摘要:
The invention relates to a method for applying a wash coat suspension to a carrier structure. To provide a method by means of which coatings of a predominantly uniform thickness starting from wash coat suspensions can be applied to a carrier structure, the invention discloses a device (10) designed to create a fluidised bed of carrier structures, in which the carrier structures have an elliptical or toroidal flow, preferably toroidal, by means of a process gas (40). The method comprises the steps: a) the device (10) is charged with carrier structures and a carrier structure fluidised bed is created by means of a process gas (40), the carrier structures in the fluidised bed having an elliptical or toroidal flow, preferably toroidal; b) the carrier structures are impregnated with a wash coat suspension by spraying the carrier structures with an elliptical or toroidal flow with said suspension; c) drying of the carrier structures that have been sprayed with the wash coat suspension; d) optional calcining of the carrier structures charged with the solid fractions of the wash coat suspension.
摘要:
The present invention relates to a method for activating a catalyst, to a catalyst activated according to the claimed method, to the use of said catalyst for producing formaldehyde, and to a reactor containing the catalyst treated according to the invention.
摘要:
The invention relates to a method for producing a nanocrystalline molybdenum mixed oxide, to the use of said molybdenum mixed oxide as a catalyst for chemical reactions, especially a reaction of acrolein to form acrylic acid, and to a catalst containing said molybdenum mixed oxide.
摘要:
The invention relates to a shell catalyst for producing vinyl acetate monomer. Said shell catalyst comprises an oxidic porous catalyst support having an outer shell that contains metallic Pd and Au, the framework of the porous catalyst support containing hafnium oxide moieties. The shell catalyst according to the invention is suitable for the production of VAM and is characterized by a relatively high activity and VAM selectivity and preserves this activity and selectivity over a relatively long service life. The invention also relates to a method for producing the shell catalyst.
摘要:
The invention relates to a supported catalyst comprising a molded support and a layer that is made of a metal oxide of a main group metal, an early transition metal, or a lanthanoid, is arranged on the molded support, and is composed of individual particles. An oxide composition, the surface density of which corresponds at least to a monolayer and which contains molybdenum and/or vanadium and/or iron, is provided on the layer or on the individual particles. The invention further relates to the use of said catalyst for reacting methanol into formaldehyde.
摘要:
The invention relates to a method for producing a shell catalyst which comprises a porous molded catalyst support having an outer shell in which at least one transition metal is contained in metallic form. The aim of the invention is to provide a shell catalyst production method which allows production of supported transition metal catalysts in the form of shell catalysts that have a relatively little shell thickness. The method according to the invention makes use of a device (10) which is adapted to cause the molded catalyst supports to circulate by means of a reducing process gas (40). Said method comprises the following steps: a) feeding molded catalyst supports to the device (10) and causing the molded catalyst supports to circulate by means of a reducing process gas (40); b) impregnating an outer shell of the molded catalyst supports with a transition metal precursor compound by spraying the circulating molded catalyst supports with a solution that contains the transition metal precursor compound; c) converting the metal component of the transition metal precursor compound to the metallic form by reduction with the process gas (40); d) drying the molded catalyst supports that are sprayed with said solution.
摘要:
The invention relates to a porous catalyst support, consisting of a material that comprises a natural phyllosilicate, with ZrO2 being contained distributed in the material. The invention also relates to method for producing the catalyst support according to the invention and to a shell catalyst containing the catalyst support according to the invention, and to the use of the catalyst according to the invention especially for the production of vinyl acetate monomer (VAM).
摘要:
The invention relates to a method for producing a shell catalyst which comprises a porous molded catalyst support having an outer shell in which at least one catalytically active species is contained. The aim of the invention is to provide a shell catalyst production method which allows production of shell catalysts that have a substantially uniform concentration in catalytically active species over a relatively large part of their shell thickness and that have a substantially uniform shell thickness. The method according to the invention makes use of a device (10) which is adapted to produce a fluid bed of molded catalyst supports by means of a process gas (40), the molded catalyst supports revolving in said bed on elliptical or toroidal, preferably toroidal, orbits. Said method comprises the following steps: a) feeding molded catalyst supports to the device (10) and producing a fluid bed of molded catalyst supports by means of a process gas (40), the molded catalyst supports revolving in said bed on elliptical or toroidal, preferably toroidal, orbits; b) impregnating an outer shell of the molded catalyst supports with a catalytically active species or a precursor thereof by spraying the molded catalyst supports that revolve in the fluid bed on elliptical or toroidal orbits with a solution that contains a catalytically active species or a precursor thereof; c) drying the molded catalyst supports that are sprayed with said solution.
摘要:
The invention relates to a method for producing nanocrystalline nickel oxides, the nickel oxides produced by means of the disclosed method, and the use thereof as a catalyst following the reduction to the nickel metal, in particular for hydrogenation reactions.
摘要:
The invention relates to a shell catalyst for producing vinyl acetate monomer (VAM). Said shell catalyst comprises a porous catalyst support which is based on a natural phyllosilicate, especially on an acid-treated calcined bentonite, and which is loaded with Pd and Au. In order to provide a shell catalyst for use in the production of VAM which is characterized by a relatively high VAM selectivity and high activity, the catalyst support has a surface of less than 130 m2/g.