公开(公告)号：EP2256101A2

公开(公告)日：2010-12-01

申请号：EP09724254.9

申请日：2009-02-09

申请人： SK Energy Co., Ltd. ,  SNU R&DB Foundation

发明人： CHUNG, Young Min ,  KWON, Yong Tak ,  KIM, Tae Jin ,  LEE, Seong Jun ,  KIM, Yong Seung ,  OH, Seung Hoon ,  SONG, In Kyu ,  KIM, Hee Soo ,  JUNG, Ji Chul ,  LEE, Ho Won

IPC分类号： C07C5/32

CPC分类号： C07C5/42 ,  C07C2523/80 ,  C07C2523/887 ,  C07C11/167

摘要： The present invention relates to a method of producing 1,3-butadiene by the oxidative dehydrogenation of n-butene using a continuous-flow dual-bed reactor designed such that two kinds of catalysts charged in a fixed-bed reactor are not physically mixed. More particularly, the present invention relates to a method of producing 1,3-butadiene by the oxidative dehydrogenation of n-butene using a C4 mixture including n-butene and n-butane as reactants and using a continuous-flow dual-bed reactor in which a multi-component bismuth molybdate catalyst and a zinc ferrite catalyst having different reaction activity in the oxidative dehydrogenation reaction of n-butene isomers (1-butene, trans-2-butene, cis-2-butene).

摘要翻译： 本发明涉及一种通过使用连续流的双重床反应器设计的搜索做了两种固定床反应器装入催化剂是不物理混合正丁烯的氧化脱氢制备1,3-丁二烯的方法。 更具体地，本发明涉及使用C4混合物包含正丁烯和正丁烷作为反应物通过正丁烯的氧化脱氢制备1,3-丁二烯和使用一式连续流动床反应器的方法 其中的多组分钼酸铋催化剂和具有正丁烯异构体（1-丁烯，反式-2-丁烯，顺式-2-丁烯）的氧化脱氢反应不同的反应活性的铁酸锌催化剂。

公开(公告)号：EP2256101B1

公开(公告)日：2015-08-26

申请号：EP09724254.9

申请日：2009-02-09

申请人： SK Innovation Co., Ltd. ,  SNU R&DB Foundation

发明人： CHUNG, Young Min ,  KWON, Yong Tak ,  KIM, Tae Jin ,  LEE, Seong Jun ,  KIM, Yong Seung ,  OH, Seung Hoon ,  SONG, In Kyu ,  KIM, Hee Soo ,  JUNG, Ji Chul ,  LEE, Ho Won

IPC分类号： C07C5/32

CPC分类号： C07C5/42 ,  C07C2523/80 ,  C07C2523/887 ,  C07C11/167

公开(公告)号：EP2190568A2

公开(公告)日：2010-06-02

申请号：EP08778783.4

申请日：2008-07-14

申请人： Korea Research Institute Of Chemical Technology ,  Daelim Industrial Co., Ltd. ,  Doosan Mecatec Co., Ltd. ,  Korea National Oil Corporation ,  Hyundai Engineering Co., Ltd. ,  SK Energy Co., Ltd.

发明人： JUN, Ki-won ,  SONG, In Kyu ,  CHO, Kyung min ,  PARK, Sunyoung ,  BAECK, Sung-Hyeon

IPC分类号： B01J8/04 ,  C07C1/04

CPC分类号： B01J8/0457 ,  B01J8/0492 ,  B01J8/0496 ,  B01J23/75 ,  B01J23/755 ,  B01J29/0333 ,  B01J37/0201 ,  C10G2/32 ,  C10G2/332 ,  C10G47/14 ,  C10G69/02

摘要： The present invention relates to a process of preparing liquid-phase hydrocarbon mixture, which comprises continuously conducting Fischer-Tropsch synthesis reaction in the upper part and hydrocracking reaction in the lower part by using a continuous-flow dual-bed reactor which comprises two fixed-bed reactors filled with catalysts and continuously placed in upper and lower parts and a hydrogen-supplying pipe between the upper and the lower fixed-bed reactors and continuously supplying hydrogen in the lower fixed-bed reactor, thereby remarkably increasing the yield of C
10 -C
20 liquid-phase hydrocarbon mixture as compared to the conventional Fischer-Tropsch synthesis reaction.

