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1.发明授权
公开(公告)号：EP0211030B1
公开(公告)日：1991-04-03
申请号：EP86900815.1
申请日：1986-01-24
申请人： Secretary of State for Defence in Her Britannic Majesty's Gov. of the United Kingdom of Great Britain and Northern Ireland , STC PLC
发明人： COATES, David , GRAY, George, William , LACEY, David , YOUNG, Daniel, James, Stephen , TOYNE, Kenneth, Johnson , BONE, Matthew, Francis
IPC分类号： C07C69/76 , C07C251/24 , C07D239/26 , C09K19/58
CPC分类号： C07D239/26 , C09K19/126 , C09K19/2021 , C09K19/2028 , C09K19/22 , C09K19/3001 , C09K19/32 , C09K19/42 , C09K19/50 , C09K19/58 , C09K19/586 , C09K2019/3095
摘要： Novel derivatives of cyclic and acyclic terpenoid alcohols, having general formula (I) X-(CO)n-O-T1, where n = O or 1, T1 is a terpenoid group and X is a combination of cyclic groups, eg phenyl, cyclohexyl and pyrimidyl. X preferably contains up to three cyclic groups. Preferred derivatives are esters of cyclic terpenoid alcohols, eg menthol, borneol and isopineocampheol, eg formula (II) (-)-menthol. Ferroelectric smectic liquid crystal mixtures and devices containing these derivatives as chiral dopants in a tilted smectic host are also described. The properties of various other derivatives of terpenoid alcohols of formula (I) are also described, eg those of neomenthol, isolongifolol, fenchol, carveol, myrthenol, nopol, citronellol, perilla alcohol and dihydrocitronellol.
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公开(公告)号：EP0201554B2
公开(公告)日：1993-01-27
申请号：EP85905639.2
申请日：1985-11-08
申请人： Secretary of State for Defence in Her Britannic Majesty's Gov. of the United Kingdom of Great Britain and Northern Ireland , STC PLC
发明人： BONE, Matthew, Francis 47 Newtown Road , JACKSON, Adam , CHAN, Lawrence, Kam, Ming 112 Lee Street , COATES, David , GEMMELL, Peter, Alan , GRAY, George, William , LACEY, David , TOYNE, Kenneth, Johnson , YOUNG, Daniel, James, Stephen 2 York Way , SCROWSTON, Richard, Michael 11 Saunders Croft
CPC分类号： C09K19/2028 , C09K19/126 , C09K19/2021 , C09K19/22 , C09K19/3001 , C09K19/3068 , C09K19/32 , C09K19/42 , C09K19/50 , C09K2019/3095
摘要： Ferroelectric smectic liquid crystal mixtures are provided consisting of two constituents; a smectic host and another containing a chiral compound in which rotation of the chiral centre relative to the molecular core is sterically hindered, so that the chiral compound induces a high Ps in the mixture. A preferred class of chiral compounds is those derived from naturally occurring compounds with chiral groups, especially alpha-hydroxycarboxylic acids, amino acids and terpenoids, e.g. with chiral groups (I), (II), (III). The chiral group is incorporated into a compound containing a mesogenic combination of groups, e.g. with chains of cyclic groups and some mesogenic combinations are described.
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3.发明授权
公开(公告)号：EP0258298B1
公开(公告)日：1990-08-29
申请号：EP87901069.2
申请日：1987-01-28
申请人： SECRETARY OF STATE FOR DEFENCE IN HER BRITANNIC MAJESTY'S GOV. OF THE UNITED KINGDOM OF GREAT BRITAIN AND NORTHERN IRELAND , STC PLC
发明人： GRAY, George, William , LACEY, David , TOYNE, Kenneth, Johnson , COATES, David , JACKSON, Adam , SCROWSTON, Richard, Michael
CPC分类号： C09K19/2028 , C09K19/126 , C09K19/2021 , C09K19/32
摘要： Novel compounds suitable for use as components of a ferroelectric smectic liquid crystal composition, which contain two or more chiral centers derived from optically active alpha-hydroxy carboxylic acids, secondary alcohols, and terpenoid alcohols. These units are combined with a mesogenic combination of cyclic groups. Preferred compounds contain two or more lactate groups, lactate and 2-octyl groups, or lactate and terpenoid groups in combination with phenyl groups. Ferroelectric smectic liquid compositions containing these compounds, and a device using them are also described.
