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1.发明公开PROTECTED ALLOY SURFACES IN MICROCHANNEL APPARATUS AND CATALYSTS, ALUMINA SUPPORTED CATALYSTS, CATALYST INTERMEDIATES, AND METHODS OF FORMING CATALYSTS AND MICROCHANNEL APPARATUS 审中-公开专有合金表面微沟槽装置和催化剂，催化剂ALUMINIUMOXIDGETRÄGERTE催化剂中间产品及其制造方法催化剂和微通道设备
公开(公告)号：EP1740303A2
公开(公告)日：2007-01-10
申请号：EP05729334.2
申请日：2005-03-23
申请人： Velocys, Inc.
发明人： YANG, Barry , RAMLER, Jeffrey, J. , LONG, Richard , TAHA, Rachid , CHIN, YA-Huei , Johnson, Bradley, R. , FITZGERALD, Sean, P. , MAZANEC, Terry , WATSON, Junko, M. , DALY, Francis, P. , YANG, Barry, L.
IPC分类号： B01J19/00
CPC分类号： B01J37/0226 , B01J19/0093 , B01J35/04 , B01J37/0215 , B01J37/0238 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00837 , B01J2219/00873 , B01J2219/00891 , B01J2219/00905 , B01J2219/00995 , B01L3/502707 , B01L3/502746 , B01L2200/12 , B01L2300/16 , B01L2400/0406 , B01L2400/086 , B01L2400/088
摘要： The invention describes microchannel apparatus and catalysts that contain a layer of a metal aluminide or are made in a process in which a metal aluminide layer is formed as an intermediate. Certain processing conditions have surprisingly been found to result in superior coatings. The invention includes chemical processes conducted through apparatus described in the specification. Other catalysts and catalyst synthesis techniques are also described.
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2.发明公开PROCESS FOR CONDUCTING AN EQUILIBRIUM LIMITED CHEMICAL REACTION IN A SINGLE STAGE PROCESS CHANNEL 审中-公开方法实施处于平衡LIMITED一步法CHANNEL化学反应
公开(公告)号：EP1536884A1
公开(公告)日：2005-06-08
申请号：EP03788295.8
申请日：2003-07-31
申请人： Velocys, Inc.
发明人： TONKOVICH, Anna, Lee , SIMMONS, Wayne, W. , JAROSCH, Kai , MAZANEC, Terry , DAYMO, Eric , PENG, Ying , MARCO, Jennifer
IPC分类号： B01J19/00
CPC分类号： B01J19/0093 , B01J23/80 , B01J2219/00783 , B01J2219/00835 , B01J2219/0086 , B01J2219/00873 , C01B3/16 , C01B2203/0283 , C01B2203/1041 , Y02P20/52
摘要： This invention relates to a process for conducting an equilibrium limited chemical reaction in a single stage process channel. A process for conducting a water shift reaction is disclosed. A multichannel reactor with cross flow heat exchange is disclosed.
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3.发明授权
公开(公告)号：EP1713883B1
公开(公告)日：2019-03-20
申请号：EP04814270.7
申请日：2004-12-15
申请人： Velocys, Inc.
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4.发明授权PROCESS FOR CONVERTING ETHYLENE TO ETHYLENE OXIDE USING MICROCHANNEL PROCESS TECHNOLOGY 有权PROCESS乙烯乙烯中转换使用微通道工艺技
公开(公告)号：EP1786797B1
公开(公告)日：2014-11-26
申请号：EP05784239.5
申请日：2005-08-11
申请人： Velocys, Inc.
发明人： MAZANEC, Terry , TONKOVICH, Anna, Lee , SIMMONS, Wayne, W. , DALY, Francis, P. , LONG, Richard, Q. , SILVA, Laura, J.
IPC分类号： C07D303/04 , C07D301/06 , C07D301/08 , C07D301/10 , B01J19/00 , B01J19/24 , C07D301/02
CPC分类号： B01J19/249 , B01J19/0093 , B01J2219/00117 , B01J2219/00783 , B01J2219/00819 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , B01J2219/00889 , B01J2219/2453 , B01J2219/2458 , B01J2219/246 , B01J2219/2465 , B01J2219/2474 , B01J2219/2479 , B01J2219/2486 , B01J2219/2487 , B01J2219/2488 , B01J2219/2493 , C07D301/02 , C07D301/06 , C07D301/08 , C07D301/10 , Y02P20/582
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5.发明授权MICRO-CHANNEL REACTOR WITH CATALYST APPLIED TO THERMALLY-GROWN ALUMINA, METHODS OF USING SAME, CATALYST AND ITS MAKING 有权采用催化剂热生长铝微通道反应器，它们的用途和催化剂及其制备方法
公开(公告)号：EP1755777B1
公开(公告)日：2012-05-23
申请号：EP05813296.0
申请日：2005-03-23
申请人： Velocys, Inc.
