公开(公告)号：EP2632891A1

公开(公告)日：2013-09-04

申请号：EP11838503.8

申请日：2011-10-25

申请人： Stepan Company

发明人： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  GANGULY-MINK, Sangeeta ,  MALEC, Andrew, D. ,  MANUEL, Teresa, C. ,  MASTERS, Ronald, A. ,  MUNIE, Lawrence, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  TERRY, Michael, R. ,  WEITGENANT, Jeremy, Aaron ,  WHITLOCK, Laura, Lee ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC分类号： C07C211/00

CPC分类号： C07C309/69 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/447 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C04B24/121 ,  C04B24/124 ,  C04B24/16 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C211/63 ,  C07C219/08 ,  C07C229/12 ,  C07C231/12 ,  C07C233/36 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K8/54 ,  C09K8/60 ,  C09K15/22 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

摘要： Quaternary ammonium, betaine, or sulfobetaine compositions derived from fatty amines, wherein the fatty amine is made by reducing the amide reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives and a secondary amine, are disclosed. Quaternary ammonium, betaine, or sulfobetaine compositions derived from fatty amidoamines, wherein the amidoamine is made by reacting of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives and an aminoalkyl-substituted tertiary amine, are also disclosed. The quaternized compositions are advantageously sulfonated or sulfated. In one aspect, the ester derivative of the C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The quaternary ammonium, betaine, and sulfobetaine compositions and their sulfonated or sulfated derivatives are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), antimicrobial compositions, agricultural uses, and oil field applications.

公开(公告)号：EP2632271A1

公开(公告)日：2013-09-04

申请号：EP11838510.3

申请日：2011-10-25

申请人： Stepan Company

发明人： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  MALEC, Andrew, D. ,  WOLFE, Patrick, Shane

IPC分类号： A01N57/18

CPC分类号： C11C3/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

摘要： Aqueous glyphosate formulations comprising a surfactant derived from metathesized natural oil feedstocks are disclosed. The formulations comprise a glyphosate salt, water, and a surfactant derived from a metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. The surfactant is selected from C
10 or C
12 amine oxides, C
10 or C
12 quats, C
10 , C
12 , or C
16 amidoamines, C
10 or C
12 amidoamine oxides, C
10 imidazoline quats, C
10 or C
12 amidoamine quats, C
10 , C
12 , or C
16 betaines, C
16 amidoamine betaines, C
18 diamidoamines, C
18 diamidoamine oxides, C
18 diamidoamine diquats, C
18 diamidoamine oxide quats, C
18 diamidoamine oxide betaines, Cis diamidoamine monobetaines, C
18 diamidoamine monobetaine quats, C
18 ester amidoamine quats, and amidoamines and their oxidized or quaternized derivatives made from self- or cross-metathesized palm or soybean oil. The surfactants noted above impart substantial stability to highly concentrated glyphosate formulations at, above, and below room temperature and perform as well or better than commercial alternatives.

公开(公告)号：EP2633008B1

公开(公告)日：2019-03-20

申请号：EP11838497.3

申请日：2011-10-25

申请人： Stepan Company

发明人： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC分类号： C07C211/00

公开(公告)号：EP2633022B1

公开(公告)日：2019-01-23

申请号：EP11838507.9

申请日：2011-10-25

申请人： Stepan Company

发明人： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  MASTERS, Ronald, A. ,  WOLFE, Patrick, Shane ,  TITIEVSKY, Lena

IPC分类号： C07C211/00 ,  C11D1/28 ,  C11D1/62 ,  C11D1/88 ,  C11D1/92 ,  C11D1/94 ,  C11C3/00 ,  C07C211/21 ,  C07C219/08 ,  C07C237/16 ,  C07C209/12 ,  C07C303/18 ,  A61Q19/10 ,  A61K8/44 ,  A61K8/46 ,  B01F17/00 ,  B01F17/08 ,  C11D1/74 ,  A01N25/02 ,  A01N25/30

公开(公告)号：EP2633022A2

公开(公告)日：2013-09-04

申请号：EP11838507.9

申请日：2011-10-25

申请人： Stepan Company

发明人： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  MASTERS, Ronald, A. ,  WOLFE, Patrick, Shane ,  TITIEVSKY, Lena

