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    Thermoplastic resin composition and injection-molded article thereof
    1.
    发明公开
    Thermoplastic resin composition and injection-molded article thereof 失效
    Thermoplastische Harzzusammensetzung und Spritzgussfaserteile daraus。

    公开(公告)号：EP0580069A1

    公开(公告)日：1994-01-26

    申请号：EP93111287.4

    申请日：1993-07-14

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED ,  TOYOTA JIDOSHA KABUSHIKI KAISHA

    发明人： Abe, Hiroomi ,  Fujii, Takeshi ,  Yamamoto, Masashi ,  Nishio, Takeyoshi ,  Nomura, Takao

    IPC分类号： C08L53/00

    CPC分类号： C08L53/00 ,  C08L2666/02

    摘要： A thermoplastic resin composition which contains a resin composition containing a crystalline polypropylene component, an ethylene-butene-1 copolymer rubber and an ethylene-propylene copolymer rubber; a modified polypropylene; a saturated polyester resin; and an epoxy group-containing copolymer; and optionally talc exhibits high low-temperature impact strength, stiffness and Rockwell hardness and a small coefficient of linear expansion, which composition gives an injection-molded article suitably used for a bumper for automobile.

    摘要翻译： 一种含有结晶聚丙烯组分，乙烯 - 丁烯-1共聚物橡胶和乙烯 - 丙烯共聚物橡胶的树脂组合物的热塑性树脂组合物; 改性聚丙烯; 饱和聚酯树脂; 和含环氧基的共聚物; 并且任选的滑石显示出高的低温冲击强度，刚度和洛氏硬度和较小的线膨胀系数，该组合物给出适合用于汽车保险杠的注塑制品。

    Surface treating of polyphenylene ether thermoplastic shaped articles
    7.
    发明公开
    Surface treating of polyphenylene ether thermoplastic shaped articles 失效
    Oberflächenbehandlungeines geformten thermoplastischenPolyphenenäthergegenstandstand。

    公开(公告)号：EP0447239A2

    公开(公告)日：1991-09-18

    申请号：EP91302177.0

    申请日：1991-03-14

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Abe, Hiroomi ,  Shinonaga, Hideo ,  Kitadono, Kaoru ,  Suzuki, Yasuro ,  Sogabe, Satoru

    IPC分类号： B29C59/16 ,  C08L71/00

    CPC分类号： B29C59/16 ,  B05D3/063 ,  B29C59/005 ,  B29K2071/00 ,  C08L67/00 ,  C08L71/123 ,  C08L77/00 ,  C08L2666/02

    摘要： A composition is prepared of, by wt, (I) 100 parts of a mixture of 5 to 100% of a polyphenylene ether or a mixture thereof with a styrene polyester, or a graft copolymer thereof and styrene and (b) 95 to 0% of a thermoplastic polyamide and/or saturated polyester resin; and optionally (II) 0 to 50 parts of a rubbery substance; (III) 0 to 50 parts of inorganic filler and/or glass fibers; and (IV) 0 to 10 parts of at least one of seven types of compatibilizer which improves compatibility of the polymers (I) (a) and (b).
    The production of these components is described.
    The components are mixed in any order and molded. The surface of the molded article, e.g. a film, plate or fibers, may be degreased and is irradiated with ultraviolet light of wavelength less than 300 nm, preferably 185 and 254 nm as main wavelengths, for 20 seconds to 10 minutes: The irradiation improves the coatability of the surface, which may then be coated with a coating of an alkyd-melamine or an acrylic urethane.

    摘要翻译： 制备（I）100份5-100％聚苯醚或其与苯乙烯聚酯或其接枝共聚物和苯乙烯的混合物的混合物的组合物，和（b）95至0％ 的热塑性聚酰胺和/或饱和聚酯树脂; 和任选的（II）0至50份橡胶状物质; （III）0〜50份无机填料和/或玻璃纤维; 和（IV）0至10份改善聚合物（I）（a）和（b）的相容性的七种增容剂中的至少一种。 描述了这些部件的生产。 组分以任何顺序混合并成型。 模制品的表面，例如， 薄膜，板或纤维可以脱脂，并用波长小于300nm，优选185和254nm的紫外线作为主要波长照射20秒至10分钟。照射改善了表面的可涂覆性， 然后涂覆醇酸三聚氰胺或丙烯酸聚氨酯的涂层。

    Thermoplastic resin composition
    8.
    发明公开
    Thermoplastic resin composition 失效
    热塑性树脂组合物

    公开(公告)号：EP0435504A2

    公开(公告)日：1991-07-03

    申请号：EP90313421.1

    申请日：1990-12-11

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Abe, Hiroomi ,  Nagaoka, Kenji ,  Nishio, Taichi ,  Shinonaga, Hideo ,  Sanada, Takashi

    IPC分类号： C08L71/12 ,  C08L77/00 ,  C08K5/00 ,  C08K5/3492 ,  C08L25/08

    CPC分类号： C08L71/123 ,  C08K5/18 ,  C08K5/315 ,  C08K5/3412 ,  C08K5/34922 ,  C08L77/00 ,  Y10S525/905 ,  C08L2666/02

    摘要： The present invention provides a thermoplastic resin composition which comprises:

    (i) at least one compatibilizing agent in an amount effective for compatibilization,
    (ii) (A) a polyphenylene ether in an amount of about 40 - 100% by weight based on the total amount of (A) and (B) and
    (B) a homopolymer of alkenyl aromatic compound or a random copolymer of alkenyl aromatic compound and unsaturated compound in an amount of 0-about 60% by weight based on the total amount of (A) and (B), the total amount of (A) and (B) being about 10% by weight or more based on total amount of all polymer components,
    (iii) at least one polyamide in an amount more than the amount required for forming a continuous phase, and
    (iv) a compound having a molecular weight of 2,000 or less, containing nitrogen element, and having ring opening or condensation polymerizability or reactivity with acid or amine.

