摘要:
In an embodiment, a method of producing a carbonate comprises reacting carbon monoxide and chlorine in a phosgene reactor in the presence of a catalyst to produce a first product comprising phosgene; wherein carbon tetrachloride is present in the first product in an amount of 0 to 10 ppm by volume based on the total volume of phosgene; and reacting a monohydroxy compound with the phosgene to produce the carbonate; wherein the phosgene reactor comprises a tube, a shell, and a space located between the tube and the shell; wherein the tube comprises one or more of a mini-tube section and a second tube section; a first concentric tube concentrically located in the shell; a twisted tube; an internal scaffold; and an external scaffold.
摘要:
The invention relates to a method for producing isocyanates by reacting primary amines with phosgene in a stoichiometric excess in the gas phase, wherein the excess phosgene is subsequently recovered and recirculated back into the reaction.
摘要:
A production process such as an isocyanate production process, conducted with a production facility having (a) at least two incoming streams, b) at least one exit stream and c) at least one inner recycling stream is controlled by adjusting at least one incoming stream amount by means of regulating controls to control the exit stream concentration and/or amount.
摘要:
The invention relates to a method for separating hydrogen chloride and phosgene. Said method is characterized in that a mixture of hydrogen chloride and phosgene is contacted with an ionic liquid in which at least some of the hydrogen chloride is dissolved in step a), whereupon the hydrogen chloride dissolved in the ionic liquid is separated in step b).
摘要:
A method of selectively removing an acid, e.g., HF, which coexists with an organic acid fluoride unstable to water. The method of separating an acid from a system in which the acid coexists with an organic acid fluoride represented by the formula RCOF (wherein R represents C 1−20 linear, branched, or cyclic alkyl or haloalkyl optionally containing a fluorine atom or heteroatom, or C 6−20 aryl or haloaryl) is characterized by using as a deacidifying agent an aromatic heterocyclic compound having a boiling point of 50°C or higher and containing a nitrogen atom as a heteroatom.
摘要:
The invention relates to a method for producing carbon monoxide gas (CO gas) which is as free as possible of sulphur compounds, to a method for desulphurising a CO gas containing sulphur, and to the use of said gas in chemical syntheses, e.g. for the synthesis of phosgene from carbon monoxide and chlorine.
摘要:
Carbonylfluorid, das auch als Ätzgas verwendet werden kann, lässt sich durch photochemische Oxidation von Chlordifluormethan mit Licht, beispielsweise mit Licht einer Wellenlänge ≥ 280 nm in Anwesenheit von Chlor herstellen.