公开(公告)号：EP2399889A1

公开(公告)日：2011-12-28

申请号：EP11172990.1

申请日：2009-07-17

申请人： GRT, Inc.

发明人： Gadewar, Sagar ,  Zhang, Aihua ,  Julka, Vivek ,  McFarland, Eric, W. ,  Grosso, Philip ,  Janmachi, Krishna ,  Sardar, Saydul, Amin ,  Stoimenov, Peter ,  Komon, Zachary, J.A. ,  Lin, Hongfei ,  Cutler, Charles, Ian ,  Cheng, Jihong ,  Wheeler, Jean ,  Sun, Shouli ,  Auerbach, Daniel, J. ,  Wyrsta, Michael, D. ,  Coronella, Charles, J. ,  Huff, Shawn

IPC分类号： C07C2/00 ,  C07C1/26

CPC分类号： B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/16 ,  B01J2229/183 ,  B01J2229/186 ,  C01B7/01 ,  C01B7/093 ,  C01B7/096 ,  C01B7/13 ,  C01B7/19 ,  C07C1/26 ,  C07C17/10 ,  C07C17/37 ,  C07C2529/40 ,  C07C2529/46 ,  C07C2529/70 ,  C07C2529/83 ,  C07C2529/85 ,  Y02P20/584 ,  Y02P20/588 ,  C07C11/02 ,  C07C15/02 ,  C07C19/075

摘要： A method comprising: providing a first halogen stream; providing a first alkane stream; reacting at least a portion of the first halogen stream with at least a portion of the first alkane stream in a first reaction vessel to form a first halogenated stream; providing a second alkane stream comprising C 2 and higher hydrocarbons; providing a second halogen stream; and reacting at least a portion of the second halogen stream with at least a portion of the second alkane stream in a second reaction vessel to form a second halogenated stream.

摘要翻译： 一种方法，包括：提供第一卤素流; 提供第一烷烃物流; 在第一反应容器中使至少一部分第一卤素流与至少一部分第一烷烃流反应以形成第一卤化流; 提供包含C 2和更高级烃的第二烷烃物流; 提供第二卤素流; 以及使第二卤素流的至少一部分与第二反应容器中的至少一部分第二烷烃流反应以形成第二卤化流。

公开(公告)号：EP1435349B1

公开(公告)日：2011-08-10

申请号：EP04075889.8

申请日：2002-06-13

申请人： GRT, Inc. ,  The Regents of The University of California

发明人： Zhou, Xiao P. ,  Lorkovic, Ivan M. ,  Stucky, Galen, D. ,  Ford, Peter, C. ,  Sherman, Jeffrey, H. ,  Grosso, Philip

IPC分类号： C07C29/124 ,  C07C31/04 ,  C07C41/01 ,  C07C43/04 ,  C07C17/10 ,  C07C19/075

CPC分类号： C07C29/124 ,  C07C17/10 ,  C07C41/01 ,  C07D301/26 ,  Y02P20/125 ,  C07C19/075 ,  C07C31/04 ,  C07C43/043

公开(公告)号：EP2277847A3

公开(公告)日：2011-07-27

申请号：EP10176682.2

申请日：2002-07-17

申请人： GRT, Inc. ,  The Regents of The University of California

发明人： Zhou, Xiao, Ping ,  Lorkovic, Ivan, Marc ,  Sherman, Jeffrey A.

IPC分类号： C07C27/10 ,  C07C27/12 ,  C07C27/14 ,  C07C27/16 ,  C07C29/48 ,  C07B41/02 ,  B01J10/00 ,  B01J8/04 ,  B01J35/02 ,  B01J8/02 ,  B01J8/08

CPC分类号： C07C29/124 ,  C07C17/10 ,  C07C41/01 ,  C07C45/27 ,  Y02P20/125 ,  C07C19/075 ,  C07C31/08 ,  C07C43/06 ,  C07C47/06

摘要： Alcohols, ethers and olefins are manufactured from alkanes by mixing an alkane and bromine in a reactor to form alkyl bromide and hydrogen bromide. The alkyl bromide only or the alkyl bromide and the hydrogen bromide are directed into contact with the metal oxide to form an alcohol and/or ether, or an olefin and metal bromide. The metal bromide is oxidised to form original metal oxide and bromine, both of which are recycled.

公开(公告)号：EP1682465A1

公开(公告)日：2006-07-26

申请号：EP04778505.0

申请日：2004-07-15

申请人： GRT, Inc. ,  The Regents of the University of California

发明人： LORKOVIC, Ivan, M. ,  NOY, Maria ,  SHERMAN, Jeffrey, H. ,  WEISS, Michael, J. ,  STUCKY, Galen, D.

IPC分类号： C07C1/26

CPC分类号： C07C1/26 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2529/18 ,  C07C2529/40 ,  Y10S585/935 ,  Y10S585/943

摘要： A method of synthesizing hydrocarbons from smaller hydrocarbons includes the steps of hydrocarbon halogenation, simultaneous oligornerization and hydrogen halide neutralization, and product recovery, with a metal-oxygen cataloreactant used to facilitate carbon-carbon coupling. Treatment with air or oxygen liberates halogen and regenerates the cataloreactant.