IPC分类号： C11D10/00

CPC分类号： C11C3/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

摘要： Aqueous hard surface cleaner compositions derived from metathesized natural oil feedstocks are disclosed. In one aspect, the compositions comprise at least one anionic surfactant derived from a metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. Particular classes of sulfonated materials (e.g., certain amide sulfonates, sulfonated fatty ester alkoxylates, amidoamine sulfonates, amidoamine betaine sulfonates, sulfo-estolides) are identified as having value as the anionic surfactant. In another aspect, aqueous hard surface cleaners comprising at least one nonionic or amphoteric surfactant derived from a metathesis- derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. Particular classes of these surfactants (e.g., certain amides, imidazoline quat sulfonates, fatty ester alkoxylates, and amine oxides, betaines, amidoamine sulfobetaines) are also identified. The aqueous cleaners noted above rival or outperform commercial baselines in a Gardner straight-line washability test. Industrial degreasers comprising a C
10 or C
12 amide solvent and derived from a metathesis-derived C
10 -C
17 monounsaturated acid are superior to commercial standards.

公开(公告)号：EP2633008A1

公开(公告)日：2013-09-04

申请号：EP11838497.3

申请日：2011-10-25

申请人： Stepan Company

发明人： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC分类号： C10L1/18

CPC分类号： C11C3/04 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/39 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/86 ,  A61K8/92 ,  A61Q5/12 ,  A61Q17/005 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/02 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

摘要： Alkoxylated fatty ester compositions are disclosed. In one aspect, the compositions comprise a reaction product of a metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with one or more alkylene oxides in the presence of an insertion catalyst to give an alkoxylated fatty ester. In another aspect, the metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or its ester derivative is reacted with a glycol ether or a glycol ether alkoxylate, to give an alkoxylated fatty ester. In yet another aspect, the metathesis-derived C
10 -C
17 monounsaturated acid or octadecene-1,18-dioic acid is reacted with one or more alkylene oxides to give a fatty acid alkoxylate, followed by etherification of the fatty acid alkoxylate.

公开(公告)号：EP2576635A1

公开(公告)日：2013-04-10

申请号：EP11787187.1

申请日：2011-05-23

申请人： Stepan Company

发明人： LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew, D. ,  TERRY, Michael, R. ,  WOLFE, Patrick, Shane

IPC分类号： C08F8/30

CPC分类号： C09D133/12 ,  C08J5/18 ,  C09D7/63 ,  C09D167/08 ,  C09J167/08 ,  C08K5/20

摘要： A film may be formed from film forming compositions which comprise at least one carboxamide based coalescing solvent. These coalescing solvents impart equivalent or improved wet-scrub resistance, block resistance, gloss, dirt pick-up resistance and leveling characteristics to the films on a substrate, without contributing to total VOC levels, when replacing conventional coalescing solvents. The present invention also includes a method for forming a film comprising applying a film forming composition comprising polyunsaturated reactive carboxamides to a substrate and curing the film under ambient conditions. The coalescing carboxamide solvents are suitable for paint, latex based caulk, adhesives and floor care applications.

公开(公告)号：EP2576635B1

公开(公告)日：2017-09-13

申请号：EP11787187.1

申请日：2011-05-23

申请人： Stepan Company

发明人： LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew, D. ,  TERRY, Michael, R. ,  WOLFE, Patrick, Shane

IPC分类号： C08F8/30

CPC分类号： C09D133/12 ,  C08J5/18 ,  C09D7/63 ,  C09D167/08 ,  C09J167/08 ,  C08K5/20

摘要： A film may be formed from film forming compositions which comprise at least one carboxamide based coalescing solvent. These coalescing solvents impart equivalent or improved wet-scrub resistance, block resistance, gloss, dirt pick-up resistance and leveling characteristics to the films on a substrate, without contributing to total VOC levels, when replacing conventional coalescing solvents. The present invention also includes a method for forming a film comprising applying a film forming composition comprising polyunsaturated reactive carboxamides to a substrate and curing the film under ambient conditions. The coalescing carboxamide solvents are suitable for paint, latex based caulk, adhesives and floor care applications.

