公开(公告)号：EP2958878A1

公开(公告)日：2015-12-30

申请号：EP14753994.4

申请日：2014-02-25

申请人： The Scripps Research Institute

发明人： PERIANA, Roy ,  HASHIGUCHI, Brian G. ,  KONNICK, Michael M. ,  BISCHOF, Steven M.

IPC分类号： C07C9/02 ,  C07C27/10 ,  C07C29/50

CPC分类号： C07C67/035 ,  C07C69/63

摘要： The invention provides processes and materials for the efficient and cost- effective functionalization of alkanes, such as methane from natural gas, to provide esters, alcohols, and other compounds. The method can be used to produce liquid fuels such as methanol from a natural gas methane-containing feedstock. The soft oxidizing electrophile, a compound of a main group, post- transitional element such as Tl, Pb, Bi, and I, that reacts to activate the alkane C- H bond can be regenerated using inexpensive regenerants such as hydrogen peroxide, oxygen, halogens, nitric acid, etc. Main group compounds useful for carrying out this reaction includes haloacetate salts of metals having a pair of available oxidation states, such as Tl, Pb, Bi, and I. The inventors herein believe that a unifying feature of many of the MXn electrophiles useful in carrying out this reaction, such as Tl, Pb, and Bi species, is their isoelectronic configuration in the alkane -reactive oxidation state; the electrons having the configuation [Xe]4f145d10, with an empty 6s orbital. However, the iodine reagents have a different electronic configuration.

公开(公告)号：EP1989161B1

公开(公告)日：2013-05-15

申请号：EP07763341.0

申请日：2007-01-30

申请人： Celanese International Corporation

发明人： MCSWAIN, C., V. ,  RYAN, Debra, Ann

IPC分类号： C07C27/10 ,  C07C51/16 ,  C07C67/055 ,  C07C51/25 ,  C07C51/215 ,  B01J23/00

CPC分类号： C07C51/25 ,  B01J23/002 ,  B01J2523/00 ,  C07C51/215 ,  C07C67/055 ,  Y02P20/125 ,  C07C53/08 ,  C07C69/01 ,  B01J2523/23 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/68 ,  B01J2523/824 ,  B01J2523/57 ,  B01J2523/64 ,  C07C69/15

公开(公告)号：EP1989161A4

公开(公告)日：2011-06-22

申请号：EP07763341

申请日：2007-01-30

申请人： CELANESE INT CORP

发明人： MCSWAIN C V ,  RYAN DEBRA ANN

IPC分类号： C07C27/10 ,  C07C51/16

CPC分类号： C07C51/25 ,  B01J23/002 ,  B01J2523/00 ,  C07C51/215 ,  C07C67/055 ,  Y02P20/125 ,  C07C53/08 ,  C07C69/01 ,  B01J2523/23 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/68 ,  B01J2523/824 ,  B01J2523/57 ,  B01J2523/64 ,  C07C69/15

公开(公告)号：EP2277847A2

公开(公告)日：2011-01-26

申请号：EP10176682.2

申请日：2002-07-17

申请人： GRT, Inc. ,  The Regents of The University of California

发明人： Zhou, Xiao, Ping ,  Lorkovic, Ivan, Marc ,  Sherman, Jeffrey A.

IPC分类号： C07C27/10 ,  C07C27/12 ,  C07C27/14 ,  C07C27/16 ,  C07C29/48 ,  C07B41/02 ,  B01J10/00 ,  B01J8/04 ,  B01J35/02 ,  B01J8/02 ,  B01J8/08

CPC分类号： C07C29/124 ,  C07C17/10 ,  C07C41/01 ,  C07C45/27 ,  Y02P20/125 ,  C07C19/075 ,  C07C31/08 ,  C07C43/06 ,  C07C47/06

摘要： Alcohols, ethers and olefins are manufactured from alkanes by mixing an alkane and bromine in a reactor to form alkyl bromide and hydrogen bromide. The alkyl bromide only or the alkyl bromide and the hydrogen bromide are directed into contact with the metal oxide to form an alcohol and/or ether, or an olefin and metal bromide. The metal bromide is oxidised to form original metal oxide and bromine, both of which are recycled.