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4.发明授权ALPHA-HYDROXY CARBOXYLIC ACID DERIVATIVES SUITABLE FOR USE IN LIQUID CRYSTAL MATERIALS AND DEVICES 失效适用于液晶材料和器件的ALPHA-羟基羧酸衍生物
公开(公告)号：EP0201578B1
公开(公告)日：1989-11-02
申请号：EP85905852.1
申请日：1985-11-08
申请人： Secretary of State for Defence in Her Britannic Majesty's Gov. of the United Kingdom of Great Britain and Northern Ireland , STC PLC
发明人： CHAN, Lawrence, Kam, Ming 112 Lee Street , COATES, David , GEMMELL, Peter, Alan 71 The Knoll , GRAY, George, William Glenwood , LACEY, David , TOYNE, Kenneth, Johnson , YOUNG, Daniel, James, Stephen 2 York Way
CPC分类号： C09K19/586 , C09K19/126 , C09K19/2028 , C09K19/3068 , C09K19/42 , C09K19/50
摘要： Compounds which may be used as a dopant or host in a ferroelectric chiral smectic liquid crystal mixture. The compounds are characterised in that they are derivatives of an X-hydroxy carboxylic acid and contain the chiral unit (I), in which Ro may be alkyl, alkoxy, halogen, formula (II), where b may be 0 to 3 and the phenyl ring may be substituted, and a is 0 or 1. The chiral unit is combined with a range of mesogenic combinations of groups. Lactic acid derivatives are described in detail (i.e. Ro = methyl) together with various preparative routes, for example the compound formula (III), which has dopant properties in a range of hosts.
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公开(公告)号：EP0201554B1
公开(公告)日：1989-02-08
申请号：EP85905639.2
申请日：1985-11-08
申请人： Secretary of State for Defence in Her Britannic Majesty's Gov. of the United Kingdom of Great Britain and Northern Ireland , STC PLC
发明人： BONE, Matthew, Francis 47 Newtown Road , JACKSON, Adam , CHAN, Lawrence, Kam, Ming 112 Lee Street , COATES, David , GEMMELL, Peter, Alan , GRAY, George, William , LACEY, David , TOYNE, Kenneth, Johnson , YOUNG, Daniel, James, Stephen 2 York Way , SCROWSTON, Richard, Michael 11 Saunders Croft
CPC分类号： C09K19/2028 , C09K19/126 , C09K19/2021 , C09K19/22 , C09K19/3001 , C09K19/3068 , C09K19/32 , C09K19/42 , C09K19/50 , C09K2019/3095
摘要： Ferroelectric smectic liquid crystal mixtures are provided consisting of two constituents; a smectic host and another containing a chiral compound in which rotation of the chiral centre relative to the molecular core is sterically hindered, so that the chiral compound induces a high Ps in the mixture. A preferred class of chiral compounds is those derived from naturally occurring compounds with chiral groups, especially alpha-hydroxycarboxylic acids, amino acids and terpenoids, e.g. with chiral groups (I), (II), (III). The chiral group is incorporated into a compound containing a mesogenic combination of groups, e.g. with chains of cyclic groups and some mesogenic combinations are described.
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公开(公告)号：EP0486646B1
公开(公告)日：1998-01-07
申请号：EP91910766.4
申请日：1991-06-11
发明人： MCDONNELL, Damien Gerard , DAY, Sally Elizabeth , COATES, David , JENNER, John Anthony , HIRD, Michael John, Liquid Cristal Group , TOYNE, Kenneth Johnson, Liquid Cristal Group
IPC分类号： C07C323/62 , C09K19/12 , C09K19/18 , C09K19/30 , C09K19/34 , C07D213/84 , C07D239/28 , C07D319/06 , C07C323/20 , C07C321/28
CPC分类号： C07C323/62 , C09K19/12 , C09K19/18 , C09K19/3003 , C09K19/3059 , C09K19/3402 , C09K19/3441 , C09K2019/3422
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公开(公告)号：EP0440643B1
公开(公告)日：1997-09-03
申请号：EP89907213.6
申请日：1989-06-09
发明人： COATES, David , SAGE, Ian , GREENFIELD, Simon , GRAY, George, William , LACEY, David , TOYNE, Kenneth, Johnson , CHAN, Lawrence, Kam, Ming , HIRD, Michael
IPC分类号： C07C255/54 , C09K19/12 , C07C255/56
CPC分类号： C07C255/50 , C09K19/12
摘要： Fluorinated 4''-cyano substituted terphenyls of general formula (I), wherein R1 is selected from alkenyl, H, R, RO and RCO where R is alkyl or perfluoroalkyl containing up to 12 carbon atoms, n is 1, 2 or 3 and the lateral fluorosubstituent(s) may be in any of of the available substitution positions are provided. These have liquid crystalline properties and may be used as components of liquid crystal materials.
