公开(公告)号：EP2127762B1

公开(公告)日：2017-01-25

申请号：EP08738874.0

申请日：2008-03-26

Applicant: TOTO LTD.

Inventor： KITAZAKI, Satoru ,  KAMESHIMA, Junji ,  OMOSHIKI, Koji ,  TAKAKI, Yoji ,  TANAKA, Yuki ,  IWATA, Hironaga ,  HAYAKAWA, Makoto ,  KANNO, Mitsuyoshi

IPC: B05D7/24 ,  C09D1/00 ,  C09D7/12 ,  C09D183/04

CPC classification number: C09D1/00 ,  B01J35/004 ,  B01J37/0009 ,  B01J37/0219 ,  C03C17/007 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/477 ,  C03C2217/478 ,  C03C2217/48 ,  C03C2217/71 ,  C08K3/22 ,  C09D7/61 ,  C09D7/67 ,  C09D183/04

Abstract: There is disclosed a photocatalyst-coated body which is superior in weather resistance, noxious gas decomposability, and various coating properties (such as ultraviolet absorptivity, transparency and film strength) while preventing corrosion of a substrate (in particular an organic substrate), and a photocatalyst coating liquid therefor. The photocatalyst-coated body comprises a substrate and a photocatalyst layer provided on the substrate. The photocatalyst layer comprises photocatalyst particles of 1 part or more by mass and less than 20 parts by mass; inorganic oxide particles of 70 parts or more by mass and less than 99 parts by mass; and a hydrolyzable silicone of zero parts or more by mass and less than 10 parts by mass, provided that a total amount of the photocatalyst particles, the inorganic oxide particles and the hydrolyzable silicone is 100 parts by mass.

Abstract translation: 公开了一种防止基板（特别是有机基板）的腐蚀的耐候性，有害气体分解性和各种涂布性（例如紫外线吸收性，透明性和膜强度）的光催化剂涂布体，以及 光催化剂涂布液体。 光催化剂涂覆体包括基材和设置在基材上的光催化剂层。 光催化剂层包含1质量％且小于20质量份的光催化剂颗粒; 无机氧化物粒子为70质量份以上且小于99质量份; 以及零质量以上且小于10质量份的可水解硅氧烷，条件是光催化剂颗粒，无机氧化物颗粒和可水解硅氧烷的总量为100质量份。

公开(公告)号：EP2409763A1

公开(公告)日：2012-01-25

申请号：EP10753578.3

申请日：2010-03-18

Applicant: Toto Ltd.

Inventor： HAYAKAWA, Makoto ,  KATAOKA, Kyoko ,  KITAZAKI, Satoru ,  KAMESHIMA, Junji ,  KANNO, Mitsuyoshi

IPC: B01J35/02 ,  A61L9/00 ,  A61L9/01 ,  B01D53/86 ,  B01J37/02

CPC classification number: A61L9/18 ,  A61L9/205 ,  B01D53/8668 ,  B01D53/885 ,  B01D2255/20707 ,  B01D2255/9202 ,  B01D2257/708 ,  B01D2257/91 ,  B01J21/06 ,  B01J21/063 ,  B01J35/004 ,  B01J37/0045 ,  B01J37/0217 ,  B01J37/0225 ,  C08J7/045 ,  C08J7/12 ,  C08J2309/06 ,  C08J2323/12 ,  C08J2333/06 ,  C08J2367/02 ,  C08J2483/07 ,  C08K3/22 ,  C09D7/61 ,  C23C10/08 ,  C23C10/60 ,  C23C24/02 ,  Y02P20/52

Abstract: Disclosed is a photocatalyst member that, even when used in a form where warm water resistance and acid resistance are required, can exert a photocatalytic decomposition ability over a long period of time. The member having a photocatalytic decomposition ability comprises: a base material; and photocatalytic metal oxide particles immobilized on the base material, the base material having a surface treated with silicification flame treatment, the photocatalytic metal oxide particles are immobilized with a silicon-type binder on the base material on the surface treated with silicification flame treatment.

Abstract translation: 公开了一种光催化剂成分，即使以需要耐温性和耐酸性的形式使用时，也能够长时间地发挥光催化分解能力。 具有光催化分解能力的部件包括：基材; 固定在基材上的光催化性金属氧化物粒子，通过硅化火焰处理进行表面处理的基材，将该光催化性金属氧化物粒子用硅系粘合剂固定在用硅化火焰处理处理的表面上的基材上。

公开(公告)号：EP2596864A1

公开(公告)日：2013-05-29

申请号：EP11809589.2

申请日：2011-07-13

Applicant: Toto Ltd.

