摘要:
A process for the preparation of 3-methacryloxypropyldimethylchlorosilane by reaction of allylmethacrylate with dimethylchlorosilane in the presence of a hydrosilylation catalyst, characterized in that the reaction is carried out in the absence of a peroxide is provided. The process includes providing a first stream containing allylmethacrylate. A a second stream containing dimethylchlorosilane is provided. The streams contact in a continuous flow reactor in the presence of the hydrosilylation catalyst, thereby producing 3-methacryloxypropyldimethylchlorosilane. A product stream is continuously removed from the continuous flow reactor.
摘要:
There is provided a trisiloxane having a 3-(meth)acryloxy-substituted (hydroxylcyclohexyl)ethyl group, useful in making water absorbing silicone-hydrogel films for biomedical devices, such as contact lens, and a process for producing these monomers. This invention also provides for copolymers made from the trisiloxane having a 3-(meth)acryloxy-substituted (hydroxylcyclohexyl)ethyl group described herein.
摘要:
The invention concerns a method of hydrosilylation between a siloxane compound (A) comprising at least one hydrogen atom bonded to a silicon atom and an unsaturated compound (B) comprising at least one alkene function and/or at least one alkyne function, the method being characterized in that it is catalysed by a photocatalyst selected from among the polyoxometalates.
摘要:
The invention relates to a process for the body-hydrophobization of substrates by means of organosilicon compounds (O) which are solid at 20°C and can be prepared by reacting one molar equivalent of silane (S) selected from among hydrocarbyltrihalosilane, hydrocarbyltrihydrocarbyloxysilane and mixtures thereof and partial hydrolysates thereof with polyhydroxy compounds (P) in such a ratio that from 0.3 to 1.3 molar equivalence of hydroxy radicals are present per molar equivalent of halo or hydrocarbyloxy radical. The invention further provides building material mixtures containing organosilicon compounds (O) and the substrates to be hydrophobicized.
摘要:
The present invention provides a hydrophilic silicone which has a predetermined number of silicon atoms and a high purity and is suitable for producing an ophthalmic device and a process for preparing the same. The silicone compound is represented by formula (1) with a purity of 95 % by weight or higher, wherein m is one value out of the integers of from 3 to 10, n is one value out of the integers of from 1 to 10, R 1 is one out of alkyl groups having 1 to 4 carbon atoms, and R 2 is one out of a hydrogen atom and a methyl group.
摘要:
Disclosed herein is a process for the hydrasilylation of a composition containing a silyl hydride and a compound containing at least one unsaturated group, the process comprising contacting a non-previous metal based complex as a catalyst precursor with an activator being a reducing agent shortly before, simultaneously or after contacting the complex with the composition, to cause the siiyl hydride to react with the compound containing at least one unsaturated group to produce a hydrosilylation product.
摘要:
A silicone compound represented by the following Chemical Structure 1:
where Y represents a substituted or non-substituted alkyl group having one to ten carbon atoms, X1, X2, and X3 independently represent methyl groups or any of the following Substituents A-1 to A-7, and 1, m, and n are independently zero or an integer of from 1 to 6,
where R1 is a hydrogen atom, an alkyl group having one to four carbon atoms, or an alkoxy group having one to four carbon atoms,
where R2 represents a single bonding or an alkylene group having one to four carbon atoms and R3 represents a single bonding or an alkyleneoxy group having one to four carbon atoms,
where R4 and R5 independently represent hydrogen atoms or methyl groups,