METHOD FOR PREPARING 1,3-BUTADIENE FROM NORMAL BUTENE BY USING CONTINUOUS-FLOW DUAL-BED REACTOR
    2.
    发明公开
    METHOD FOR PREPARING 1,3-BUTADIENE FROM NORMAL BUTENE BY USING CONTINUOUS-FLOW DUAL-BED REACTOR 有权
    用于制备1,3-丁二烯FROM NORMALBUTEN使用双床反应器具有连续流动

    公开(公告)号:EP2256101A2

    公开(公告)日:2010-12-01

    申请号:EP09724254.9

    申请日:2009-02-09

    IPC分类号: C07C5/32

    摘要: The present invention relates to a method of producing 1,3-butadiene by the oxidative dehydrogenation of n-butene using a continuous-flow dual-bed reactor designed such that two kinds of catalysts charged in a fixed-bed reactor are not physically mixed. More particularly, the present invention relates to a method of producing 1,3-butadiene by the oxidative dehydrogenation of n-butene using a C4 mixture including n-butene and n-butane as reactants and using a continuous-flow dual-bed reactor in which a multi-component bismuth molybdate catalyst and a zinc ferrite catalyst having different reaction activity in the oxidative dehydrogenation reaction of n-butene isomers (1-butene, trans-2-butene, cis-2-butene).

    摘要翻译: 本发明涉及一种通过使用连续流的双重床反应器设计的搜索做了两种固定床反应器装入催化剂是不物理混合正丁烯的氧化脱氢制备1,3-丁二烯的方法。 更具体地,本发明涉及使用C4混合物包含正丁烯和正丁烷作为反应物通过正丁烯的氧化脱氢制备1,3-丁二烯和使用一式连续流动床反应器的方法 其中的多组分钼酸铋催化剂和具有正丁烯异构体(1-丁烯,反式-2-丁烯,顺式-2-丁烯)的氧化脱氢反应不同的反应活性的铁酸锌催化剂。