Abstract:
This invention relates to an organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.
Abstract:
This invention relates to an organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.
Abstract:
The invention concerns an organometallic compound of formula RO-M(L1)X (L2)Y (L3)Z wherein M is a metal selected from titanium, zirconium, hafnium, iron (III), cobalt (III) or aluminium; L1 and L2 are each independently selected from a diketonate, an ester or amide of acetoacetic acid, a hydroxycarboxylic acid or ester thereof, R1COO- where R1 is substituted or unsubstituted C5 - C30 branched or linear alkyl, substituted or unsubstituted aryl including polycyclic structures such as naphthyl or anthracyl, phosphate, phosphinate, phosphonate, siloxy or sulphonato, provided that when L1 is a ligand which forms two covalent bonds with the metal atom, and x= 1 then y = 0; L3 is selected from substituted or unsubstituted aryloxy, R2COO- where R2 is a linear or branched C6 - C30 alkyl or a substituted or unsubstituted aryl, a polyoxyalkyl or hydroxyalkoxyalkylgroup; R is alkyl or hydroxy-alkyl hydroxyalkoxyalkyl, or (hydroxy)polyoxyalkyl group, x, y and z are each either 0 or 1 (x+y+z ) ≤ V-1, where V= the valency of the metal M. The invention further concerns compositions and processes for the manufacture of polyurethane articles using the organometallic compounds as catalysts to provide cured articles having a comparable performance to those produced using a commercial mercury-based catalyst.
Abstract:
A metal (M) alkyl acid phosphate catalyst for the reaction of an epoxy compound with a carboxyl compound to provide a coating formulation that is stable at room temperature; that is humidity resistant, and non-yellowing, wherein the alkyl acid phosphate has the formula (RO)n-(P=O)-(OH)m and wherein: a each R is selected from the group consisting of: i) a C1 to C18 alkyl, cycloalkyl, or aryl; ii) a linear or branched C6 to C18 alkyl substituted with -(O-CH2-CH2-)o or -(O-CH-CH3-CH2-)p, wherein o or p is from 1 to 20; iii) a β-hydroxyethyl compound, R'-X-CH2-CH-OH-CH2-, wherein R' is a C6 to C18 alkyl or cycloalkyl or aryl, X is either -CH2-, -O- or -COO-; b) n+m=3 and n is between 2 to 1; and c) M is Zn or Sn (II) in a mole equivalent of 0.7 to 1.5 moles per mole of alkyl acid phosphate.
Abstract:
A titanium catalyst for reaction between a carbon-carbon unsaturated bond and a compound having an electrophilic functional group or an electrophilic reagent, said titanium catalyst being composed of a titanium compound represented by the formula (1) below
TiX 1 X 2 X 3 X 4 (1)
(where X 1 , X 2 , X 3 , and X 4 denote independently a halogen atom, C 1-20 alkoxyl group, aralkyloxy group, aryloxy group, or -NRxRy group (where Rx and Ry denote independently a C 1-20 alkyl group or aralkyl group), and any two of X 1 , X 2 , X 3 , and X 4 may form a ring.) and a Grignard reagent represented by the formula (2) below in a molar amount 1.5-2.5 times as much as the titanium compound.
R 1 MgX 5 (2)
(where R 1 denotes a C 2-10 alkyl group having a hydrogen atom at the β position and X 5 denotes a halogen atom.) The titanium catalyst of the present invention activates the carbon-carbon unsaturated bond, which has a comparatively low reactivity, thereby catalyzing the reaction with an electrophilic functional group. It is inexpensive and industrially advantageous. When applied to reaction between a carbon-carbon unsaturated bond and an electrophilic functional group, it yields industrially a variety of adducts of a compound having a carbon-carbon unsaturated bond and a compound having an electrophilic functional group, and it also yields a variety of intramolecular adducts of a compound having a carbon-carbon unsaturated bond and an electrophilic functional group in the same molecule.
Abstract translation:一种用于在碳 - 碳不饱和键和具有亲电官能团的化合物或亲电试剂之间进行反应的钛催化剂,所述钛催化剂由TiX 1 X 2以下的式(1)表示的钛化合物组成, X 3 X 4(其中X 1,X 2,X 3和X 4独立地表示卤素原子,C 1-20烷氧基,芳烷氧基,芳氧基或 - NR x R y基团(其中R x和R y独立地表示C 1-20烷基或芳烷基),并且X 1,X 2,X 3和X 4中的任意两个可以形成环。 和由下式(2)表示的格氏试剂,摩尔量为钛化合物的1.5-2.5倍。 R 1 MgX 5(其中R 1表示在β位具有氢原子的C 2-10烷基,X 5表示卤素原子。)本发明的钛催化剂活化碳 - 碳不饱和键,其具有相对低的反应性,从而催化与亲电官能团的反应。 廉价且工业上有利。 当应用于碳 - 碳不饱和键和亲电官能团之间的反应时,它在工业上产生具有碳 - 碳不饱和键的化合物和具有亲电官能团的化合物的各种加合物,并且还产生各种 在同一分子中具有碳 - 碳不饱和键和亲电官能团的化合物的分子内加合物。
Abstract:
L'invention concerne un procédé amélioré de conversion de l'éthylène en butène-1, dans lequel on met l'éthylène en contact avec un catalyseur obtenu par l'interaction d'un titanate d'alkyle, éventuellement mélangé avec un éther, avec un composé d'aluminium de formule AlR 3 ou AlR 2 H, et en présence d'un additif constitué par au moins un polyéthylèneglycol et / ou un de ses dérivés tel qu'un monoéther ou un monoester de polyéthylèneglycol.