公开(公告)号：EP1712522A1

公开(公告)日：2006-10-18

申请号：EP05008172.8

申请日：2005-04-14

申请人： Schlögl, Robert, Prof. Dr. ,  Sharifah Bee Binti O A Abd Hamid, Prof. Dr.

发明人： Schlögl, Robert, Prof. Dr. ,  Sharifah Bee Binti O A Abd Hamid, Prof. Dr.

IPC分类号： C01B31/02 ,  D01F9/127 ,  B01J21/18

CPC分类号： D01F9/127 ,  B01J21/18 ,  B01J23/745 ,  B01J23/755 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C02F1/283 ,  C02F1/288 ,  C02F2101/20 ,  C02F2101/308 ,  C02F2103/02 ,  C02F2303/02 ,  C02F2303/18 ,  C02F2305/08 ,  Y10T428/25 ,  Y10T428/30

摘要： The present invention relates to carbon-carbon composite material comprising a carbonaceous carrier and nanosize carbon structures (e.g. CNT or CNF), wherein the nanosize carbon structures are grown on the carbonaceous carrier. The carrier may be porous, as in activated carbon or consists of carbon black particles. In accordance with the invention, nanocarbon growth in the pores of porous carriers can be realized.
The process for the manufacture of a this carbon-carbon-composite material comprises the steps of treating a carbonaceous carrier material with a metal-containing catalyst material, said metal being capable of forming nanosize carbon structures, and growing nanosize carbon structures by means of a CVD (chemical vapour deposition) method on the treated carrier in a gas atmosphere comprising a carbon-containing gas, followed by an optional surface modification step. This process allows optimising porosity, hydrodynamical properties and surface chemistry independently from each other, which is particularly beneficial in respect of the use of the composite for water purification. Carbon black-based composites are particularly useful for filler applications.

摘要翻译： 本发明涉及包含碳载体和纳米尺寸碳结构（例如CNT或CNF）的碳 - 碳复合材料，其中纳米尺度碳结构在碳质载体上生长。 载体可以是多孔的，如在活性炭中或由炭黑颗粒组成。 根据本发明，可以实现多孔载体的孔中的纳米碳生长。 制造这种碳 - 碳复合材料的方法包括以下步骤：用含金属的催化剂材料处理含碳载体材料，所述金属能够形成纳米尺度的碳结构，并通过以下方式生长纳米尺度的碳结构 在包含含碳气体的气体气氛中处理的载体上的CVD（化学气相沉积）方法，随后是任选的表面改性步骤。 该方法允许彼此独立地优化孔隙率，流体动力学性质和表面化学性质，这在复合材料用于水净化方面是特别有利的。 碳黑基复合材料对于填料应用特别有用。

公开(公告)号：EP1930074A1

公开(公告)日：2008-06-11

申请号：EP06025439.8

申请日：2006-12-08

申请人： Schlögl, Robert, Prof. Dr. ,  Trunschke, Annette, Dr.

发明人： Schlögl, Robert, Prof. Dr. ,  Trunschke, Annette, Dr.

IPC分类号： B01J23/28 ,  B01J27/057 ,  B01J29/03 ,  C07C51/215 ,  B01J35/10 ,  B01J37/03

CPC分类号： B01J29/0308 ,  B01J23/002 ,  B01J23/28 ,  B01J27/0576 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/033 ,  B01J2523/00 ,  C01G39/006 ,  C01P2002/72 ,  C01P2002/85 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2006/16 ,  C01P2006/17 ,  C04B35/495 ,  C04B2235/3229 ,  C04B2235/3239 ,  C04B2235/3241 ,  C04B2235/3244 ,  C04B2235/3251 ,  C04B2235/3256 ,  C04B2235/3258 ,  C04B2235/3262 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3279 ,  C04B2235/3286 ,  C04B2235/3289 ,  C04B2235/3294 ,  C04B2235/3298 ,  C04B2235/449 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

摘要： The present invention relates to novel mesoporous mixed metal oxide catalysts and a method for the preparation thereof, as well as the use thereof as a catalyst in the oxidation of hydrocarbons or partially oxidized hydrocarbons. More specifically, the present invention relates to mesoporous mixed metal oxide catalysts comprising at least two, preferably at least three different metal species, at least one of which belongs to the group of transition metals, a method for the preparation thereof, which comprises a production step over the neutral templating route and a calcination step in a substantially oxygen-free atmosphere at a temperature between 300 to 700°C, and the use of such catalysts as oxidation catalyst in the preparation of oxidized hydrocarbons, and especially the selective oxidation or ammoxidation of propane to acrylic acid and acrylonitrile, respectively. A more preferred catalyst comprises Mo, V, Te and Nb.

摘要翻译： 本发明涉及新型介孔混合金属氧化物催化剂及其制备方法，以及其在烃或部分氧化烃的氧化中作为催化剂的用途。 更具体地说，本发明涉及介孔混合金属氧化物催化剂，其包含至少两种，优选至少三种不同的金属物质，其中至少一种属于过渡金属族，其制备方法包括生产 在300-700℃的温度下，在基本上不含氧气氛中的中性模板化路线上进行煅烧步骤，以及在氧化型烃的制备中使用氧化催化剂等催化剂，特别是选择性氧化或氨氧化 丙烷分别与丙烯酸和丙烯腈反应。 更优选的催化剂包括Mo，V，Te和Nb。