ONLINE MONITORING OF CONTAMINANTS IN CRUDE AND HEAVY FUELS, AND REFINERY APPLICATIONS THEREOF
    1.
    发明公开
    ONLINE MONITORING OF CONTAMINANTS IN CRUDE AND HEAVY FUELS, AND REFINERY APPLICATIONS THEREOF 有权
    污染的原材料和重质燃料和精炼其应用在线监测

    公开(公告)号:EP2721396A2

    公开(公告)日:2014-04-23

    申请号:EP12802054.2

    申请日:2012-06-14

    IPC分类号: G01N23/223 G01N33/22

    摘要: A technique, including associated method and system, for on-line measurement of a trace element in a crude or heavy fuel stream for a refinery, including in one embodiment: providing at least one x-ray fluorescence ("XRF") analyzer at a point for the refinery; analyzing the petroleum stream for chlorine using the analyzer; and providing results from the analyzer to refinery operators, to improve refinery operations. The analyzer may be a monochromatic wavelength XRF analyzer, wherein the analyzer focuses energy to/from the stream using an x-ray engine having at least one focusing, monochromating x-ray optic. The analyzer may be an MWDXRF or ME-EDXRF analyzer; and the trace element may be one or more of the following elements: S, Cl, P, K, Ca, V, Mn, Fe, Co, Ni, Cu, Zn, Hg, As, Pb, and Se; and in one embodiment the stream is crude, and the trace element is chlorine.

    ONLINE MONITORING OF CONTAMINANTS IN CRUDE AND HEAVY FUELS, AND REFINERY APPLICATIONS THEREOF
    3.
    发明公开
    ONLINE MONITORING OF CONTAMINANTS IN CRUDE AND HEAVY FUELS, AND REFINERY APPLICATIONS THEREOF 有权
    在线 - ÜBERWACHUNGVON VERUNREINIGUNGEN在ROH- UND SCHWEREN KRAFTSTOFFEN SOWIE RAFFINERIEANWENDUNGENDAFÜR

    公开(公告)号:EP2721396A4

    公开(公告)日:2014-11-12

    申请号:EP12802054

    申请日:2012-06-14

    摘要: A technique, including associated method and system, for on-line measurement of a trace element in a crude or heavy fuel stream for a refinery, including in one embodiment: providing at least one x-ray fluorescence (“XRF”) analyzer at a point for the refinery; analyzing the petroleum stream for chlorine using the analyzer; and providing results from the analyzer to refinery operators, to improve refinery operations. The analyzer may be a monochromatic wavelength XRF analyzer, wherein the analyzer focuses energy to/from the stream using an x-ray engine having at least one focusing, monochromating x-ray optic. The analyzer may be an MWDXRF or ME-EDXRF analyzer; and the trace element may be one or more of the following elements: S, Cl, P, K, Ca, V, Mn, Fe, Co, Ni, Cu, Zn, Hg, As, Pb, and Se; and in one embodiment the stream is crude, and the trace element is chlorine.

    摘要翻译: 一种包括相关方法和系统的技术,用于在线测量用于炼油厂的原油或重质燃料流中的微量元素,包括在一个实施方案中:在一个实施方案中提供至少一个X射线荧光(“XRF”)分析仪 炼油厂点; 使用分析仪分析氯气石油流; 并向炼油厂提供分析仪的结果,以提炼炼油厂的运作。 分析仪可以是单色波长XRF分析仪,其中分析仪使用具有至少一个聚焦单色x射线光学器件的x射线引擎将能量聚焦到流/从流中。 分析仪可以是MWDXRF或ME-EDXRF分析仪; 微量元素可以是以下元素中的一种或多种:S,Cl,P,K,Ca,V,Mn,Fe,Co,Ni,Cu,Zn,Hg,As,Pb和Se; 并且在一个实施方案中,流是粗的,微量元素是氯。

    ONLINE MONITORING OF CONTAMINANTS IN CRUDE AND HEAVY FUELS, AND REFINERY APPLICATIONS THEREOF
    8.
    发明授权
    ONLINE MONITORING OF CONTAMINANTS IN CRUDE AND HEAVY FUELS, AND REFINERY APPLICATIONS THEREOF 有权
    在线监测原油和重油中的污染物及其炼油厂的应用

    公开(公告)号:EP2721396B1

    公开(公告)日:2018-04-04

    申请号:EP12802054.2

    申请日:2012-06-14

    摘要: A technique, including associated method and system, for on-line measurement of a trace element in a crude or heavy fuel stream for a refinery, including in one embodiment: providing at least one x-ray fluorescence (“XRF”) analyzer at a point for the refinery; analyzing the petroleum stream for chlorine using the analyzer; and providing results from the analyzer to refinery operators, to improve refinery operations. The analyzer may be a monochromatic wavelength XRF analyzer, wherein the analyzer focuses energy to/from the stream using an x-ray engine having at least one focusing, monochromating x-ray optic. The analyzer may be an MWDXRF or ME-EDXRF analyzer; and the trace element may be one or more of the following elements: S, Cl, P, K, Ca, V, Mn, Fe, Co, Ni, Cu, Zn, Hg, As, Pb, and Se; and in one embodiment the stream is crude, and the trace element is chlorine.

