摘要:
A solid oxide fuel cell (SOFC) includes a plurality of subassemblies. Each subassembly includes at least one subcell of a first electrode, a second electrode and an electrolyte between the first and second electrodes. A first bonding layer is at the second electrode and an interconnect layer is at the first bonding layer distal to the electrolyte. A second bonding layer that is compositionally distinct from the first bonding layer is at the interconnect layer, whereby the interconnect partitions the first and second bonding layers. A method of fabricating a fuel cell assembly includes co-firing at least two subassemblies using a third bonding layer that is microstructurally or compositionally distinct from the second bonding layer.
摘要:
A solid oxide fuel cell includes an anode layer, an electrolyte layer over a surface of the anode layer, and a cathode layer over a surface of the electrolyte layer. The cathode layer includes a cathode bulk layer, a porous cathode functional layer at an electrolyte, an intermediate cathode layer partitioning the cathode bulk layer and the porous cathode functional layer, the porous intermediate cathode layer having a porosity greater than that of the cathode bulk layer. The solid oxide fuel cells can be combined to form subassemblies that are bonded together to form solid oxide fuel cell assemblies.
摘要:
A solid oxide fuel cell includes an anode layer, a cathode layer, and an electrolyte layer partitioning the anode layer and the cathode layer. The anode layer and the cathode layer are of about the same thickness and have about the same coefficient of thermal expansion (CTE).
摘要:
A solid oxide fuel cell electrolyte is fabricated by combining an yttria- stabilized zirconia powder with α- Al 2 O 3 having a d 5o particle size in a range of between about 10 nm and about 200 nm and Mn 2 O 3 to form an electrolyte precursor composition, and then sintering the electrolyte precursor composition to thereby form the electrolyte. The α- Al 2 O 3 and Mn 2 O 3 can be present in the electrolyte precursor composition in an amount in a range of between about 0.25 mol% and about 5 mol%. The electrolyte can be a component of a solid oxide fuel cell of the invention.
摘要翻译:固体氧化物燃料电池电解质通过将氧化钇稳定的氧化锆粉末与具有约10nm至约200nm范围内的50μm粒径的α-Al 2 O 3和Mn 2 O 3组合以形成电解质前体组合物, 然后烧结电解质前体组合物从而形成电解质。 α-Al 2 O 3和Mn 2 O 3可以以约0.25mol%至约5mol%的量存在于电解质前体组合物中。 电解质可以是本发明的固体氧化物燃料电池的组件。
摘要:
The present disclosure relates to solid oxide fuel cells, and particularly raw powder materials which form a layer in a solid oxide fuel. The raw powder materials include an ionic conductor powder material; and an electronic conductor powder material. The ratio of an average particle diameter of the ionic conductor powder material to an average particle diameter of the electronic conductor powder material is greater than about 1:1, and an average particle diameter of at least one of the electronic conductor powder material or the ionic conductor powder material is coarse.
摘要:
An interconnect of a solid oxide fuel cell article is disclosed. The interconnect is disposed between a first electrode and a second electrode of the solid oxide fuel cell article. The interconnect comprises a first phase including a ceramic interconnect material and a second phase including partially stabilized zirconia. The partially stabilized zirconia may be in a range of between about 0.1 vol % and about 70 vol % of the total volume of the interconnect.
摘要:
An interconnect material is formed by combining a lanthanum-doped strontium titanate with an aliovalent transition metal to form a precursor composition and sintering the precursor composition to form the interconnect material. The aliovalent transition metal can be an electron-acceptor dopant, such as manganese, cobalt, nickel or iron, or the aliovalent transition metal can be an electron-donor dopant, such as niobium or tungsten. A solid oxide fuel cell, or a strontium titanate varistor, or a strontium titanate capacitor can include the interconnect material that includes a lanthanum-doped strontium titanate that is further doped with an aliovalent transition metal.
摘要:
An interconnect of a solid oxide fuel cell article is disclosed. The interconnect is disposed between a first electrode and a second electrode of the solid oxide fuel cell article. The interconnect comprises a first phase including a ceramic interconnect material and a second phase including partially stabilized zirconia. The partially stabilized zirconia may be in a range of between about 0.1 vol % and about 70 vol % of the total volume of the interconnect.
摘要:
A glass-ceramic seal for ionic transport devices such as solid oxide fuel cell stacks or oxygen transport membrane applications. Preferred embodiments of the present invention comprise glass-ceramic sealant material based on a Barium-Aluminum-Silica system, which exhibits a high enough coefficient of thermal expansion to closely match the overall CTE of a SOFC cell/stack (preferably from about 11 to 12.8 ppm/° C.), good sintering behavior, and a very low residual glass phase (which contributes to the stability of the seal).
摘要:
The present disclosure relates to solid oxide fuel cells, and particularly raw powder materials which form a layer in a solid oxide fuel. The raw powder materials include an ionic conductor powder material; and an electronic conductor powder material. The ratio of an average particle diameter of the ionic conductor powder material to an average particle diameter of the electronic conductor powder material is greater than about 1:1, and an average particle diameter of at least one of the electronic conductor powder material or the ionic conductor powder material is coarse.