IPC分类号： B01J19/00
CPC分类号： B01J23/34 , B01J23/626 , B01J37/0217 , B01J37/0226 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00831 , B01J2219/00833 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , B01J2219/00891 , C07C5/3337 , C07C2523/62 , Y02P20/52 , C07C11/04
摘要： The invention describes microchannel reactors comprising a metal substrate having an alumina-layer, such as aluminide and catalyst metal particles directly disposed thereon, such as via thermal-growth. The catalyst may comprise a Pt/Sn atomic ratio of 1:4. Cross-flow, post-assembly and channels of complex, continuous or interior nature may be used. Methods of making catalysts in a microreactor channel, methods of making catalysts as such, methods of making a microchannel reactor and methods of conducting chemical reactions such as oxidative dehydrogenations and conversion of ethane to ethylene are also described. Superior performance, especially for high temperature reactions at high flow rates and low contact times, can be obtained from a catalyst formed by directly depositing a catalytic material onto a low surface area thermally-grown alumina layer, said layer preferably grown at a temperature from 1000-1100°C. The alumina layer is to be dense and substantially defect-free.
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6.发明公开PROCESS AND APPARATUS EMPLOYING MICROCHANNEL PROCESS TECHNOLOGY 审中-公开VERFAHREN UND VORRICHTUNG UNTER VERWENDUNG VON MIKROKANALVERFAHRENSTECHNIK
公开(公告)号：EP2346964A2
公开(公告)日：2011-07-27
申请号：EP09737306.2
申请日：2009-10-09
申请人： Velocys, Inc.
发明人： TONKOVICH, Anna, Lee , ARORA, Ravi , BROPHY, John , DALY, Francis, P. , DESHMUKH, Soumitra , FANELLI, Maddalena , JAROSCH, Kai Tod Paul , LAPLANTE, Timothy, J. , LONG, Richard, Q. , MAZANEC, Terry , RYAN, Daniel Francis , SILVA, Laura, J. , SIMMONS, Wayne, W. , STANGELAND, Bruce , WANG, Yong , YUSCHAK, Thomas
IPC分类号： C10J3/46
CPC分类号： C10G47/14 , B01J19/0093 , B01J21/12 , B01J23/42 , B01J23/75 , B01J23/96 , B01J35/023 , B01J2219/00783 , B01J2219/00788 , B01J2219/00835 , B01J2219/00873 , B01J2219/00889 , B01J2219/00891 , B01J2219/00984 , C10G2/32 , C10G45/02 , C10G47/00 , C10G47/02 , C10G2300/202 , C10G2300/4018 , Y02P20/582
摘要： This invention relates to a process for conducting a hydrocracking or a hydrotreating process in a microchannel reactor. This invention also relates to a process and apparatus for flowing a vapor and liquid into a plurality of microchannels in a microchannel processing unit.
摘要翻译： 本发明涉及在微通道反应器中进行加氢裂化或加氢处理工艺的方法。 本发明还涉及一种将蒸汽和液体流入微通道处理单元中的多个微通道的方法和装置。
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公开(公告)号：EP1819436A1
公开(公告)日：2007-08-22
申请号：EP05851354.0
申请日：2005-11-03
申请人： Velocys, Inc.
发明人： TONKOVICH, Anna, Lee , LAMONT, Michael , MAZANEC, Terry , FITZGERALD, Sean, P. , NEAGLE, Paul, W. , HESSE, David, J. , SILVA, Laura, J. , CHADWELL, G., Bradley , QIU, Dongming , ARORA, Ravi , YANG, Bin , JAROSH, Kai
CPC分类号： F28F1/00 , B01B1/005 , B01J19/0013 , B01J19/0093 , B01J2219/00054 , B01J2219/00074 , B01J2219/00783 , B01J2219/00822 , B01J2219/00835 , B01J2219/0086 , B01J2219/00869 , B01J2219/00873 , B01J2219/00891 , B01J2219/00995 , B01J2219/182 , B01J2219/2411 , B01J2219/2462 , C07B61/00 , F28D9/00 , F28D15/04 , F28D2015/0225 , F28D2021/0022 , F28D2021/0064 , F28F13/00 , F28F13/187 , F28F2260/02
摘要： The invention provides methods, apparatus and systems in which there is partial boiling of a liquid in a mini-channel or microchannel for a length of at least 15 cm. The partial boiling removes heat from a Fischer-Tropsch reaction.