Inventor： HAYAKAWA, Makoto ,  TERASAKI, Hiroshi ,  KAMESHIMA, Junji ,  FUJII, Hiroyuki ,  OMOSHIKI, Koji ,  KITAZAKI, Satoru ,  KANNO, Mitsuyoshi

IPC: B01J35/02 ,  B01J31/38

CPC classification number: B01J37/0215 ,  B01J21/063 ,  B01J35/004 ,  B01J35/023 ,  C03C17/007 ,  C03C2217/212 ,  C03C2217/23 ,  C03C2217/477 ,  C03C2217/71 ,  C09D5/1618

Abstract: Disclosed is use of a composite material including a transparent photocatalyst layer that can allow a design of a substrate to be utilized and, at the same time, can exert a photocatalytic decomposition function while effectively suppressing a silicone contamination-derived appearance change over a long period of time. The composite material includes a photocatalyst layer. The photocatalyst layer includes photocatalyst particles and inorganic oxide particles where the total mass of the photocatalyst particles and the inorganic oxide particles is 80% by mass (exclusive) to 100% by mass (inclusive) when the mass of the whole photocatalyst layer is presumed to be 100% by mass. The number mean particle diameter of particulate components constituting the photocatalyst layer is less than 90 nm as calculated by measuring the length of any 100 particles present in a field of view under a scanning electron microscope at a magnification of 200000 times. The photocatalyst layer is transparent and has a thickness of not more than 3 µm. The photocatalyst is excited by sunlight to decompose substances, thereby reducing or preventing silicone contamination on the surface of the photocatalyst layer.

公开(公告)号：EP2551015A1

公开(公告)日：2013-01-30

申请号：EP11759584.3

申请日：2011-03-25

Applicant: TOTO LTD.

Inventor： HAYAKAWA, Makoto ,  OMOSHIKI, Koji ,  KITAZAKI, Satoru ,  FUJII, Hiroyuki ,  KANNO, Mitsuyoshi ,  KAMESHIMA, Junji

IPC: B01J35/02 ,  B01J21/06 ,  B05D5/00 ,  C09D1/00

CPC classification number: B01J35/004 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J35/023 ,  B01J37/0215 ,  C04B41/009 ,  C04B41/52 ,  C04B41/89 ,  C04B2111/00827 ,  C04B2111/2061 ,  C08K3/22 ,  C08K3/36 ,  C09D5/1618 ,  C09D7/67 ,  C04B33/00 ,  C04B41/483 ,  C04B2103/54 ,  C04B41/501 ,  C04B41/5041 ,  C04B41/5089

Abstract: Disclosed are a photocatalyst-coated body that can realize a good weather resistancce, a photocatalyst-coated body that, in removing NOx, particularly in removing NOx in air, can suppress the production of an intermediate product such as NO 2 while increasing the NOx removed, and a photocatalytic coating liquid for use in the formation of the photocatalyst-coated body. The photocatalyst-coated body comprises a photocatalyst layer provided on a substrate. The photocatalyst layer comprises at least photocatalytic titanium oxide particles, silica particles, and a product obtained by drying water soluble zirconium compound. When the photocatalyst layer is presumed to be totally 100% by mass, the content of the photocatalytic titanium oxide particles are not less than 1% by mass and not more than 20% by mass, the content of the silica particles are not less than 51 % by mass and not more than 98% by mass, and the content of the product obtained by drying water soluble zirconium compound is not less than 1% by mass and not more than 48% by mass in terms of zirconium oxide (ZrO 2 ).

Abstract translation: 公开了能够实现良好的耐候性的光催化剂涂布体，特别是在除去空气中的NOx时，除去NOx，可以抑制中间产物如NO 2的产生，同时增加除去的NO x的光催化剂涂覆体 ，以及用于形成光催化剂涂覆体的光催化涂布液。 光催化剂涂覆体包括设置在基材上的光催化剂层。 光催化剂层至少包含光催化氧化钛颗粒，二氧化硅颗粒和通过干燥水溶性锆化合物获得的产物。 假定光催化剂层为100质量％时，光催化性氧化钛粒子的含量为1质量％以上且20质量％以下，二氧化硅粒子的含量为51以上 质量％以上且98质量％以下，通过干燥水溶性锆化合物而得到的产物的含量，以氧化锆（ZrO 2）计为1质量％以上48质量％以下， 。

公开(公告)号：EP2127762A1

公开(公告)日：2009-12-02

申请号：EP08738874.0

申请日：2008-03-26

Applicant: Toto Ltd.