    VERFAHREN ZUR CHARAKTERISIERUNG DER KATALYSATORSTRUKTUR IN EINER BRENNSTOFFZELLE, SOWIE DAZU GEEIGNETES BRENNSTOFFZELLENDESIGN
    9.
    发明公开
    VERFAHREN ZUR CHARAKTERISIERUNG DER KATALYSATORSTRUKTUR IN EINER BRENNSTOFFZELLE, SOWIE DAZU GEEIGNETES BRENNSTOFFZELLENDESIGN 有权
    为表征的催化剂结构的方法在燃料电池和燃料电池配合设计

    公开(公告)号:EP2962089A1

    公开(公告)日:2016-01-06

    申请号:EP14710790.8

    申请日:2014-01-17

    IPC分类号: G01N23/083 H01M4/86 H01M8/02

    摘要: The invention relates to a method for characterising the catalyst structure in a fuel cell, and at the same time in particular the transmission X-ray absorption measurements (XAS), in which a novel fuel cell design is used. The fuel cell comprises a first (planar) electrode having a first catalyst, a second (planar) electrode having a second catalyst, and an electrolyte membrane having a layer thickness l
    m arranged between the electrodes, wherein the first electrode has at least one catalyst-free circular region of radius R
    1
    max . Unlike hitherto customary practice, the second electrode of the fuel cell according to the invention likewise has a catalyst-free circular region of radius R
    2 1
    max . Advantageously, 0.5 l
    m ≤ [R
    1
    max - R
    2 ] ≤ 2 l
    m applies. Simulations prove that during these investigations, which record only a narrow catalyst-containing sample ring, the local current density over the surface can be maintained virtually constant, and therefore the recorded catalyst particles are clearly more representative of the entire catalyst layer than in the previous investigations using fuel cells that use a completely circular measurement geometry as sample.

    摘要翻译: 一种用于在燃料电池中表征的催化剂结构的方法,特别是透射X射线吸收测量(XAS),其中使用的新的燃料电池设计。 所述燃料电池包括具有第一催化剂,具有第二催化剂的第二(平面)电极的第一(平面)电极,以及电解质膜的电极和具有层厚度为1m之间设置,worin所述第一电极包括至少一种催化剂 具有半径r1max -free圆形区域。 相反的是已经成为惯例到现在为止,在燃料电池gemäß到本发明的第二电极同样包括具有半径R2

    X-ray interferometer
    10.
    发明授权
    X-ray interferometer 有权
    X射线干涉仪

    公开(公告)号:EP2586373B1

    公开(公告)日:2014-12-03

    申请号:EP12190359.5

    申请日:2012-10-29

    摘要: Embodiments relate to an X-ray interferometer for imaging an object (130) comprising: a phase grating (122) for effecting in correspondence with the phase grating geometry a phase shift to at least a part of X-ray incident onto the phase grating (122); and an absorption grating (123) for effecting in correspondence with the absorption grating geometry absorption to at least a part of X-ray incident onto the absorption grating (123). The X-ray interferometer may be characterized in that the grating period (P 122 ) of the phase grating (122), and the grating period (P 123 ) of the absorption grating (123) are dimensioned such that a detector (140) for X-rays can be placed at a relatively large distance away from the absorption grating (123) such the phase contrast sensitivity of the image of the object detected by the detector remains substantially unaffected.

    摘要翻译: 实施例涉及用于对物体(130)进行成像的X射线干涉仪,包括:相位光栅(122),用于对应于相位光栅几何形状进行相移到至少入射到相位光栅上的X射线的一部分( 122); 以及吸收光栅(123),用于与吸收光栅几何形状吸收相对应地进入到入射到吸收光栅(123)上的至少一部分X射线。 X射线干涉仪的特征在于,相位光栅(122)的光栅周期(P 122)和吸收光栅(123)的光栅周期(P 123)的尺寸设定成使得用于 可以将X射线放置在远离吸收光栅(123)的相对较大的距离处,从而由检测器检测到的物体的图像的相对对比灵敏度基本上不受影响。