摘要翻译： 膜可以由包含至少一种甲酰胺基聚结溶剂的成膜组合物形成。 这些聚结溶剂在替代常规聚结溶剂时赋予基底上薄膜同等或改进的耐湿擦洗性，抗粘连性，光泽度，耐沾污性和流平特性，而不会影响总VOC水平。 本发明还包括一种形成膜的方法，该方法包括将包含多不饱和反应性羧酰胺的成膜组合物施涂到基材上并在环境条件下固化该膜。 聚结羧酰胺溶剂适用于涂料，乳胶基填缝剂，粘合剂和地板护理应用。

公开(公告)号：EP2841468A1

公开(公告)日：2015-03-04

申请号：EP13781311.9

申请日：2013-03-13

申请人： Stepan Company

发明人： ALLEN, David, R. ,  ALONSO, Marcos ,  BEDDAOUI, Mary ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  DONG, Xue, Min ,  GORMAN, Wilma ,  HUTCHISON, John, C. ,  LUEBKE, Gary ,  LUKA, Renee ,  LUXEM, Franz ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  SPAULDING, Chris ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC分类号： C08F18/20

摘要： Unsaturated fatty alcohol alkoxylates, processes for making them, and methods of using them are disclosed. In one aspect, a monounsaturated fatty alcohol alkoxylate is made by reducing a metathesis-derived monounsaturated alkyl ester, followed by alkoxylation of the resulting monounsaturated alcohol. Microscopy reveals that the monounsaturated alkoxylates have isotropic and lamellar phases over a wider range of actives levels compared with their saturated analogs. This attribute expands formulating latitude for many end-use applications. The unsaturated fatty alcohol alkoxylates are valuable in, for example, agricultural solvents, nonionic emulsifiers for agricultural compositions, hard surface cleaners, laundry detergents, specialty foams, additives or surfactants for paints or coatings, and surfactant compositions for enhanced oil recovery.

公开(公告)号：EP2632256A1

公开(公告)日：2013-09-04

申请号：EP11838499.9

申请日：2011-10-25

申请人： Stepan Company

发明人： ALLEN, Dave R. ,  ALONSO, Marcos ,  BERNHARDT, Randal J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew D. ,  MASTERS, Ronald A. ,  MURPHY, Dennis S. ,  SHAPIRO, Irene ,  SKELTON, Patti ,  SOOK, Brian ,  TERRY, Michael R. ,  WALLACE, Gregory ,  WHITLOCK, Laura Lee ,  WIESTER, Michael ,  WOLFE, Patrick, Shane ,  TITIEVSKY, Lena

IPC分类号： A01N37/00 ,  A61K31/20

CPC分类号： C07C233/09 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q17/005 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C233/20 ,  C07C233/38 ,  C07C237/16 ,  C07C303/18 ,  C07C309/15 ,  C07C309/70 ,  C07D233/24 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C08K5/42 ,  C09D7/45 ,  C09D7/63 ,  C09K8/00 ,  C09K8/524 ,  C09K8/54 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/66 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C11D11/0017 ,  C07C211/63 ,  C07C211/64 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

摘要： Fatty amide compositions and their derivatives are disclosed. The fatty amides comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a primary or secondary amine. Derivatives made by reducing, quaternizing, sulfonating, alkoxylating, sulfating, and sulfitating the fatty amide are also included. The amine reactant can be diethylenetriamine or (2-aminoethyl)ethanolamine, which provide imidazoline amides or esters, respectively. In one aspect, the ester derivative of the C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The compositions are valuable for cleaners, fabric treatment, hair conditioning, personal care, antimicrobial compositions, agricultural uses, and oil field applications.

摘要翻译： 公开了脂肪酰胺组合物及其衍生物。 脂肪酰胺包含由复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与伯胺或仲胺的反应产物。 还包括通过还原，季铵化，磺化，烷氧基化，硫酸化和硫酸化而制得的衍生物。 胺反应物可以是二亚乙基三胺或（2-氨基乙基）乙醇胺，其分别提供咪唑啉酰胺或酯。 一方面，C10-C17单不饱和酸或十八碳烯-1,18-二酸的酯衍生物是低级烷基酯。 在其它方面，酯衍生物是通过天然油或通过天然油与烯烃的交叉复分解制备的不饱和甘油三酯的自分解制备的改性甘油三酯。 组合物对于清洁剂，织物处理，头发调理，个人护理，抗微生物组合物，农业用途和油田应用是有价值的。