摘要翻译： 醇，醚和烯烃由烷烃通过在反应器中混合烷烃和溴而形成烷基溴和溴化氢制成。 仅将烷基溴或烷基溴和溴化氢引导与金属氧化物接触以形成醇和/或醚，或烯烃和金属溴化物。 金属溴化物被氧化以形成原始金属氧化物和溴，这两者都被回收。

公开(公告)号：EP1474371A2

公开(公告)日：2004-11-10

申请号：EP02748199.3

申请日：2002-07-17

申请人： GRT, Inc. ,  The Regents of The University of California

发明人： ZHOU, Xiao, Ping ,  LORKOVIC, Ivan, Marc ,  SHERMAN, Jeffrey, A.

IPC分类号： C07C27/10 ,  C07C27/12 ,  C07C27/14 ,  C07C27/16 ,  C07C29/48 ,  C07B41/02 ,  B01J10/00 ,  B01J8/04 ,  B01J35/02 ,  B01J8/02 ,  B01J8/08

CPC分类号： C07C29/124 ,  C07C17/10 ,  C07C41/01 ,  C07C45/27 ,  Y02P20/125 ,  C07C19/075 ,  C07C31/08 ,  C07C43/06 ,  C07C47/06

摘要： Alcohols, ethers, and olefins are manufactured from alkanes by mixing an alkane and bromine in a reactor to form alkyl bromide and hydrogen bromide. The alkyl bromide only or the alkyl bromide and the hydrogen bromide are directed into contact with metal oxide to form an alcohol and/or an ether, or an olefin and metal bromide. The metal bromide is oxidized to form original metal oxide and bromine, both of which are recycled.

公开(公告)号：EP1303471A4

公开(公告)日：2004-10-20

申请号：EP01950851

申请日：2001-07-05

申请人： SAUDI BASIC IND CORP ,  KHANMAMEDOVA ALLA KONSTANTIN

发明人： KHANMAMEDOVA ALLA KONSTANTIN

IPC分类号： B01J23/66 ,  B01J21/08 ,  B01J23/52 ,  B01J23/58 ,  B01J31/04 ,  B01J31/30 ,  B01J37/02 ,  B01J37/03 ,  B01J37/06 ,  B01J37/16 ,  B01J37/18 ,  C07B61/00 ,  C07C67/055 ,  C07C69/15 ,  C07C27/10 ,  B01J23/44 ,  B01J23/48 ,  B01J23/56 ,  C07C51/02 ,  C07C51/16 ,  C07C67/00 ,  C07C67/05

CPC分类号： B01J31/30 ,  B01J21/08 ,  B01J23/52 ,  B01J23/58 ,  B01J31/04 ,  B01J37/0203 ,  B01J37/031 ,  B01J37/06 ,  B01J37/16 ,  B01J37/18 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： A shell impregnated catalyst of Pd-Au produced on a silica support to have a Pd loading of 1.8 g/L of catalyst to about 7.2 g/L and a Au to Pd weight ratio of 0.3 to 2.0 by impregnating the support with aqueous solutions of palladium and gold salts or acids and thereafter precipitating water insoluble compounds of Pd and Au on the with alkali metal silicate or hydroxide solutions, then dried, and the surface precipitated compounds of Pd and Au are then reduced by reaction with ethylene or hydrogen at a temperature of greater than 150 °C up to 310 °C or with hydrogen up to 299 °C until substantially all of the Pd and Au contents are reduced to a free metal state, after which the support is impregnated with potassium acetate to an extent of 6 to 7 weight percent of the weight of the total catalyst. For production of vinyl acetate (VA) such catalyst has a space-time yield (STY) and specific activity (SA) about 20-30 % greater than an otherwise identical catalyst composition that is formed from impregnated support reduced at 150 °C, and in a temperature range of 140 °C to 160 °C at a gas hourly space velocity of 4500/hr will at 120 psig exhibit a VA selectivity of 90 % or greater when operated under reaction conditions that result in a STY of at least 600.

公开(公告)号：EP1019346B1

公开(公告)日：2003-05-07

申请号：EP98910139.9

申请日：1998-01-07

申请人： Catalytic Distillation Technologies

发明人： NEMPHOS, Speros, P. ,  GROTEN, Willibrord, A. ,  ADAMS, John, R.

