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公开(公告)号：EP0272830A3
公开(公告)日：1988-08-31
申请号：EP87310752
申请日：1987-12-07
CPC分类号： B01J21/18 , B01J29/084 , B01J37/0018 , B01J2229/123 , B01J2229/34 , C07C2/66 , C07C2521/04 , C07C2529/08 , C07C2529/60 , C07C2529/70
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公开(公告)号：EP0148147A3
公开(公告)日：1985-09-25
申请号：EP84870181
申请日：1984-12-19
CPC分类号： C07C2/66 , C07C2/864 , C07C2529/035 , Y02P30/42 , C07C15/02
摘要： A process for the selective alkylation of monoalkylbenzene into dialkylbenzenes wherein the para isomer of the disubstituted product is present in a concentration greater than in a thermodynamic equilibrium is provided. The method comprises passing the monoalkylbenzene and an alkylating agent capable of methylation. ethylation or propylation through a reaction zone containing an unmodified crystalline silica catalyst of the silicalite type having the monoclinic symmetry.
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3.发明公开Para-selective and beta-selective crystallized glass zeolite alkylation catalyst 失效PARA选择性和BETA选择性结晶玻璃沸石烷基化催化剂
公开(公告)号：EP0126245A3
公开(公告)日：1985-09-18
申请号：EP84103503
申请日：1984-03-29
CPC分类号： C07C2/66 , B01J29/86 , C07C2/864 , C07C2529/86 , Y10S423/22 , C07C15/00
摘要： There are provided crystallized borosilicate glass zeolite catalysts which are para-selective in the alkylation of benzene and derivatives thereof and beta-selective in the alkylation of naphthalene and derivatives thereof. There is provided a process for the production of such catalysts wherein a borosilicate type glass is reacted with a zeolite synthesis template. There is also provided a selective alkylation process for the alkylation of benzene and its derivatives and of naphthalene and its derivatives wherein these are reacted with an alkylation agent in the presence of such catalyst.
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公开(公告)号：EP0193282A3
公开(公告)日：1987-10-14
申请号：EP86300581
申请日：1986-01-29
CPC分类号： C07C6/126 , B01J29/70 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C01B39/48 , C07C1/20 , C07C2/66 , C07C5/271 , C07C6/123 , C07C2529/70 , C07C15/00
摘要： A synthetic porous crystalline zeolite having a distinctive X-ray diffraction pattern and designated as ZSM-58 has a composition in the as-synthesized form, on an anhydrous basis and in terms of moles of oxides per 100 moles of silica, expressed by the formula:
wherein M is an alkali or alkaline earth metal, n is the valence of M, and R is the methyltropinium cation of the formula (I). ZSM-58 is useful as a catalyst for aromatic and oxygenate conversion process. I-
5.发明公开
公开(公告)号：EP0161112A3
公开(公告)日：1986-07-30
申请号：EP85303229
申请日：1985-05-07
发明人： Mizui, Kinya , Takeda, Masami , Ozaki, Yoshimi , Tomita, Ryosuke
CPC分类号： C07C13/68 , C07C2/66 , C07C13/61 , C07C2603/68 , C07C2603/86
摘要： An aromatic hydrocarbon in which at least one hydrogen atom on the ring is substituted by a group selected from the class consisting of unsubstituted or lower alkyl-substituted tricyclo [5.2.1.0 1,6 ]dec-3-yl, tricyclo [5.2.1.0 2,6 ]dec-4-yl, tetracyclo [6.2.1.1 3,6 .0 2.7 ]dodec-4-yl and tetracyclo [6.2.1.1 3,6 .0 2,7 ]dodec-5-yl groups, or its hydrogenation product. The compound is prepared by reacting an aromatic hydrocarbon having at least one hydrogen atom on the ring with a compound selected from the group consisting of unsubstituted or lower alkyl-substituted tricyclo-[5.2.1.0 2,6 ]dec-3-ene and tetracyclo [6.2.1.1 3,6 .0 2,7 ]-dodec-4-ene in the presence of a Friedel-Crafts catalyst, or hydrogenating the thus- obtained compound in the presence of a hydrogenation catalyst. The compound is useful as an additive for adhesives.
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6.发明公开Method for promoting the activity and/or extending the life of cation-exchangeable layered clay catalysts in proton-catalysed reactions 失效用于促进活性和/或延长可交换层状催化剂在原子催化反应中的寿命的方法
公开(公告)号：EP0073141A3
公开(公告)日：1984-02-01
申请号：EP82304375
申请日：1982-08-19
发明人： Gregory, Reginald
CPC分类号： B01J21/16 , B01J29/049 , B01J2229/42 , C07C2/66 , C07C2/864 , C07C67/04 , C07C2521/16 , Y10S502/514 , C07C15/00 , C07C69/14
摘要： A method for promoting the activity and/or extending the life of a cation-exchangeable layered clay catalyst in reactions susceptible to catalysis by protons which method comprises the addition to the catalyst of water as the sole additive. The quantity of water employed is suitably up to 40°C. preferably up to 10% based on weight of reactants. The layered clay catalyst can be for example montmorillonite, bentonite or vermiculite. Suitable proton catalysed reactions include formation of esters, (eg by reaction of olefin and carboxylic acid), ethers, aldehydes, thioethers and alkylation and cracking reactions.
