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公开(公告)号：EP0174898A3
公开(公告)日：1986-05-28
申请号：EP85630145
申请日：1985-09-03
发明人： Wideman, Lawson Gibson , Hsu, Wen-Liang , Maly, Neil Arthur , Matrans, Barry Allen , Strozier, Robert William
IPC分类号： C07C01/253 , B01J27/16 , C07C11/12
CPC分类号： C07C1/24 , B01J27/16 , C07C2527/167 , C07C11/12 , C07C11/18
摘要： @ This invention is directed to a process for the conversion of an aldehyde to a diolefin comprising contacting an aldehyde of 4 to 6 carbon atoms in the vapor phase at a temperature of 300° to 400°C with a catalyst comprising boron phosphate wherein the initial molar ratio of phosphorous (P) to boron (B) (P/B) is less than 0.1 but greater than 0.6 which is in intimate admixture with from 0.1 to 10 weight percent graphite. More specifically, this invention is concerned with a process for the catalytic dehydration of 2-methylbutanal (2MBA) to isoprene in the vapor phase with a boron phosphate catalyst wherein the improvement comprises the use of a catalyst with a molar ratio of P/B of less than 0.1 but greater than 0.6 which contains from 0.1 to 10 weight percent graphite and 0 to 10 mole percent, based on moles of boron, of ammonia or an amine selected from the group consisting of mono-, di- and/or tri- alkyl amines of 1 to 10 carbon atoms.
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公开(公告)号：EP0033860A3
公开(公告)日：1981-10-14
申请号：EP81100347
申请日：1981-01-17
IPC分类号： C07B01/00 , C07C29/17 , C07C29/19 , C07C29/132 , C07C05/02 , C07D211/02 , C07D307/08 , C07C01/253 , C07C85/12 , C07C87/28 , C07C85/11
CPC分类号： C07D295/023 , C07C1/22 , C07C5/03 , C07C29/145 , C07C29/172 , C07C29/20 , C07C209/48 , C07C2523/755 , C07C2601/14 , C07C2602/44 , C07D307/08 , C07C13/40 , C07C13/18 , C07C31/10 , C07C31/12 , C07C31/207 , C07C35/08
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公开(公告)号：EP0121730A3
公开(公告)日：1987-10-21
申请号：EP84102150
申请日：1984-03-01
IPC分类号： C01B33/28 , B01J29/28 , C07C01/04 , C07C01/20 , C07C01/253
CPC分类号： C07C1/044 , B01J29/70 , C01B39/445 , C07C1/043 , C07C1/0435 , C07C1/20 , C07C2529/65 , C07C11/02
摘要： Crystalline aluminosilicates, a process for the production thereof and uses therefor are disclosed. The crystalline aluminosilicates are of new crystalline structure, which, as determined after calcination in the air at 550°C, have a composition represented by the general formula (I): pM 2/n O · Al 2 O 3 · qSiO 2 (the symbols are as defined in the appended claims) and give a principal X-ray diffraction. pattern as shown in Table 1. They are used as catalysts for the conversion of synthesis gas or oxygen-containing organic compounds such as alcohol, ether into hydrocarbons.
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公开(公告)号：EP0193282A3
公开(公告)日：1987-10-14
申请号：EP86300581
申请日：1986-01-29
CPC分类号： C07C6/126 , B01J29/70 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C01B39/48 , C07C1/20 , C07C2/66 , C07C5/271 , C07C6/123 , C07C2529/70 , C07C15/00
摘要： A synthetic porous crystalline zeolite having a distinctive X-ray diffraction pattern and designated as ZSM-58 has a composition in the as-synthesized form, on an anhydrous basis and in terms of moles of oxides per 100 moles of silica, expressed by the formula:
wherein M is an alkali or alkaline earth metal, n is the valence of M, and R is the methyltropinium cation of the formula (I). ZSM-58 is useful as a catalyst for aromatic and oxygenate conversion process. I-
公开(公告)号：EP0219042A3
公开(公告)日：1987-10-21
申请号：EP86113875
申请日：1986-10-07
CPC分类号： C07C1/24 , C07C2529/04 , C07C2529/40 , C07C2529/86 , C07C2529/88
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公开(公告)号：EP0209785A3
公开(公告)日：1987-06-10
申请号：EP86109258
申请日：1986-07-07
IPC分类号： C07C49/04 , C07C45/54 , C07C11/18 , C07C01/253
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