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8.发明公开PROCESS AND APPARATUS FOR IMPROVED METHODS FOR MAKING VINYL ACETATE MONOMER (VAM) 审中-公开的方法和设备用于生产乙酸乙烯酯单体改进方法（VAM）
公开(公告)号：EP1812373A1
公开(公告)日：2007-08-01
申请号：EP05847767.0
申请日：2005-11-02
发明人： MAZANEC, Terry , JOHNSTON, Victor, J. , HUCKMAN, Michael , FITZGERALD, Sean, P. , FOSTER, James, A. , LINDLEY, Daniel , TONKOVICH, Anna Lee , DALY, Francis, P. , WADE, Leslie , HAMMOCK, Tony , YUSCHAK, Thomas, D. , YANG, Bin , JAROSH, Kai
IPC分类号： C07C69/01 , C07C67/055 , B01J19/00 , B01J8/02
CPC分类号： B01J19/0093 , B01J2219/00783 , B01J2219/00835 , B01J2219/0086 , B01J2219/00862 , B01J2219/00873 , B01J2219/00889 , C07C67/055 , C07C69/01 , C07C69/15
摘要： The invention provided an apparatus for the production of VAM, comprising: a continuous reaction channel comprising at least 2 catalyst-free mixing zones alternating with at least 2 catalyst-containing reaction zones; and a cooling channel adjacent to the reaction channel, wherein the catalyst in the at least 2 catalyst-containing reaction zones comprises Pd and Au.
摘要翻译： 提供给装置用于生产VAM，包括以下发明：连续反应通道包括至少两个催化剂游离的混合区具有至少2个含催化剂的反应区交替; 和一个冷却通道相邻于反应通道，worin在所述至少两个含催化剂的反应区中的催化剂包括Pd和Au。
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9.发明公开MICRO-CHANNEL REACTOR WITH CATALYSTS APPLIED DIRECTLY TO THERMALLY-GROWN ALUMINA, METHODS USING SAME AND OXIDATIVE DEHYDROGENATION 有权采用催化剂热生长铝微通道反应器，它们的用途和催化剂及其制备方法
公开(公告)号：EP1755777A1
公开(公告)日：2007-02-28
申请号：EP05813296.0
申请日：2005-03-23
申请人： Velocys, Inc.
IPC分类号： B01J19/00
CPC分类号： B01J23/34 , B01J23/626 , B01J37/0217 , B01J37/0226 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00831 , B01J2219/00833 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , B01J2219/00891 , C07C5/3337 , C07C2523/62 , Y02P20/52 , C07C11/04
摘要： The invention describes microchannel reactors comprising a metal substrate having an alumina-layer, such as aluminide and catalyst metal particles directly disposed thereon, such as via thermal-growth. The catalyst may comprise a Pt/Sn atomic ratio of 1:4. Cross-flow, post-assembly and channels of complex, continuous or interior nature may be used. Methods of making catalysts in a microreactor channel, methods of making catalysts as such, methods of making a microchannel reactor and methods of conducting chemical reactions such as oxidative dehydrogenations and conversion of ethane to ethylene are also described. Superior performance, especially for high temperature reactions at high flow rates and low contact times, can be obtained from a catalyst formed by directly depositing a catalytic material onto a low surface area thermally-grown alumina layer, said layer preferably grown at a temperature from 1000-1100°C. The alumina layer is to be dense and substantially defect-free.
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10.发明公开FISCHER-TROPSCH SYNTHESIS USING MICROCHANNEL TECHNOLOGY AND NOVEL CATALYST AND MICROCHANNEL REACTOR 审中-公开费 - 托微通道技术工艺手段和新催化剂和微通道反应器
公开(公告)号：EP1713883A1
公开(公告)日：2006-10-25
申请号：EP04814270.7
申请日：2004-12-15
申请人： Velocys, Inc.
发明人： WANG, Yong , TONKOVICH, Anna, Lee , MAZANEC, Terry , DALY, Francis, P. , VANDERWIEL, Dave , HU, Jianli , CAO, Chunshe , KIBBY, Charles , LI, Xiaohong , BRISCOE, Michael, D. , GANO, Nathan , CHIN, Ya-Huei
CPC分类号： C10G2/332 , B01J19/0093 , B01J21/04 , B01J23/75 , B01J23/8896 , B01J23/8913 , B01J35/0066 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0205 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00826 , B01J2219/00831 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , C10G2/341 , C10G2300/301 , C10G2300/4018 , C10G2300/4025 , C10G2300/70 , C10G2400/04 , C10G2400/10 , Y02P20/582
摘要： The disclosed invention relates to a process for converting a reactant composition comprising H 2 and Co to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%.
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