FLUOROALLYLSULFONYL AZIDE MONOMERS AND POLYMERS THERE FROM
    2.
    发明公开
    FLUOROALLYLSULFONYL AZIDE MONOMERS AND POLYMERS THERE FROM 有权
    氟代磺酰亚胺单体及其聚合物

    公开(公告)号:EP2791185A1

    公开(公告)日:2014-10-22

    申请号:EP12809147.7

    申请日:2012-12-06

    摘要: This invention pertains to fluoroallylsulfonyl azide compounds of formula: CF
    2 =CF-CF
    2 -O-R
    f -SO
    2 N
    3 formula (I) wherein R
    f is a divalent (per)fluorinated group, optionally comprising one or more than one ethereal oxygen atom [monomer (Az)], which are useful as functional monomers in fluoropolymers, to the fluoropolymers which comprise recurring units derived from such fluoroallylsulfonyl azide compounds, to a process for their manufacture, to a curable compound comprising the same and to a method for crosslinking the same.

    摘要翻译: 本发明涉及式(CF 2)CF 2 = CF-CF 2 -OR f -SO 2 N 3的氟烯丙基磺酰基叠氮化物,其中R f是二价(全)氟化的基团,任选地包含一个或多于一个醚氧原子 可用作含氟聚合物中的官能单体的[单体(Az)],包含衍生自这类氟烯丙基磺酰基叠氮化物化合物的重复单元的含氟聚合物,其制备方法,包含其的可固化化合物和交联方法 一样。

    CROSSLINKABLE COMPOSITIONS BASED ON VINYLIDENE FLUORIDE-TRIFLUOROETHYLENE POLYMERS
    5.
    发明公开
    CROSSLINKABLE COMPOSITIONS BASED ON VINYLIDENE FLUORIDE-TRIFLUOROETHYLENE POLYMERS 有权
    以偏氟乙烯TRIFLUORETHYLENPOLYMEREN固化组合物

    公开(公告)号:EP2791233A1

    公开(公告)日:2014-10-22

    申请号:EP12795465.9

    申请日:2012-12-06

    IPC分类号: C08K5/28

    摘要: The present invention relates to crosslinkable compositions comprising vinylidene fluoride (VDF)/trifluoroethylene (TrFE) polymers and a fluorine-containing crosslinking agent of formula (A) [agent (Cz)]: {N
    3 [S(O)
    g1 ]
    s1 }
    na -(R
    H )
    nh -R
    f -(R'
    H )
    nh' -{[S(O)
    g2 ]
    s2 N
    3 }
    na' formula (A) wherein each of g1 and g2, equal to or different from each other, is 1 or 2, each of s1 and s2, equal to or different from each other, is 0 or 1, each of na and na' is independently zero or an integer of 1 to 3, provided that the sum na+na' is at least 2, each of R
    H and R'
    H , equal to or different from each other, is a C
    1 -C
    12 hydrocarbon group free of fluorine atoms, nh and nh', equal or different from each other are independently 0 or 1, and R
    f is selected from the group consisting of i) a C
    3 -C
    20 fluorocarbon group, possibly comprising one or more ethereal oxygen atoms, ii) an oligomer comprising copolymerized units of vinylidene fluoride and trifluoroethylene, to a process for the manufacture of said compositions, to a method for curing the same, and to the use of said copolymers in electrical and electronic devices.

    HYDRO-FLUOROCOMPOUNDS
    6.
    发明公开
    HYDRO-FLUOROCOMPOUNDS 审中-公开
    HYDRO氟化合物

    公开(公告)号:EP2714639A1

    公开(公告)日:2014-04-09

    申请号:EP12724943.1

    申请日:2012-05-24

    摘要: The invention pertains to certain hydro-fluorocompounds of the following formula (I): R
    f O-R
    H -O-(CH2)
    m -[CF(X)]
    n -COOX
    a wherein: - X
    a is H, a monovalent metal (preferably an alkaline metal) or an ammonium group of formula -N(R'
    n )
    4 , wherein each of R'
    n , equal to or different from each other, independently represents a hydrogen atom or a C
    1-6 hydrocarbon group (preferably an alkyl group); - R
    f is a C
    1 -C
    6 (per)fluoroalkyl optionally comprising one or more catenary oxygen atoms, preferably R
    f is a group of formula R
    'f -CH
    2 -, wherein R'
    f is a C
    1 -C
    5 perfluorinated group, possibly comprising one or more ethereal oxygens, preferably a C
    1 -C
    3 perfluorinated group, possibly comprising one or more ethereal oxygens; - R
    H is a fluorine-free hydrocarbon group optionally comprising one or more catenary oxygen atoms; - X is F or CF
    3 , preferably X is F; - m is 0 or 1; - n is 1 to 3, to a process for the manufacture of said hydro-fluorocompounds, to a method of making fluoropolymers in the presence of said hydro-fluorocompounds, and to fluoropolymer dispersions comprising said hydro-fluorocompound.

    摘要翻译: 本发明涉及下式(I)的某些氢氟化合物:其中:-X a为H,一价金属(优选 碱金属)或式-N(R'n)4的铵基,其中每个R'n彼此相同或不同,独立地表示氢原子或C 1-6烃基(优选 烷基); -R f是任选地包含一个或多个链状氧原子的C 1 -C 6(全)氟烷基,优选R f是式R'f-CH 2 - 的基团,其中R'f是C 1 -C 5 全氟化基团,其可能包含一种或多种醚性氧,优选C 1 -C 3全氟化基团,可能包含一种或多种醚性氧; -R H是任选地包含一个或多个悬链氧原子的无氟烃基; - X是F或CF 3,优选X是F; - m是0或1; n为1至3,涉及用于制造所述氢氟化合物的方法,涉及在所述氢氟化合物存在下制备含氟聚合物的方法以及包含所述氢氟化合物的含氟聚合物分散体。