摘要翻译： 本发明涉及制备液相烃混合物，其包括连续地使用连续流的双重床反应器，其包括两个固定翼传导​​在下部的上部和加氢裂化反应的费 - 托合成反应的过程 填充有催化剂和连续布置在上部和下部与上部和下部的固定床反应器，并在较低的固定床反应器中连续供给氢气之间的氢供给管床反应器，从而显着地提高C10-C20的产率 液相烃混合物作为相比于常规费 - 托合成反应。

公开(公告)号：EP2219782A2

公开(公告)日：2010-08-25

申请号：EP08859263.9

申请日：2008-11-07

申请人： SK Energy Co., Ltd.

发明人： CHUNG, Young Min ,  KWON, Yong Tak ,  LEE, Seong Jun ,  KO, Min Su ,  KIM, Yong Seung ,  SONG, In Kyu ,  KIM, Tae Jin ,  OH, Seung Hoon

IPC分类号： B01J23/84

CPC分类号： B01J23/8892 ,  B01J23/002 ,  B01J23/80 ,  B01J35/002 ,  B01J37/031 ,  B01J2523/00 ,  C07C5/48 ,  C07C2523/06 ,  C07C2523/34 ,  C07C2523/745 ,  C07C2523/80 ,  C07C2523/889 ,  C07C11/167 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/27

摘要： The present invention provides a method of producing a mixed manganese ferrite catalyst, and a method of preparing 1,3 -butadiene using the mixed manganese ferrite catalyst. Specifically, the present invention provides a method of producing a mixed manganese ferrite catalyst through a coprecipitation method which is performed at a temperature of 10 ~ 40 °C, and to a method of preparing 1,3 -butadiene using the mixed manganese ferrite catalyst through an oxidative dehydrogenation reaction, in which a C4 mixture containing n-butene, n-butane and other impurities is directly used as reactants without performing additional n-butane separation process or n-butene extraction. The present invention is advantageous in that 1,3-butadiene can be prepared directly using a C4 mixture including n-butane at a high concentration as a reactant through an oxidative hydrogenation reaction without performing an additional n-butane separation process, and 1,3-butadiene, having high activity, can be also obtained in high yield for a long period of time.

公开(公告)号：EP2197578A1

公开(公告)日：2010-06-23

申请号：EP08793495.6

申请日：2008-08-26

申请人： SK Energy Co., Ltd.

发明人： CHUNG, Young Min ,  KIM, Tae Jin ,  LEE, Seong Jun ,  KIM, Yong Seung ,  OH, Seung Hoon ,  SONG, In Kyu ,  KIM, Hee Soo ,  JUNG, Ji Chul ,  LEE, Ho Won

IPC分类号： B01J23/84

CPC分类号： B01J23/8876 ,  B01J23/002 ,  B01J23/8898 ,  B01J37/03 ,  B01J2523/00 ,  C07C5/48 ,  C07C2523/887 ,  C07C11/167 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/27 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/22 ,  B01J2523/17

摘要： This invention relates to a method of preparing multicomponent bismuth molybdate catalysts composed of four metal components and a method of preparing 1,3 -butadiene using the catalyst, and particularly, to multicomponent bismuth molybdate catalysts composed of a divalent cationic metal, a trivalent cationic metal, bismuth and molybdenum, a preparation method thereof, and a method of preparing 1,3-butadiene from a C4 mixture including n-butene and n-butane using oxidative dehydrogenation. According to this invention, it is possible to prepare catalysts having high activity for the preparation process of 1,3-butadiene only using four metal components as shown through systematic investigation of types and ratios of metal components, unlike conventional multicomponent metal oxide catalysts having a complicated composition of metal components.