摘要翻译： 其中R1选自链烯基，H，R，RO和RCO的氟化4“ - 氰基取代的三联苯，其中R是含有至多12个碳原子的烷基或全氟烷基，n是1,2或3，和 可以提供侧向氟取代基处于任何可用的取代位置。 它们具有液晶性，可以用作液晶材料的成分。
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8.发明授权LIGHT MODULATING MATERIAL COMPRISING POLYMER DISPERSED LIQUID CRYSTALS 失效材料用于光调制的含液体晶体POLYMERDISPERSIERTE
公开(公告)号：EP0505448B1
公开(公告)日：1997-04-23
申请号：EP91901304.5
申请日：1990-12-13
发明人： COATES, David
IPC分类号： C09K19/00 , C09K19/12 , G02F1/1333
CPC分类号： C09K19/12 , C09K19/544
摘要： A light modulating material is disclosed, comprising a solid, light transmissive, polymeric matrix having dispersed within said matrix droplets of a liquid crystalline composition, wherein said composition is a mixture of at least 2 compounds, at least one of said compounds having general formula (I), where n is 1 or 2, the fluorine substituent(s) may be in any of the available substitution positions and R1 is C¿1-12? alkynyl, hydrogen, R, RO or RCO where R is alkyl or perfluoroalkyl and at least one other of said compounds having general formula (II), where m is 0 or 1 and R?2¿ is hydrogen or C¿1-12? alkyl or alkoxy.
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9.发明授权CYANOHYDRIN DERIVATIVES AND THEIR USE IN LIQUID CRYSTAL MATERIALS AND DEVICES 失效氰基衍生物及其在液晶材料和器件中的应用
公开(公告)号：EP0391956B1
公开(公告)日：1993-04-21
申请号：EP89900631.6
申请日：1988-12-15
申请人： Secretary of State for Defence in Her Britannic Majesty's Gov. of the United Kingdom of Great Britain and Northern Ireland , SAGE, Ian Charles
CPC分类号： C09K19/2021 , C07C255/16 , C07C2601/12 , C09K19/126 , C09K19/322 , C09K2019/123
摘要： Novel cyanohydrin derivatives of general formula (I) wherein R1 is hydrogen, alkyl, alkoxy, perfluoroalkyl or perfluoroalkoxy, R2 is alkyl, r is 1 to 10, n and m are 0 or 1, provided if both n and m are 0 then X is (II) or (III), where (F) indicates one or more optional fluorines, p is 0 or 1, Z is a single bond if p is 0 and COO if p is 1; and if one or both of n or m are 1 then X is (IV), where each ring A, B and C is phenyl, fluoro- or chloro-phenyl, cyclohexyl, pyrimidyl, pyridyl, or dioxanyl, A, B and C are single bonds or linking groups, and (a + b + c) is 2 or 3. Liquid crystal materials containing these compounds are also described.
摘要翻译： 通式（I）的新型羟腈衍生物，其中R 1为氢，烷基，烷氧基，全氟烷基或全氟烷氧基，R 2为烷基，r为1至10，n和m为0或1，条件是如果n 且m为0，则X为（II）或（III），其中（F）表示一个或多个任选的氟，p为0或1，如果p为0，则Z为单键，如果p为1，则Z为单键; 并且如果n或m中的一个或两个为1，则X为（IV），其中每个环A，B和C为苯基，氟或氯 - 苯基，环己基，嘧啶基，吡啶基或二恶烷基，A，B和C 是单键或连接基团，（a + b + c）是2或3.也描述了含有这些化合物的液晶材料。
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10.发明公开TERPENOID DERIVATIVES AND LIQUID CRYSTAL MATERIALS AND DEVICES CONTAINING THEM 失效基于铁电Terpenoidderivaten近晶相液晶材料。
公开(公告)号：EP0211030A1
公开(公告)日：1987-02-25
申请号：EP86900815.0
申请日：1986-01-24
申请人： The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and , STC PLC
发明人： COATES, David , GRAY, George, William , LACEY, David , YOUNG, Daniel, James, Stephen , TOYNE, Kenneth, Johnson , BONE, Matthew, Francis
CPC分类号： C07D239/26 , C09K19/126 , C09K19/2021 , C09K19/2028 , C09K19/22 , C09K19/3001 , C09K19/32 , C09K19/42 , C09K19/50 , C09K19/58 , C09K19/586 , C09K2019/3095
摘要： Nouveaux dérivés d'alcools de terpénoïdes cycliques et acycliques ayant la formule (I) X-(CO)nO-T1, où n = O ou 1, T1 est un groupe de terpénoïdes et X est une combinaison de groupes cycliques, par ex. phényle, cyclohexyle et pyrimidyle. X contient de préférence jusqu'à trois groupes cycliques. Des dérivés préférés sont des esters d'alcools de terpénoïdes cycliques, par ex. menthol, borneol et isopinéocampheol, par ex. formule (II) (-)-menthol. Des mélanges et dispositifs à cristaux liquides smectiques ferroélectriques contenant ces dérivés sous forme de dopants de chiralité dans un hôte smectique renversé sont également décrits. Les propriétés de divers autres dérivés d'alcools de terpénoïdes de formule (I) sont aussi écrites, par ex. celles de néomenthol, isolongifolol, fenchol, carvéol, myrthénol, nopol, citronellol, alcool de perilla et dihydrocitronellol.
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