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1.
公开(公告)号:EP1705737B8
公开(公告)日:2018-10-31
申请号:EP05709329.6
申请日:2005-01-25
申请人: Panasonic Corporation , AGC Inc.
发明人: YOSHIMURA, Mikiko, , HORI, Yoshihiro , TSUJI, Yoichiro , YOSHIDA, Akihiko , YONAMINE, Takeshi , UCHIDA, Makoto
IPC分类号: H01M8/1004 , H01M8/1039 , H01M8/102 , H01M4/86 , H01M4/88 , H01M4/92
CPC分类号: H01M8/1004 , H01M4/8605 , H01M4/8642 , H01M4/8657 , H01M4/881 , H01M4/8828 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M8/102 , H01M8/1039
摘要: An object of the present invention is to provide a catalyst-coated membrane suitable for achieving a polymer electrolyte fuel cell that sufficiently prevents a decrease in the initial characteristics and also exhibits sufficient cell performance for a long period of time and has excellent durability. In at least the cathode catalyst layer, the ratio (W P /W Cat-C ) of the weight of the polymer electrolyte (W P ) to the weight of the catalyst-carrying carbon (W Cat-C ) is decreased from an innermost layer positioned closest to the polymer electrolyte membrane toward an outermost layer positioned farthest from the polymer electrolyte membrane. The ratio (W P /W Cat-C ) in the innermost layer is 0.8 to 3.0, and the ratio (W P /W Cat-C ) in the outermost layer is 0.2 to 0.6.
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2.
公开(公告)号:EP1367662B1
公开(公告)日:2009-11-04
申请号:EP02702747.3
申请日:2002-03-05
发明人: YASUMOTO, Eiichi , YOSHIDA, Akihiko , UCHIDA, Makoto , MORITA, Junji , SUGAWARA, Yasushi , KANBARA, Teruhisa
CPC分类号: H01M8/1004 , H01M4/8605 , H01M4/8807 , H01M4/8821 , H01M4/8828 , H01M4/92 , H01M4/926 , H01M2300/0082 , Y02P70/56
摘要: A polymer electrolyte type fuel cell comprising a hydrogen ion-conductive polymer electrolyte film, an anode and a cathode between which the electrolyte film is sandwiched, an anode-side conductive separator having a gas passage for feeding a fuel gas to the anode, and a cathode-side conductive separator having a gas passage for feeding a gaseous oxidizing agent to the cathode, wherein the anode and the cathode each comprises a catalyst layer in contact with the electrolyte film and a gas diffusion layer in contact with the catalyst layer and the separator, and at least one of the anode and the cathode contains a compound represented by the formula (1): R1-O-{(C2H4O)n-(C3H6O)m}-R2 (wherein R1 and R2 each is C5-15 alkyl or hydrogen and n and m each is an integer satisfying the relationships 0 = n = 5, 0 = m = 5, and 1 = n + m = 5, provided that when neither n nor m is 0, then the at least one ethylene oxide unit and at least one propylene oxide unit are randomly arranged).
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3.
公开(公告)号:EP1705737B1
公开(公告)日:2018-09-05
申请号:EP05709329.6
申请日:2005-01-25
发明人: YOSHIMURA, Mikiko, , HORI, Yoshihiro , TSUJI, Yoichiro , YOSHIDA, Akihiko , YONAMINE, Takeshi , UCHIDA, Makoto
IPC分类号: H01M8/1004 , H01M8/1039 , H01M8/102 , H01M4/86 , H01M4/88 , H01M4/92
CPC分类号: H01M8/1004 , H01M4/8605 , H01M4/8642 , H01M4/8657 , H01M4/881 , H01M4/8828 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M8/102 , H01M8/1039
摘要: An object of the present invention is to provide a catalyst-coated membrane suitable for achieving a polymer electrolyte fuel cell that sufficiently prevents a decrease in the initial characteristics and also exhibits sufficient cell performance for a long period of time and has excellent durability. In at least the cathode catalyst layer, the ratio (W P /W Cat-C ) of the weight of the polymer electrolyte (W P ) to the weight of the catalyst-carrying carbon (W Cat-C ) is decreased from an innermost layer positioned closest to the polymer electrolyte membrane toward an outermost layer positioned farthest from the polymer electrolyte membrane. The ratio (W P /W Cat-C ) in the innermost layer is 0.8 to 3.0, and the ratio (W P /W Cat-C ) in the outermost layer is 0.2 to 0.6.
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公开(公告)号:EP1231656B1
公开(公告)日:2009-04-29
申请号:EP00961147.6
申请日:2000-09-20
发明人: SAKAI, Osamu , GYOTEN, Hisaaki , KUSAKABE, Hiroki , YASUMOTO, Eiichi , SUGAWARA, Yasushi , KANBARA, Teruhisa , YOSHIDA, Akihiko , UCHIDA, Makoto , MORITA, Junji
CPC分类号: H01M4/8657 , H01M4/8636 , H01M8/0234 , H01M8/0245 , H01M8/1004 , H01M8/1007 , H01M8/241 , H01M8/2415 , H01M8/2457 , H01M8/2484 , H01M2250/20 , H01M2250/402 , H01M2300/0082 , Y02B90/12 , Y02E60/521 , Y02P70/56 , Y02P90/40 , Y02T90/32 , Y10T29/49108
摘要: A polymer electrolyte fuel cell is provided comprising: a hydrogen ion conductive polymer electrolyte membrane; an anode and a cathode sandwiching the hydrogen ion conductive polymer electrolyte membrane; an anode side electroconductive separator having a gas channel for supplying a fuel gas to the anode; a cathode side electroconductive separator having a gas channel for supplying an oxidant gas to the cathode; characterized in that the anode and the cathode comprise a gas diffusion layer and a catalyst layer formed on the gas diffusion layer at the side in contact with the hydrogen ion conductive polymer electrolyte membrane, the catalyst layer has catalyst particles and a hydrogen ion conductive polymer electrolyte, and at least either of hydrogen ion conductivity and gas permeability of at least either of the anode and the cathode varies in a thickness direction of the anode or the cathode.
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公开(公告)号:EP1306913B1
公开(公告)日:2012-03-14
申请号:EP01954442.8
申请日:2001-08-03
发明人: UCHIDA, Makoto , SUGAWARA, Yasushi , YASUMOTO, Eiichi , YOSHIDA, Akihiko , MORITA, Junji , YAMAMOTO, Masao , KOSAKO, Shinya , SAKAI, Osamu , HORI, Yoshihiro
CPC分类号: H01M4/8605 , H01M4/8807 , H01M4/8828 , H01M4/921 , H01M4/926 , H01M8/0234 , Y02P70/56 , Y10T29/49115
摘要: A polyelectrolyte fuel cell having a gas channel, a proton channel and an electron channel formed in the vicinity of a pole in a catalyst layer to increase a reaction area, and comprising a hydrogen ion conductive polyelectrolyte film, and a pair of electrodes each having a catalyst layer sandwiching the hydrogen ion conductive polyelectrolyte film and a gas diffusion layer in contact with the catalyst layer, wherein the catalyst layer of at least one electrode contains carbon particles each supporting a noble-metal catalyst, and the carbon particles consist of at least two types of carbon particles being in mutually different dispersion conditions and having a hydrogen ion conductive polyelectrolyte adsorbed thereto.
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