CATALYST AND PROCESS
    3.
    发明公开
    CATALYST AND PROCESS 审中-公开
    催化剂和方法

    公开(公告)号:EP1560863A1

    公开(公告)日:2005-08-10

    申请号:EP03775546.9

    申请日:2003-11-12

    Abstract: The invention concerns an organometallic compound of formula RO-M(L1)X (L2)Y (L3)Z wherein M is a metal selected from titanium, zirconium, hafnium, iron (III), cobalt (III) or aluminium; L1 and L2 are each independently selected from a diketonate, an ester or amide of acetoacetic acid, a hydroxycarboxylic acid or ester thereof, R1COO- where R1 is substituted or unsubstituted C5 - C30 branched or linear alkyl, substituted or unsubstituted aryl including polycyclic structures such as naphthyl or anthracyl, phosphate, phosphinate, phosphonate, siloxy or sulphonato, provided that when L1 is a ligand which forms two covalent bonds with the metal atom, and x= 1 then y = 0; L3 is selected from substituted or unsubstituted aryloxy, R2COO- where R2 is a linear or branched C6 - C30 alkyl or a substituted or unsubstituted aryl, a polyoxyalkyl or hydroxyalkoxyalkylgroup; R is alkyl or hydroxy-alkyl hydroxyalkoxyalkyl, or (hydroxy)polyoxyalkyl group, x, y and z are each either 0 or 1 (x+y+z ) ≤ V-1, where V= the valency of the metal M. The invention further concerns compositions and processes for the manufacture of polyurethane articles using the organometallic compounds as catalysts to provide cured articles having a comparable performance to those produced using a commercial mercury-based catalyst.

    METAL SALTS OF PHOSPHORIC ACID ESTERS AS CROSS LINKING CATALYSTS
    6.
    发明公开
    METAL SALTS OF PHOSPHORIC ACID ESTERS AS CROSS LINKING CATALYSTS 有权
    作为交联催化剂的磷酸酯的金属盐

    公开(公告)号:EP1235646A1

    公开(公告)日:2002-09-04

    申请号:EP00992325.1

    申请日:2000-11-08

    Abstract: A metal (M) alkyl acid phosphate catalyst for the reaction of an epoxy compound with a carboxyl compound to provide a coating formulation that is stable at room temperature; that is humidity resistant, and non-yellowing, wherein the alkyl acid phosphate has the formula (RO)n-(P=O)-(OH)m and wherein: a each R is selected from the group consisting of: i) a C1 to C18 alkyl, cycloalkyl, or aryl; ii) a linear or branched C6 to C18 alkyl substituted with -(O-CH2-CH2-)o or -(O-CH-CH3-CH2-)p, wherein o or p is from 1 to 20; iii) a β-hydroxyethyl compound, R'-X-CH2-CH-OH-CH2-, wherein R' is a C6 to C18 alkyl or cycloalkyl or aryl, X is either -CH2-, -O- or -COO-; b) n+m=3 and n is between 2 to 1; and c) M is Zn or Sn (II) in a mole equivalent of 0.7 to 1.5 moles per mole of alkyl acid phosphate.

    Abstract translation: 一种用于使环氧化合物与羧基化合物反应以提供在室温下稳定的涂料配方的金属(M)烷基酸式磷酸酯催化剂; (RO)n-(P = O) - (OH)m并且其中:每个R选自:i)一个或多个选自以下的基团: C1至C18烷基,环烷基或芳基; ii)用 - (O-CH 2 -CH 2 - )0或 - (O-CH-CH 3 -CH 2 - )p取代的直链或支链C 6 -C 18烷基,其中o或p为1至20; iii)β-羟乙基化合物,R'-X-CH 2 -CH-OH-CH 2 - ,其中R'为C 6至C 18烷基或环烷基或芳基,X为-CH 2 - , - O-或-COO- ; b)n + m = 3且n在2至1之间; 和c)M是每摩尔酸式磷酸烷基酯0.7-1.5摩尔当量的Zn或Sn(II)。

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