    摘要翻译： 本发明提供了一种热塑性树脂组合物，其包含：（i）至少一种有效增容量的相容剂，（ii）（A）聚苯醚，其量为总量的约40-100重量％ （A）和（B）的总量为0〜约60重量％的量的（A）和（B）和（B）链烯基芳族化合物的均聚物或链烯基芳族化合物与不饱和化合物的无规共聚物， 和（B）中，（A）和（B）的总量基于全部聚合物组分的总量为约10重量％以上，（iii）至少一种聚酰胺的量大于形成所需的量 （iv）分子量等于或小于2000的化合物，其含有氮元素，并且具有开环或缩合聚合性或与酸或胺的反应性。

    Thermoplastic resin composition
    9.
    发明公开
    Thermoplastic resin composition 失效
    热塑性树脂组合物

    公开(公告)号：EP0394055A2

    公开(公告)日：1990-10-24

    申请号：EP90304238.0

    申请日：1990-04-20

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Abe, Hiroomi ,  Nishio, Taichi ,  Sanada, Takashi ,  Kawaga, Noriyasu

    IPC分类号： C08L71/12 ,  C08L77/00 ,  C08K5/09

    CPC分类号： C08L71/123 ,  C08L63/00 ,  C08L77/00 ,  C08L2666/02 ,  C08L2666/24

    摘要： A novel thermoplastic composition having improved paint adhesion strength comprising,

    A) from about 5 to 95 weight % of at least one polyphenylene ether.
    B) from about 95 to 5 weight % of at least one polyamide,
    C) paint adhesion improving amount of at least one paint adhesion improver selected from the class consisting of

    a) homopolymers or copolymers of unsaturated nitrile compounds and
    b) homopolymers or copolymers of alkyl (meth)­acrylate, excluding an ethylene alkylacrylate copolymer having about 50 weight % or higher of ethylene,

    D) from about 0.01 to 30 parts by weight of at least one compatibilizer, based on 100 by weight of the total of the polyphenylene ether and polyamide.

    摘要翻译： 一种具有改进的漆粘合强度的新型热塑性组合物，其包含：A）约5-95重量％的至少一种聚苯醚。 B）约95-5重量％的至少一种聚酰胺，C）油漆粘合改进量的至少一种油漆粘合改进剂，所述油漆粘合改进剂选自a）不饱和腈化合物的均聚物或共聚物，和b）不饱和腈化合物的均聚物或共聚物 （甲基）丙烯酸烷基酯，不包括具有约50重量％或更高乙烯的乙烯烷基丙烯酸酯共聚物，D）基于100重量份的聚苯醚和约0.01-30重量份的至少一种增容剂和 聚酰胺。

    Thermoplastic resin composition
    10.
    发明公开
    Thermoplastic resin composition 失效
    Thermoplastische Harzzusammensetzung。

    公开(公告)号：EP0381390A2

    公开(公告)日：1990-08-08

    申请号：EP90300841.5

    申请日：1990-01-26

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Abe, Hiroomi ,  Nishio, Taichi ,  Suzuki, Yasurou ,  Tsuji, Mitsuji ,  Sanada, Takashi

    IPC分类号： C08L71/12 ,  C08L77/00 ,  C08L51/04

    CPC分类号： C08L71/123 ,  C08L51/04 ,  C08L63/00 ,  C08L71/12 ,  C08L77/00 ,  C08L2666/14 ,  C08L2666/22 ,  C08L2666/02 ,  C08L2666/24

    摘要： A thermoplastic resin composition which comprises:

    (A) 100 parts by weight of:
    (i) a resin composition comprising 5-95% by weight of a polyphenylene ether obtainable by oxidation polymerisation of at least one phenol compound represented by the formula:
    wherein R¹, R², R³, R⁴ and R⁵, which may be identical or different, each represents a hydrogen atom, a halogen atom or a substituted or unsubstituted hydrocarbon group, and at least one of R¹ to R⁵ is a hydrogen atom, or
    (ii) a polyphenylene ether-based resin composition comprising said polyphenylene ether and a polystyrene, and
    95-5% by weight of a polyamide resin;
    (B) 5 - 50 parts by weight of a saturated rubber obtainable by grafting 5 - 100 parts by weight of an aromatic vinyl compound onto 100 parts by weight of a saturated rubber and allowing 0.05 - 10 parts by weight of a compatibilising agent to react with said rubber, the grafting degree of said aromatic vinyl compound being 50% by weight or more; and
    (C) 0.05 - 20 parts by weight of a compatibilising agent.

    摘要翻译： 一种热塑性树脂组合物，其包含：（A）100重量份：（i）包含5-95重量％的聚苯醚的树脂组合物，其可通过至少一种由下式表示的酚化合物的氧化聚合获得：