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    CATALYTIC CRACKING CATALYST FOR HIGH-EFFICIENCY CONVERSION OF HEAVY OIL AND PREPARATION METHOD THEREOF
    4.
    发明公开
    CATALYTIC CRACKING CATALYST FOR HIGH-EFFICIENCY CONVERSION OF HEAVY OIL AND PREPARATION METHOD THEREOF 审中-公开
    催化剂用于其制造重油和方法具有较高的有效转化的催化裂化

    公开(公告)号：EP2857096A1

    公开(公告)日：2015-04-08

    申请号：EP12877707.5

    申请日：2012-07-27

    申请人： Petrochina Company Limited

    发明人： GAO, Xionghou ,  ZHANG, Haitao ,  LI, Di ,  TAN, Zhengguo ,  DUAN, Hongchang ,  LI, Xueli ,  LIU, Chaowei ,  ZHENG, Yunfeng ,  HUANG, Xiaoliang ,  CAI, Jinjun ,  PAN, Zhishuang ,  SUN, Xueqin

    IPC分类号： B01J29/08 ,  C10G11/05 ,  C01B39/24

    CPC分类号： B01J29/85 ,  B01J21/16 ,  B01J29/084 ,  B01J29/088 ,  B01J29/40 ,  B01J29/605 ,  B01J29/7003 ,  B01J29/7007 ,  B01J29/7049 ,  B01J29/80 ,  B01J35/002 ,  B01J35/10 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/28 ,  B01J37/30 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C10G11/05 ,  C10G2400/30

    摘要： The present invention provides a catalytic cracking catalyst for heavy oil and preparation methods thereof. The catalyst comprises 2 to 50% by weight of a phosphorus-containing ultrastable rare earth Y-type molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of a rare earth oxide. The phosphorus-containing ultra-stable rare earth Y-type molecular sieve uses a NaY molecular sieve as a raw material. The raw material is subjected to a rare-earth exchange and a dispersing pre-exchange; the molecular sieve slurry is then filtered, washed with water and subjected to a first calcination to obtain a rare earth sodium Y molecular sieve which has been subjected to such "first-exchange first-calcination", wherein the steps of rare earth exchange and dispersing pre-exchange are not restricted in sequence; and then the rare earth sodium Y molecular sieve which has been subjected to "one-exchange one-calcination" is subjected to "second exchange and second calcination" including ammonium exchange and a phosphorus modification, wherein the steps of the ammonium exchange and the phosphorus modification are not restricted in sequence. The steps of the ammonium exchange and the phosphorus modification can be conducted continuously or non-continuously, the second calcination is conducted after the ammonium exchange for reducing sodium, the phosphorus modification can be conducted before or after the second calcination. The catalyst provided by the invention has the characteristics of high heavy oil conversion capacity, high total liquid yield, and high yield of light oil.

    摘要翻译： 本发明提供了用于其重油和制备方法催化裂化催化剂。 所述催化剂包含2至50重量％的含磷超表稀土Y型分子筛，按重量计的一种或多种其它分子筛，0.5％至70％的0.5％至30％重量的粘土，1.0％至65％ 重量耐高温无机氧化物，以及0点01至12.5％（重量）的稀土氧化物。 含磷超稳稀土Y型分子筛使用的NaY分子筛作为原料。 原料进行稀土交换和分散预交换; 然后分子筛浆料过滤，用水洗涤，并进行第一煅烧以获得已进行到这样的“第一交换第一焙” worin稀土交换和分散的步骤的稀土钠Y型分子筛 预交换未在序列的限制; 然后已经进行对“一个交换一焙”稀土钠-Y分子筛进行“第二交换和第二煅烧”包括铵交换和磷改性，worin铵交换步骤和磷 修改还没有顺序的限制。 铵交换和磷改性的步骤可以连续进行或不连续地，第二煅烧铵交换用于减少钠后进行，所述磷改性之前或在第二煅烧后进行。 由本发明提供的催化剂具有高的重油转化能力，高的总液体收率，轻油的产量高的特点。

    ULTRA-STABLE RARE EARTH Y-TYPE MOLECULAR SIEVE AND PREPARATION METHOD THEREFOR
    6.
    发明公开
    ULTRA-STABLE RARE EARTH Y-TYPE MOLECULAR SIEVE AND PREPARATION METHOD THEREFOR 审中-公开
    超声波消除器

