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    METAL-FIBER REINFORCED PLASTIC COMPOSITE MATERIAL
    1.
    发明公开
    METAL-FIBER REINFORCED PLASTIC COMPOSITE MATERIAL 审中-公开

    公开(公告)号：EP3904074A1

    公开(公告)日：2021-11-03

    申请号：EP19905148.3

    申请日：2019-12-23

    申请人： NIPPON STEEL Chemical & Material Co., Ltd.

    发明人： YOSHIOKA, Takahiro ,  TAKAHASHI, Hiroyuki ,  ANDOH, Hideki

    IPC分类号： B32B15/08 ,  B29C70/68 ,  B32B15/088 ,  C08J5/04 ,  B29K105/22

    摘要： To provide a metal-fiber reinforced plastic composite material which exhibits favorable impregnation of a matrix resin into a reinforcing fiber substrate and favorable adhesion to metal members, and which has excellent heat resistance, impact resistance and mechanical properties. The metal-fiber reinforced plastic composite material is a laminate of a metal member and a fiber reinforced plastic, wherein the fiber reinforced plastic includes a reinforcing fiber substrate (A) and a thermoplastic resin composition (B), the thermoplastic resin composition (B) contains a phenoxy resin (B-1) and a polyamide resin (B-2) at a mass ratio (B-1)/(B-2) of 80/20 to 20/80, an adhesive strength of the thermoplastic resin composition (B) to a monofilament of the reinforcing fiber substrate (A) is 40 MPa or more as an interfacial shear strength at 23°C in a microdroplet method, and an adhesive strength between the metal member and the thermoplastic resin composition (B) is 7.0 MPa or more as a tensile shear strength at 23°C.

    METAL/RESIN COMPOSITE AND PROCESS FOR PRODUCING THE COMPOSITE
    3.
    发明授权
    METAL/RESIN COMPOSITE AND PROCESS FOR PRODUCING THE COMPOSITE 有权
    METALL- / HARZ-VERBUNDSTOFF UND VERFAHREN ZUR HERSTELLUNG DES VERBUNDSTOFFS

    公开(公告)号：EP2123421B1

    公开(公告)日：2015-01-28

    申请号：EP07851101.1

    申请日：2007-12-21

    申请人： Taisei Plas Co., Ltd.

    发明人： NARITOMI, Masanori ,  ANDO, Naoki

    IPC分类号： B29C45/14 ,  C23F1/26 ,  B29K23/00 ,  B29K67/00 ,  B29K81/00 ,  B29K105/16 ,  B29K105/22 ,  B29K305/00

    CPC分类号： B29C70/683 ,  B29C45/14008 ,  B29C45/14221 ,  B29C45/14311 ,  B29C2045/14245 ,  B29C2045/14868 ,  B29K2067/006 ,  B29K2081/04 ,  B29K2705/00 ,  B29K2705/02 ,  B29K2705/08 ,  C23F1/26 ,  Y10T428/24355

    摘要： It is an object of the present invention to securely and integrally join a metal and a resin, more particularly, a shaped titanium alloy substrate and a resin composition. A titanium alloy substrate is used that has undergone surface roughening by chemical etching or the like so as to have a ultrafine textured face in which bent, ridge-like protrusions having a width and height of from ten to a few hundred nanometers and a length of from a few to a few hundred microns rise up on the surface at a spacing period of from ten to a few hundred nanometers. A titanium alloy piece 1 with its surface treated is inserted into the cavity of a metallic mold for injection molding 10 and a specific resin composition 4 is injected to obtain an integrated composite 7. The main resin component of the resin composition 4 that is used can be a polyphenylene sulfide resin (PPS) or a polybutylene terephthalate resin (PBT). High injection joining strength is obtained if the resin composition contains, as an auxiliary component, a polyethylene terephthalate resin and/or polyolefin resin in the case of PBT and a polyolefin resin in the case of PPS.

    摘要翻译： 本发明的目的是将金属和树脂，特别是成形的钛合金基材和树脂组合物牢固且一体地结合在一起。 使用通过化学蚀刻等进行表面粗糙化的钛合金基板，以具有超细纹理面，其中具有宽度和高度为10至几百纳米的弯曲的脊状突起和长度为 从几百微米上升到几百微米，间隔时间从几百纳米上升到表面。 将其表面处理的钛合金件1插入到用于注射成型的金属模具10的空腔中，并注入特定的树脂组合物4以获得一体化复合材料7.所使用的树脂组合物4的主要树脂成分可以 为聚苯硫醚树脂（PPS）或聚对苯二甲酸丁二醇酯树脂（PBT）。 如果在PPS的情况下树脂组合物含有聚对苯二甲酸乙二醇酯树脂和/或聚烯烃树脂，并且在PPS的情况下包含聚烯烃树脂，则获得高注射接合强度。

    RESIN-METAL BONDED BODY AND METHOD FOR PRODUCING THE SAME
    9.
    发明公开
    RESIN-METAL BONDED BODY AND METHOD FOR PRODUCING THE SAME 有权
    HARZ-METALL-GEBUNDENES ELEMENT UND VERFAHREN ZU SEINER HERSTELLUNG

    公开(公告)号：EP2221398A1

    公开(公告)日：2010-08-25

    申请号：EP08863133.8

    申请日：2008-12-15

    申请人： Toadenka Corporation

    发明人： KUROYAMA, Masumi ,  ISHIKAWA, Tomonori ,  KATO, Kazuo ,  SASAKI, Yaeko ,  MIURA, Shuhei ,  NAKAMURA, Masayuki ,  SATO, Setsuko

    IPC分类号： C25D11/04 ,  B29C45/14 ,  B32B15/08 ,  C25D11/18 ,  C25D11/20 ,  B29K105/22

    CPC分类号： C25D5/48 ,  B29C45/14311 ,  B29C45/14778 ,  B29K2705/00 ,  B29K2705/02 ,  C25D11/04 ,  C25D11/18 ,  C25D11/20 ,  Y10T428/269

    摘要： Disclosed is a resin-metal bonded body of an aluminum metal member and a thermoplastic resin member, which has improved bonding strength and good durability. Also disclosed is a method for producing such a resin-metal bonded body. Specifically disclosed is a resin-metal bonded body which is obtained by bonding an aluminum metal member with a thermoplastic resin member. In this resin-metal bonded body, the aluminum metal member and the thermoplastic resin member are bonded together by an anodic oxide coating having a film thickness of 70-1500 nm or an anodic oxide coating having a triazine thiol in the inner and upper portions. The anodic oxide coating has an infrared absorption spectrum peak intensity ascribed to OH group at 0.0001-0.16.

    摘要翻译： 公开了一种铝金属构件和热塑性树脂构件的树脂金属接合体，其具有改善的接合强度和良好的耐久性。 还公开了这种树脂金属粘结体的制造方法。 具体公开了通过将铝金属构件与热塑性树脂构件接合而获得的树脂金属接合体。 在该树脂金属接合体中，通过具有70〜1500nm的膜厚度的阳极氧化物涂层或在内部和上部具有三嗪硫醇的阳极氧化物涂层将铝金属部件和热塑性树脂部件接合在一起。 阳极氧化物涂层具有归属于OH基团的红外吸收光谱峰强度，为0.0001-0.16。