Inventor： KITAZAKI, Satoru ,  KAMESHIMA, Junji ,  OMOSHIKI, Koji ,  TAKAKI, Yoji ,  TANAKA, Yuki ,  IWATA, Hironaga ,  HAYAKAWA, Makoto ,  KANNO, Mitsuyoshi

IPC: B05D7/24 ,  C09D1/00 ,  C09D7/12 ,  C09D183/04

CPC classification number: C09D1/00 ,  B01J35/004 ,  B01J37/0009 ,  B01J37/0219 ,  C03C17/007 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/477 ,  C03C2217/478 ,  C03C2217/48 ,  C03C2217/71 ,  C08K3/22 ,  C09D7/61 ,  C09D7/67 ,  C09D183/04

Abstract: There is disclosed a photocatalyst-coated body which is superior in weather resistance, noxious gas decomposability, and various coating properties (such as ultraviolet absorptivity, transparency and film strength) while preventing corrosion of a substrate (in particular an organic substrate), and a photocatalyst coating liquid therefor. The photocatalyst-coated body comprises a substrate and a photocatalyst layer provided on the substrate. The photocatalyst layer comprises photocatalyst particles of 1 part or more by mass and less than 20 parts by mass; inorganic oxide particles of 70 parts or more by mass and less than 99 parts by mass; and a hydrolyzable silicone of zero parts or more by mass and less than 10 parts by mass, provided that a total amount of the photocatalyst particles, the inorganic oxide particles and the hydrolyzable silicone is 100 parts by mass.

公开(公告)号：EP2599545B1

公开(公告)日：2019-09-04

申请号：EP11812466.8

申请日：2011-07-26

Applicant: TOTO LTD.

Inventor： FUJII, Hiroyuki ,  KAMESHIMA, Junji ,  OMOSHIKI, Koji ,  KITAZAKI, Satoru ,  ADACHI, Susumu

IPC: B01J21/08 ,  B01J35/02 ,  C09D1/00 ,  C09D5/16 ,  C09D201/00

公开(公告)号：EP2599545A1

公开(公告)日：2013-06-05

申请号：EP11812466.8

申请日：2011-07-26

Applicant: TOTO LTD.

Inventor： FUJII, Hiroyuki ,  KAMESHIMA, Junji ,  OMOSHIKI, Koji ,  KITAZAKI, Satoru ,  ADACHI, Susumu

IPC: B01J35/02 ,  B01J21/08 ,  C09D1/00 ,  C09D5/16 ,  C09D7/12 ,  C09D201/00

CPC classification number: B01J21/08 ,  B01D53/00 ,  B01D53/88 ,  B01D2255/20715 ,  B01D2255/30 ,  B01D2255/802 ,  B01J21/063 ,  B01J21/066 ,  B01J35/004 ,  B01J35/006 ,  B01J37/0045 ,  B01J37/0215 ,  B01J37/038 ,  C09D1/00 ,  C09D5/1687

Abstract: Disclosed is a photocatalyst coated body which has excellent photocatalytic degradation function and excellent weather resistance. Also disclosed is a photocatalyst coated body which is capable of suppressing the formation of intermediate products such as NO 2 , while increasing the amount of NO x removed during removal of NO x in the air. The photocatalyst coated body comprises a base and a photocatalyst layer that is provided on the base. The photocatalyst coated body is characterized in that photocatalyst layer contains 1-20 (inclusive) parts by mass of photocatalyst particles, 30-98 (inclusive) parts by mass of silica particles and 1-50 (inclusive) parts by mass of zirconia particles, so that the total of the photocatalyst particles, the silica particles and the zirconia particles is 100 parts by mass. The photocatalyst coated body is also characterized in that the zirconia particles are at least one kind of particles selected from the group consisting of crystalline zirconia particles having an average crystallite diameter of 10 nm or less and amorphous zirconia particles.

Abstract translation: 公开了具有优异的光催化降解功能和优异的耐候性的光催化剂涂覆体。 还公开了一种光催化剂涂覆体，其能够抑制中间产物如NO 2的形成，同时增加在除去空气中的NO x时除去的NO x的量。 所述光催化剂涂覆体包括基材和设置在基材上的光催化剂层。 光催化剂涂布体的特征在于，光催化剂层含有1-20质量份的光催化剂颗粒，30-98（含）质量份的二氧化硅颗粒和1-50（含）质量份的氧化锆颗粒， 使得光催化剂颗粒，二氧化硅颗粒和氧化锆颗粒的总量为100质量份。 光催化剂涂覆体的特征还在于氧化锆颗粒是选自平均微晶直径为10nm以下的结晶氧化锆颗粒和无定形氧化锆颗粒中的至少一种颗粒。