3189893A1
公开(公告)日：2017-07-12
申请号：EP17156371.1
申请日：2008-03-26
申请人： PQ Corporation
发明人： LI, Hong-Xin , MODEN, Bjorn , CORMIER, William E
CPC分类号： B01D53/9418 , B01D2251/2062 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01J29/85 , B01J2229/18
摘要： There is disclosed a hydrothermally stable microporous crystalline material comprising a molecular sieve or zeolite having an 8-ring pore opening structure, such as SAPO-34 or aluminosilicate zeolite, able to retain a specific percentage of its surface area and micro pore volume after treatment with heat and moisture, such as at least 80% of its surface area and micropore volume after exposure to temperatures of up to 900 °C in the presence of up to 10 volume percent water vapor for a time ranging from 1 to 16 hours. Methods of using the disclosed crystalline material, such as in the SCR of NO x in exhaust gas are also disclosed, as are methods of making such materials.
摘要翻译： 公开了一种水热稳定的微孔结晶材料，其包含具有8环孔开口结构的分子筛或沸石，例如SAPO-34或硅铝酸盐沸石，其能够保持特定百分比的表面积和微孔体积， 例如至多80％的表面积和微孔体积，在高达10％体积的水蒸汽存在下暴露于高达900℃的温度下1-16小时。 还公开了使用所公开的晶体材料的方法，例如在排气中的NO x的SCR中，还公开了制造这种材料的方法。
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公开(公告)号：EP2571604B1
公开(公告)日：2014-04-16
申请号：EP11721964.2
申请日：2011-05-18
申请人： PQ Corporation
发明人： LI, Hong-xin , CORMIER, William, E. , MODEN, Bjorn
CPC分类号： B01D53/9418 , B01D2251/2062 , B01D2255/20738 , B01D2255/20761 , B01D2255/502 , B01J29/7615 , B01J2229/18 , C01B39/46
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10.发明公开HIGH SILICA CHABAZITE FOR SELECTIVE CATALYTIC REDUCTION, METHODS OF MAKING USING SAME 审中-公开Chabasit高硅用于选择性催化还原，用于生产
公开(公告)号：EP2512988A2
公开(公告)日：2012-10-24
申请号：EP10774106.8
申请日：2010-11-02
申请人： PQ Corporation
发明人： LI, Hong-Xin , CORMIER, William, E. , MODEN, Bjorn
IPC分类号： C01B39/48 , C01B39/54 , B01D53/94 , B01J29/70 , B01J29/76 , B01J29/85 , B01J35/00 , B01J35/02 , B01J35/10
CPC分类号： B01D53/9418 , B01D2251/2062 , B01D2251/2067 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9205 , B01J29/7015 , B01J29/763 , B01J29/85 , B01J35/002 , B01J35/023 , B01J35/1023 , B01J35/1038 , B01J2229/18
摘要： There is disclosed a microporous crystalline material comprising a metal containing chabazite having a crystal size greater than 0.5 microns and a silica-to- alumina ratio (SAR) greater than 15, wherein the metal containing chabazite retains at least 80% of its initial surface area and micropore volume after exposure to temperatures of up to 900°C in the presence of up to 10 volume percent water vapor for up to 1 hour. Methods of using the disclosed crystalline material, such as in the SCR of NO
x in exhaust gas are also disclosed, as are methods of making such materials.
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