摘要:
Des émulsions aqueuses de (A) organopolysiloxane dépourvu d'azote de base et de (B) alkyltrialcoxysilane contiennent (C) un émulsifiant et (D) de l'eau. L'organopolysiloxane (A) a la formule RaSi(OR1)bO4-ab/2, dans laquelle R désigne des résidus hydrocarbures C1-C18 monovalents identiques ou différents, substitués le cas échéant et liés par SiC; R1 désigne des résidus hydrocarbures C1-C6 monovalents identiques ou différents; a vaut 0, 1, 2 ou 3, en moyenne 0,75 à 1,5 et b vaut 1, 2, 3, en moyenne 0,2 à 2,0, l'organopolysiloxane ayant un poids moléculaire égal à au moins 600 g/mol. L'invention concerne également un procédé de production de ces émulsions et leur utilisation comme imprégnation hydrofuge d'éléments fibreux de construction liés avec du ciment.
摘要:
The invention concerns a dispersion powder composition which is redispersible in water and is made from water-insoluble homopolymers or copolymers of preferably ethylenically unsaturated monomers and one or more organosilicon compounds plus, optionally, other additives such as protective colloids and anti-blocking agents. The composition is obtained by: a) polymerizing one or more monomers in the presence of 0.1 to 30% by wt., relative to the total weight of the monomers, of one or more silicon compounds which are dispersible in water and which have a boiling point at normal pressure of > 160 °C, selected from the group comprising the silanes, polysilanes, oligosiloxanes, polysiloxanes, carbosilanes, polycarbosilanes, carbosiloxanes, polycarbosiloxanes and polysilylenedisiloxanes and: b) spray-drying the product thus obtained, either before or after addition of the additives mentioned.
摘要:
The invention concerns a dispersion powder composition which is redispersible in water and is made from water-insoluble homopolymers or copolymers of preferably ethylenically unsaturated monomers and one or more organosilicon compounds plus, optionally, other additives such as protective colloids and anti-blocking agents. The composition is obtained by: a) polymerizing one or more monomers in the presence of 0.1 to 30% by wt., relative to the total weight of the monomers, of one or more silicon compounds which are dispersible in water and which have a boiling point at normal pressure of > 160 °C, selected from the group comprising the silanes, polysilanes, oligosiloxanes, polysiloxanes, carbosilanes, polycarbosilanes, carbosiloxanes, polycarbosiloxanes and polysilylenedisiloxanes and: b) spray-drying the product thus obtained, either before or after addition of the additives mentioned.
摘要:
The invention concerns aqueous emulsions of (A) organopolysiloxane free from basic nitrogen and (B) alkyltrialkoxysilane which contain (C) an emulsifier and (D) water. Organopolysiloxane (A) has formula RaSi(OR1)bO4-a-b/2, wherein R has identical or different, monovalent, optionally substituted C1-C18 hydrocarbon residues bonded by SiC, R1 has identical or different, monovalent, optionally substituted C¿1?-C6 hydrocarbon residues, a is equal to 0, 1, 2 or 3, on average 0.75 to 1.5, and b is equal to 1, 2 or 3, on average 0.2 to 2.0, and has a molecular weight of at least 600 g/mol. Also disclosed are a method for preparing said emulsions and their use for water-repellent impregnation of cement-bonded fibrous building components.