摘要:
Heat-shrinkable polyester films characterized in that the content of 1,4-cyclohexanedimethanol is 10 to 50 % by mole based on the polyhydric alcohol component and that the heat shrinkage factors of a 10 cm square specimen of the film in (A) hot water at 75 °C, (B) hot water at 85 °C, and (C) hot water at 95 °C are 30 to 40 %, 50 to 60 %, and 65 to 77 % respectively. The films can be produced by stretching under specified conditions.
摘要:
[PROBLEMS] To provide a heat shrink film that when used as a label of beverage container, enhances the smoothness of external surface side to thereby prevent merchandise jamming in an automatic vending machine of beverage and that is fully satisfactory in solvent bonding capability and excels in processability. [MEANS FOR SOLVING PROBLEMS] There is provided a heat shrink polyester film characterized in that (A) at least one major surface thereof is overlaid with 0.002 to 0.5 g/m2, in terms of solid content coating amount, of a silicone containing easily sliding layer, (B) the easily sliding layer having an inter-easily sliding layer frictional coefficient μd ≤ 0.27, and that (C) the heat shrink polyester film exhibits a heat shrinkage factor, as measured in the direction of maximum shrinkage after immersion in 95˚C water for 10 sec, of 50% or greater. Thus, there is provided the heat shrink film that when used as a label of beverage container, enhances the smoothness of external surface side to thereby prevent merchandise jamming in an automatic vending machine of beverage and that is fully satisfactory in solvent bonding capability and excels in processability.
摘要:
Disclosed is a heat-shrinkable polyester film having a specific composition. A heat shrinkage factor of a 10cm square sample of the film in a maximal shrinkage direction of the film is not less than 20% under the condition that the sample is immersed in hot water of 85 DEG C for 10 seconds, and then in water of 25 DEG C for 10 seconds. The number of test pieces of the film having a rupture ratio of not more than 5% is not more than 10% to the total number of the test pieces under the condition that a tensile test of drawing the film in a direction orthogonal to the maximal shrinkage direction of the film is conducted with a distance between corresponding chucks of 100 mm, each test piece having 15 mm in width, a temperature of 23 DEG C, and a drawing rate of 200 mm/min.
摘要:
A film roll comprising a heat-shrinkable polystyrene based resin film wound into a roll, characterized in that, each of the samples taken out from the roll exhibits, in a heat shrinkage test under the condition of the immersion in a hot water at 85 ° C for 10 sec, a heat shrinkage rate in the main shrinking direction of within ± 5 % relative to an average rate of the total samples; a heat-shrinkable polystyrene based resin film taken from the roll; a heat-shrinkable label comprising the film; a method for producing the heat-shrinkable polystyrene based resin film roll which comprises using raw material chips having a specific form, or using a hopper having a specific shape for feeding raw material chips to an extruder, or limiting the variation of the surface temperature of a film in a specific production step to a specific range.
摘要:
A heat-shrinkable resin film which has a heat shrinkage in the maximum shrinkage direction of 20% or higher when a 10 cm by 10 cm square sample cut out thereof is immersed in 85°C water for 10 seconds, pulled out, subsequently immersed in 25°C water for 10 seconds, and then pulled out, characterized in that the content of nitrogen atoms in a film surface is 0.1 to 3.0% and the film surface has a wet tension of 36 mN/m or higher; and a film roll obtained by winding up the heat-shrinkable resin film, characterized in that when the rolled film is sampled at a first sampling part located up to 2 m apart from the end of the rolled film and at other sampling parts located after the first sampling part at intervals of about 100 m and the average nitrogen content of each sample is calculated, then the nitrogen content of each sample is within the ±0.8% range based on that average nitrogen content.
摘要:
Provided is a heat-shrinkable polyester film satisfying: (A) a heat shrinkage percentage of 10% to 50% in a maximum shrinkage direction in a hot water at 70°C, (B) a heat shrinkage percentage of not less than 75% in a maximum shrinkage direction, and not more than 10% in an orthogonal to the maximum shrinkage direction in a hot water at 85°C, (C)a heat shrinkage percentage difference ”X(%) = X 0 - X 10 of a sample is 10% to 20%, wherein, X 0 and X 10 are defined as follows, X 0 (%) : a heat shrinkage percentage in a maximum shrinkage direction in a hot water at 95°C; and X 10 (%): a heat shrinkage percentage in a maximum shrinkage direction of a film having experienced heat shrink by 10% in a maximum shrinkage direction; (D) a three-dimensional surface roughness ”a gives 0. 008 to 0.04; and (E) a three-dimensional surface roughness SRz gives 0.6 to 1.5 micrometers. Even in use for full label usage, the heat-shrinkable polyester film has excellent quality after shrink-finishing, reinforcement function of containers after wrapped by shrinking, and blocking resistance, and furthermore exhibits excellent film-formation property, and processability as well. In addition, the present invention provides a heat-shrinkable polyester film having ultraviolet absorptivity, and a heat-shrinkable polyester film roll exhibiting uniform heat shrinkage properties over whole of a long film.
摘要:
[PROBLEMS] To provide a heat-shrinkable polyester film which has excellent characteristics and which can be produced at a high rate, even when a PET bottle-recycled material is used. [MEANS FOR SOLVING PROBLEMS] A heat-shrinkable polyester film having a multi-layer structure of at least two layers, among which at least one layer is a layer containing a PET bottle-recycled material, wherein a heat shrinkage percentage in a maximum shrinkage direction of a 10 cm square sample cut out from the film is 40 % or higher, under the condition that the square sample is immersed in hot water of 95°C for 10 seconds and then immersed in water of 25°C for 10 seconds.
摘要:
A heat shrinking polyester film characterized by exhibiting a coefficient of dynamic friction between surfaces on at least one side thereof (μd) of ≤ 0.27 and range (R) of ≤ 0.05 and further exhibiting a weight loss, resulting from ten reciprocations of friction on the surface under a load of 400 g in a friction test conducted by means of a tester of dyed product fastness to rubbing having a friction member fitted with a sand paper of #1000 grain diameter, of less than 0.24 g/m2.