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公开(公告)号：EP0166454A3
公开(公告)日：1987-01-07
申请号：EP85108050
申请日：1985-06-28
CPC分类号： B41M5/1655
摘要： A solvent for the dye of pressure-sensitive recording paper which solvent has no offensive odor and both the color developing rate and the density of developed color are excellent. The solvent is is characterized in that it comprises a fraction having boiling points in the range of 270 to 350°C which is prepared by distilling the heavier products obtained from the process for producing ethyltoluene by alkylating toluene with ethylene in the presence of synthetic zeolite catalyst.
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8.发明公开
公开(公告)号：EP0177195A3
公开(公告)日：1986-05-28
申请号：EP85306337
申请日：1985-09-06
发明人： McWilliams, John Paul , Nemet-Mavrodin, Margaret Iosif , Sigal, Catherine Teague , Wilson, Robert Currin, Jr
IPC分类号： C07C07/148 , B01J21/10 , C07C06/12 , C07C02/66
CPC分类号： B01J37/0009 , B01J21/10 , C07C7/148 , C07C15/00
摘要： A method is provided for removing trace amounts of organic chlorides from feedstocks by contacting the feedstock with a guard bed catalyst comprising shaped particles formed by extruding a mixture of magnesium oxide and a binder inert to the feedstock. The process has particular importance in removing organic chlorides from toluene feedstocks prior to contacting toluene with a disporportionation or alkylation catalyst comprising magnesium-ZSM-5.
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9.发明公开Method for the synthesis of ZSM-5 zeolite, at atmospheric pressure and at low temperature 失效ZSM-5沸石合成方法，在大气压和低温条件下的合成
公开(公告)号：EP0129239A3
公开(公告)日：1985-08-28
申请号：EP84106970
申请日：1984-06-18
申请人： Montedison S.p.A.
CPC分类号： C07C6/123 , B01J29/40 , B01J2229/20 , B01J2229/37 , B01J2229/38 , C01B39/40 , C07C1/20 , C07C2/66 , C07C5/2708 , C07C2529/40 , C07C11/02 , C07C15/067
摘要： Method for the synthesis of ZSM-5 zeolites at atmospheric pressure, at a temperature preferably from 60 to 100°C wherein:
a) an aqueous solution containing a quaternary ammonium compound (OA) is added to a second aqueous solution, containing a Si compound, a Na compound and a potassium halogenide (K Hal.), according to the molar ratios:
-Na 2 O/SiO 2 ≥0.20 (preferably from 0.25 to 2); -H 2 O/SiO 2 = = from 5 to 100 (preferably from 10 to 50); -K Hal/SiO 2 = from 0.03 to 0.50; b) a third aqueous solution, containing A1 sulphate, is added to the mixture obtained according to a); c) to the mixture obtained according to b) an aqueous solution of H 2 SO 4 is added;
wherein the molar ratio Y = (QA/SiO 2 ) is from 0.02 to 0.08 and the molar ratio Z = SiO 2 /Al 2 O 3 is from 25 to 210, said Y ratio and the molar ratio X = OH - /SiO 2 being represented by points lying within triangles limited by the following 3 straight lines:
A) Y = 0.7 X; B) X = K/Z, wherein K = 4 (K being constant); C) Y = - 2/3 X + 1 - H, wherein the constant H is obtained from the expression: H = 1/2 (45/Z) 0,317 .-
10.发明公开Silica-modified catalyst and use for selective production of para-dialkyl substituted benzenes 失效二氧化硅改性催化剂和用于选择性生产对二苯基取代的苯乙烯的用途
公开(公告)号：EP0128721A3
公开(公告)日：1986-09-24
申请号：EP84303751
申请日：1984-06-04
CPC分类号： C07C6/126 , B01J29/40 , B01J29/65 , B01J29/70 , B01J29/80 , B01J37/0219 , B01J37/082 , B01J37/086 , B01J2229/12 , B01J2229/32 , C07C2/66 , C07C2/861 , C07C2/864 , C07C2/865 , C07C2/868 , C07C6/123 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/08
摘要： The present invention relates to a method for preparing a zeolite composition comprising a crystalline zeolite having deposited thereon a coating of silica which extensively covers and resides substantially exclusively on the external surface thereof, and to the composition so prepared. The present invention also relates to a process for the selective conversion of aromatic hydrocarbon feedstocks to a product rich in para-dialkyl substituted benzenes over a catalyst composition comprising such a silica-modified zeolite composition.
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