LOW-ADHESION MATERIAL, MOLD FOR SHAPING RESIN AND STAINPROOF MATERIAL
    2.
    发明公开
    LOW-ADHESION MATERIAL, MOLD FOR SHAPING RESIN AND STAINPROOF MATERIAL 有权
    低粘合材料,树脂模制和染色的耐热材料

    公开(公告)号:EP2006083A9

    公开(公告)日:2009-07-01

    申请号:EP06843408.3

    申请日:2006-12-27

    IPC分类号: B32B9/00 B29C33/38 B32B18/00

    摘要: An upper die (1) has a cavity member (6) constituting an inner bottom surface (5) of a cavity (4), and a surrounding member (7). The cavity member (6) is formed of a low adhesion material in accordance with the present invention, and includes a body portion (8) and a surface layer (10) formed on an undersurface (9) of the body portion (8) exposed to a fluid resin. The body portion (8) is formed of a first material of 3YSZ and a second material of ZrN that are mixed at a predetermined ratio. The surface layer (10) is formed of Y 2 O 3 having a low adhesion property with respect to a set resin, and has a thermal expansion coefficient smaller than that of the body portion (8). By bonding the body portion (8) and the surface layer (10) at a high temperature and then cooling them down, compressive residual stress is caused in the surface layer (10) due to a difference in the thermal expansion coefficients thereof, and the compressive residual stress is present in the surface layer (10).

    LOW-ADHESION MATERIAL, MOLD FOR SHAPING RESIN AND STAINPROOF MATERIAL
    3.
    发明公开
    LOW-ADHESION MATERIAL, MOLD FOR SHAPING RESIN AND STAINPROOF MATERIAL 有权
    低粘合材料,树脂模制和染色的耐热材料

    公开(公告)号:EP2006083A2

    公开(公告)日:2008-12-24

    申请号:EP06843408.3

    申请日:2006-12-27

    IPC分类号: B32B9/00 B29C33/38 B32B18/00

    摘要: An upper die (1) has a cavity member (6) constituting an inner bottom surface (5) of a cavity (4), and a surrounding member (7). The cavity member (6) is formed of a low adhesion material in accordance with the present invention, and includes a body portion (8) and a surface layer (10) formed on an undersurface (9) of the body portion (8) exposed to a fluid resin. The body portion (8) is formed of a first material of 3YSZ and a second material of ZrN that are mixed at a predetermined ratio. The surface layer (10) is formed of Y 2 O 3 having a low adhesion property with respect to a set resin, and has a thermal expansion coefficient smaller than that of the body portion (8). By bonding the body portion (8) and the surface layer (10) at a high temperature and then cooling them down, compressive residual stress is caused in the surface layer (10) due to a difference in the thermal expansion coefficients thereof, and the compressive residual stress is present in the surface layer (10).

    LOW-ADHESION MATERIAL, MOLDS FOR MOLDING RESINS, AND STAINPROOF MATERIAL
    4.
    发明公开
    LOW-ADHESION MATERIAL, MOLDS FOR MOLDING RESINS, AND STAINPROOF MATERIAL 审中-公开
    欢迎来到哈尔滨工业大学材料科学与技术学院

    公开(公告)号:EP1978005A1

    公开(公告)日:2008-10-08

    申请号:EP06843407.5

    申请日:2006-12-27

    IPC分类号: C04B35/50 B29C33/38

    摘要: A resin molding die (1) has a molding surface (6) formed of a low adhesion material (3) formed of a solid solution of La- Y 2 O 3 produced from Y 2 O 3 and an other oxide of La 2 O 3 . La 2 O 3 contains La, which has an ionic radius larger than Y 3+ , and is larger in basicity than Y 2 O 3 . The low adhesion material (3) contains La 2 O 3 at a predetermined ratio relative to a total of Y 2 O 3 and La 2 O 3 . The low adhesion material (3) thus has a large ionic radius contributing to a smaller number of sites per unit area than Y 2 O 3 , a larger basicity contributing to a smaller force binding the low adhesion material with a basic substance than Y 2 O 3 , and a ratio contributing to shape retention. The low adhesion material (3) thus less adhesive and more shape-retentive than Y 2 O 3 configures the molding surface (6). A low adhesion material that is less adhesive to a basic substance than Y 2 O 3 is and excellently shape-retentive, and an excellently releasable and shape-retentive resin molding die can thus be obtained.

    摘要翻译: 树脂成型模具(1)具有由由Y 2 O 3制成的La-Y 2 O 3的固溶体和La 2 O 3的其它氧化物形成的低粘合材料(3)形成的成型面(6) 。 La 2 O 3含有离子半径大于Y 3+的La,碱度大于Y 2 O 3。 低粘合性材料(3)相对于Y 2 O 3和La 2 O 3的总和以相对于预定比例含有La 2 O 3。 因此,低粘附性材料(3)具有大的离子半径,有助于每单位面积的位置数量少于Y 2 O 3,较大的碱度有助于将低粘附性材料与碱性物质结合的力小于Y 2 O 3,以及有助于形状保持的比例。 低粘合性材料(3)因此比Y 2 O 3更少的粘合剂和更多的形状 - 保持性构成了模制表面(6)。 与Y 2 O 3相比,对碱性物质的粘合性较差的粘合性低的材料具有良好的保形性,能够得到良好的脱模性和形状保持性的树脂成形模。