    公开(公告)号：EP2792641A1

    公开(公告)日：2014-10-22

    申请号：EP12857338.3

    申请日：2012-04-13

    申请人： Petrochina Company Limited

    发明人： GAO, Xionghou ,  ZHANG, Haitao ,  TAN, Zhengguo ,  LI, Di ,  JI, Dong ,  DUAN, Hongchang ,  ZHANG, Chenxi

    IPC分类号： C01B39/24 ,  B01J29/08 ,  C10G11/05

    CPC分类号： B01J29/088 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1085 ,  B01J37/30 ,  B01J2229/186 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C10G11/05

    摘要： The present invention provides an ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment. The molecular sieve comprises 1 to 20% by weight of rare earth oxide, not more than 1.2% by weight of sodium oxide, has a crystallinity of 51 to 69%, and a lattice parameter of 2.451 nm to 2.469 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 µm and a D(v,0.9) of not more than 20 µm. Cracking catalysts using the molecular sieve as an active component is characterized by a high heavy-oil-conversion capacity and a high yield of valuable target products.

    摘要翻译： 本发明提供了一种超稳定型稀土类Y分子筛及其制备方法，该方法通过以NaY分子筛为原料进行稀土交换和分散预交换，然后进行 超稳定煅烧处理。 分子筛含有1〜20重量％的稀土氧化物，不超过1.2重量％的氧化钠，结晶度为51〜69％，晶格参数为2.451〜2.469nm。 与现有技术相比，在通过该方法制备的分子筛中，稀土离子位于钠盐笼中，这是由于在反向交换过程中没有稀土离子损失的事实证明。 此外，通过这种方法制备的分子筛具有不大于3.0μm的分子粒径D（v，0.5）和不大于20μm的D（v，0.9）。 使用分子筛作为活性组分的裂化催化剂的特征在于高重油转化能力和高产率的有价值的目标产物。

    MAGNESIUM MODIFIED ULTRA-STABLE RARE EARTH Y-TYPE MOLECULAR SIEVE AND PREPARATION METHOD THEREFOR
    7.
    发明公开
    MAGNESIUM MODIFIED ULTRA-STABLE RARE EARTH Y-TYPE MOLECULAR SIEVE AND PREPARATION METHOD THEREFOR 审中-公开
    超声波发生器超声波发生器

    公开(公告)号：EP2792408A1

    公开(公告)日：2014-10-22

    申请号：EP12858105.5

    申请日：2012-04-13

    申请人： Petrochina Company Limited

    发明人： GAO, Xionghou ,  ZHANG, Haitao ,  DUAN, Hongchang ,  LIU, Chaowei ,  LI, Di ,  LI, Xueli ,  TAN, Zhengguo ,  ZHENG, Yunfeng ,  HUANG, Xiaoliang ,  CAI, Jinjun ,  ZHANG, Chenxi

    IPC分类号： B01J29/08 ,  C10G11/05

    CPC分类号： C01B39/24 ,  B01J29/084 ,  B01J29/088 ,  B01J29/80 ,  B01J35/023 ,  B01J35/10 ,  B01J35/109 ,  B01J37/08 ,  B01J37/30 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C10G11/05

    摘要： The present invention provides a magnesium-modified ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment, and finally to a magnesium modification. The molecular sieve comprises 0.2 to 5% by weight of magnesium oxide, 1 to 20% by weight of rare earth oxide, and not more than 1.2% by weight of sodium oxide, and has a crystallinity of 46 to 63%, and a lattice parameter of 2.454 nm to 2.471 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 µm and a D(v,0.9) of not more than 20 µm. Such a molecular sieve has both high stability and high selectivity for the target product, while cracking catalysts using the molecular sieve as an active component is characterized by a high heavy-oil-conversion capacity and a high yield of valuable target products.

    摘要翻译： 本发明提供一种镁改性超稳定稀土类Y分子筛及其制备方法，该方法通过以NaY分子筛为原料进行稀土交换和分散预交换， 然后进行超稳定化煅烧处理，最后进行镁改性。 分子筛含有0.2〜5重量％的氧化镁，1〜20重量％的稀土氧化物和1.2重量％的氧化钠，结晶度为46〜63％，晶格 参数为2.454 nm至2.471 nm。 与现有技术相比，在通过该方法制备的分子筛中，稀土离子位于钠盐笼中，这是由于在反向交换过程中没有稀土离子损失的事实证明。 此外，通过这种方法制备的分子筛具有不大于3.0μm的分子粒径D（v，0.5）和不大于20μm的D（v，0.9）。 这种分子筛对目标产物具有高稳定性和高选择性，而使用分子筛作为活性组分的裂化催化剂的特征在于高重油转化能力和高产率的有价值的目标产物。