IPC分类号： C07C27/10 ,  C07C29/00 ,  C07C27/00 ,  C07C29/151

CPC分类号： C07C29/1512 ,  C07C31/04

公开(公告)号：EP4210868A1

公开(公告)日：2023-07-19

申请号：EP21787142.5

申请日：2021-09-09

申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP

发明人： MONWAR, Masud, M. ,  BARR, Jared, L. ,  CRUZ, Carlos, A. ,  CLEAR, Kathy, S. ,  MCDANIEL, Max, P. ,  ELLIS, William Chad

IPC分类号： B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  C07C27/10 ,  C07C29/48 ,  C07C45/27 ,  C07C51/16 ,  B01J37/34 ,  B01J37/16 ,  B01J35/00

公开(公告)号：EP3347331B1

公开(公告)日：2019-08-21

申请号：EP16760066.7

申请日：2016-09-01

申请人： SABIC Global Technologies B.V.

发明人： SUBRAMANIAN, Selvakumar ,  DANIËLS, Dimitri ,  WONG, Kae ,Shin ,  WARD, Andrew Mark

IPC分类号： C07C2/66 ,  C07C15/02 ,  C07C15/085 ,  C07C27/10 ,  C07C37/58 ,  C07C39/04 ,  C07C45/36 ,  C07C49/08 ,  C07C49/10

公开(公告)号：EP2893326A1

公开(公告)日：2015-07-15

申请号：EP13835425.3

申请日：2013-09-05

申请人： Powerdyne, Inc.

发明人： HIRSON, Geoffrey ,  SHOUSE, Gus F.

IPC分类号： G01N21/75 ,  H05H1/42 ,  C07C27/10

CPC分类号： C10L1/04 ,  B01D21/0009 ,  B01D21/01 ,  B01J12/002 ,  B01J19/088 ,  B01J2219/00063 ,  B01J2219/00162 ,  B01J2219/00186 ,  B01J2219/0809 ,  B01J2219/0815 ,  B01J2219/0871 ,  B01J2219/0875 ,  B01J2219/0877 ,  B01J2219/0879 ,  B01J2219/0892 ,  B01J2219/0898 ,  B09B3/005 ,  C01B3/02 ,  C01B3/042 ,  C01B3/12 ,  C01B2203/0283 ,  C01B2203/062 ,  C01B2203/0861 ,  C07C1/04 ,  C10G2/32 ,  C10G2/332 ,  C10G2/333 ,  C10G2/50 ,  C10J3/00 ,  C10J2300/1238 ,  C10J2300/1671 ,  C10J2300/1675 ,  C10L1/06 ,  C10L1/08 ,  C10L2200/0415 ,  C10L2200/0423 ,  C10L2200/043 ,  C10L2200/0446 ,  C10L2200/0492 ,  C10L2270/023 ,  C10L2270/026 ,  C10L2270/04 ,  C10L2290/06 ,  C10L2290/30 ,  C10L2290/38 ,  C10L2290/42 ,  F01K25/06 ,  F02C1/05 ,  H05H1/34 ,  H05H1/42 ,  H05H1/44 ,  H05H1/48 ,  Y02E50/32 ,  Y02E60/364 ,  Y02P20/13

摘要： Methods of making fuel are described herein. A method may include providing a first working fluid, a second working fluid, and a third working fluid. The method may also include exposing the first working fluid to a first high voltage electric field to produce a first plasma, exposing the second working fluid to a second high voltage electric field to produce a second plasma, and exposing the third working fluid to a third high voltage electric field to produce a third plasma. The method may also include providing and contacting a carbon-based feedstock with the third plasma, the second plasma, and the first plasma within a processing chamber to form a mixture, cooling the mixture using a heat exchange device to form a cooled mixture, and contacting the cooled mixture with a catalyst to form a fuel.

摘要翻译： 这里描述了制造燃料的方法。 一种方法可以包括提供第一工作流体，第二工作流体和第三工作流体。 该方法还可以包括将第一工作流体暴露于第一高压电场以产生第一等离子体，将第二工作流体暴露于第二高压电场以产生第二等离子体，并且将第三工作流体暴露于第三工作流体 高电压电场以产生第三等离子体。 该方法还可以包括在处理室内提供碳基原料并与第三等离子体，第二等离子体和第一等离子体接触以形成混合物，使用热交换装置冷却混合物以形成冷却的混合物，以及 使冷却的混合物与催化剂接触以形成燃料。