摘要:
Disclosed is a composition in which a phosphorescent compound represented by formula (1) and a host material are blended with each other, wherein the amount of chlorine atoms contained as impurities in the phosphorescent compound is 3.5 ppm by mass or less with respect to the total amount of solid contents blended in the composition:
wherein, M 1 represents an iridium atom or the like; n 1 represents an integer of 1 or more, n 2 represents an integer of 0 or more, and n 1 + n 2 is 2 or 3; E 1 and E 2 represent a carbon atom or a nitrogen atom; R 1 ring represents a 5-membered aromatic heterocyclic ring and R 2 ring represents an aromatic hydrocarbon ring or the like; A 1 -G 1 -A 2 represents an anionic bidentate ligand; A 1 and A 2 represent a nitrogen atom or the like; and G 1 represents a single bond or the like.
摘要:
To provide a polymer compound which is useful for production of a light emitting device excellent in luminance life. A polymer compound comprising a constitutional unit having a residue of a compound represented by the formula (1) and a constitutional unit having no residue of a compound represented by the formula (1) described above:
[wherein, Ring A, Ring B and Ring C represent an aromatic hydrocarbon ring and the like. X represents a boron atom and the like. Y 1 , Y 2 and Y 3 represent N-Ry, a sulfur atom or a selenium atom. Ry represents a hydrogen atom, an aryl group, a monovalent heterocyclic group or an alkyl group. n3 is 0 or 1. When n3 is 0, -Y 3 - is absent.].
摘要:
A polymer compound comprising a constitutional unit having a group represented by the formula (1):
wherein Ring R 1A and Ring R 2A represent an aromatic hydrocarbon ring or a heterocyclic ring and these rings each optionally have a substituent, nA represents an integer of 0 to 5, nB represents an integer of 1 to 5, L A and L B represent an alkylene group, a cycloalkylene group, an arylene group, a divalent heterocyclic ring group, a group represented by -NR'-, an oxygen atom or a sulfur atom, and R' represents a hydrogen atom, an alkyl group or the like, and Q 1 represents a crosslinkable group.
摘要:
The present invention provides a method for producing a compound represented by the formula (3):
wherein n is an integer of 1 to 6, characterized by the steps of hydrolyzing a solution containing an ester compound represented by the formula (1):
wherein R is a lower alkyl group and n is an integer of 1 to 6, and a compound represented by the formula (2):
wherein R is as defined above, adjusting the pH of the resulting solution to pH 4 to 8, and then subjecting to phase separation to obtain an organic layer containing the carboxylic acid of formula (3).
摘要:
A method for producing a carboxylic acid compound represented by the following formula (3) (wherein n is as defined below) is characterized in that an organic layer containing a carboxylic acid compound represented by the above formula (3) is extracted by hydrolyzing a mixture containing an ester compound represented by the following formula (1) (wherein R represents a lower alkyl group and n represents an integer of 1-6) and a compound represented by the following formula (2) (wherein R is as defined above) and then separating the resulting while adjusting the pH from 4 to 8.
摘要:
To provide a light emitting device excellent in light emission efficiency. A light emitting device having an anode, a cathode, a first organic layer and a second organic layer disposed between the anode and the cathode, wherein the first organic layer is a layer containing a compound represented by the formula (T) and a fluorescent compound represented by the formula (B) and the second organic layer is a layer containing a crosslinked body of a crosslink material:
[wherein, n T1 represents an integer of 0 to 5. n T2 represents an integer of 1 to 10. Ar T1 represents a single-ring or condensed-ring monovalent hetero ring group containing a nitrogen atom having no double bond as a ring constituent atom and not containing a nitrogen atom having a double bond as a ring constituent atom. L T1 represents an alkylene group, an arylene group or the like. Ar T2 represents a single-ring or condensed-ring hetero ring group containing a nitrogen atom having a double bond as a ring constituent atom.] Ar 1B (̵R 1B ) n 1B (B) [wherein, n 1B represents an integer of 0 to 15. Ar 1B represents a condensed-ring aromatic hydrocarbon group. R 1B represents an aryl group, a monovalent hetero ring group, a substituted amino group or the like.].
摘要:
Provided is a polymer compound excellent in crosslinkability and hole transportability. A polymer compound comprising a constitutional unit represented by the formula (1A) or the formula (1B) and a constitutional unit represented by the formula (2A) or the formula (2B):
wherein R Am and R Bm represent a hydrogen atom or a substituent, Ar 1m to Ar 5m and L M represent a divalent group, Ar M represents an aromatic hydrocarbon group or a heterocyclic group, m1 to m6 represent a specified integer, and X M represents a monovalent group containing any one of the following crosslinkable groups:
wherein R An and R Bn represent a hydrogen atom or a substituent, Ar 1n to Ar 5n Ar Ln and L N represent a divalent group, Ar N represents an aromatic hydrocarbon group or a heterocyclic group, n1 to n6 and Ln represent a specified integer, and X N represents a monovalent group containing any one of the following crosslinkable groups:
wherein n XL represents an integer of 0 to 5, and R XL represents a divalent group.
摘要:
A process for producing a dicarboxylic acid compound represented by the formula (4): wherein R 1 and R 2 are the same or different and each represents lower alkyl and the wavy line indicates that this compound is the E- or Z-isomer or a mixture of them, characterized by reacting a compound represented by the formula (2): wherein R 1 , R 2 and the wavy line have the same meanings as the above, and one of X 2 and X 3 represents hydrogen and the other represents halogen, with nitrophenol represented by the formula (3): in the presence of a base; a process for producing a nitrochromone compound represented by the formula (5): wherein R 1 has the same meaning as the above, characterized by reacting the dicarboxylic acid compound or carboxylic acid thereof with an acid; a process for producing an aminochromone compound which comprises reducing the nitrochromone compound; and a process for producing an amidochromone compound which comprises acylating the aminochromone compound are provided.