公开(公告)号：EP1435349A3

公开(公告)日：2004-08-04

申请号：EP04075889.8

申请日：2002-06-13

申请人： GRT, Inc. ,  The Regents of the University of California

发明人： Zhou, Xiao P. ,  Lorkovic, Ivan M. ,  Stucky, Galen, D. ,  Ford, Peter, C. ,  Sherman, Jeffrey, H. ,  Grosso, Philip

IPC分类号： C07C29/124 ,  C07C31/04 ,  C07C41/01 ,  C07C43/04 ,  C07C17/10 ,  C07C19/075

CPC分类号： C07C29/124 ,  C07C17/10 ,  C07C41/01 ,  C07D301/26 ,  Y02P20/125 ,  C07C19/075 ,  C07C31/04 ,  C07C43/043

摘要： The present invention provides a method for synthesizing alcohols and/or ethers, from alkanes comprising: providing a quantity of an alkane selected from the group consisting of methane, ethane, propane, butane, and isobutane; providing a quantity of bromine; mixing the alkane and the bromine and thereby forming an alkyl bromide and hydrogen bromide; reacting the alkyl bromide and the hydrogen bromide with a metal oxide and thereby forming alcohol and/or ether and a metal bromide; oxidizing the metal bromide to form the original metal oxide and bromine; recycling the metal oxide; and recycling the bromine. The present invention further provides a method for converting methanol to dimethyl ether.

公开(公告)号：EP2326610A4

公开(公告)日：2011-12-28

申请号：EP09798794

申请日：2009-07-17

申请人： GRT INC

发明人： GADEWAR SAGAR ,  ZHANG AIHUA ,  JULKA VIVEK ,  MCFARLAND ERIC W ,  GROSSO PHILIP ,  JANMANCHI KRISHNA ,  SARDAR SAYDUL AMIN ,  STOIMENOV PETER ,  KOMON ZACHARY J A ,  LIN HONGFEI ,  CUTLER CHARLES IAN ,  CHENG JIHONG ,  WHEELER JEAN ,  SUN SHOULI ,  AUERBACH DANIEL J ,  WYRSTA MICHAEL D ,  CORONELLA CHARLES J ,  HUFF SHAWN

IPC分类号： C07C2/00 ,  C07C1/26

CPC分类号： C07C17/10 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/16 ,  B01J2229/183 ,  B01J2229/186 ,  C01B7/01 ,  C01B7/093 ,  C01B7/096 ,  C01B7/13 ,  C01B7/19 ,  C07C1/26 ,  C07C17/37 ,  C07C2529/40 ,  C07C2529/46 ,  C07C2529/70 ,  C07C2529/83 ,  C07C2529/85 ,  Y02P20/127 ,  Y02P20/584 ,  Y02P20/588 ,  C07C15/02 ,  C07C11/02 ,  C07C19/075

公开(公告)号：EP1474371B1

公开(公告)日：2011-12-21

申请号：EP02748199.3

申请日：2002-07-17

申请人： GRT, Inc. ,  The Regents of The University of California

发明人： ZHOU, Xiao, Ping ,  LORKOVIC, Ivan, Marc ,  SHERMAN, Jeffrey, A.

IPC分类号： C07C27/10 ,  C07C27/12 ,  C07C27/14 ,  C07C27/16 ,  C07C29/48 ,  C07B41/02 ,  B01J10/00 ,  B01J8/04 ,  B01J35/02 ,  B01J8/02 ,  B01J8/08

CPC分类号： C07C29/124 ,  C07C17/10 ,  C07C41/01 ,  C07C45/27 ,  Y02P20/125 ,  C07C19/075 ,  C07C31/08 ,  C07C43/06 ,  C07C47/06

摘要： Alcohols, ethers, and olefins are manufactured from alkanes by mixing an alkane and bromine in a reactor to form alkyl bromide and hydrogen bromide. The alkyl bromide only or the alkyl bromide and the hydrogen bromide are directed into contact with metal oxide to form an alcohol and/or an ether, or an olefin and metal bromide. The metal bromide is oxidized to form original metal oxide and bromine, both of which are recycled.

公开(公告)号：EP1773736A4

公开(公告)日：2010-08-11

申请号：EP05712315

申请日：2005-02-02

申请人： GRT INC

发明人： GROSSO PHILIP ,  SHERMAN JEFFREY H ,  MCFARLAND ERIC W

IPC分类号： C07C1/26 ,  C07C29/124 ,  C07C41/01

CPC分类号： C07C29/124 ,  C07C1/30 ,  Y02P20/125 ,  C07C11/02 ,  C07C31/04

公开(公告)号：EP2060552A3

公开(公告)日：2010-05-26

申请号：EP08075757.8

申请日：2002-06-13

申请人： GRT, Inc. ,  The Regents of the University of California

发明人： Zhou, Xiao Ping ,  Lorkovic, Ivan Marc ,  Stucky, Galen D. ,  Ford, Peter C. ,  Sherman, Jeffrey H. ,  Grosso, Philip

IPC分类号： C07C29/124 ,  C07C31/04 ,  C07C41/01 ,  C07C43/04 ,  C07C17/10 ,  C07C19/075 ,  B01J8/26

CPC分类号： C07C29/124 ,  C07C17/10 ,  C07C41/01 ,  C07D301/26 ,  Y02P20/125 ,  C07C19/075 ,  C07C31/04 ,  C07C43/043

摘要： An apparatus for converting alkanes to alcohols and/or ethers is disclosed said comprising:
a reactor;
means for directing methane and bromine into the reactor to produce methyl bromide and hydrogen bromide;
a first converter comprising a solid metal oxide;
means for directing alkyl bromide from the reactor into contact with the metal oxide of the converter to form an alcohol and/or ether, and the metal bromide;
a second converter comprising a solid metal oxide;
means for directing hydrogen bromide from the reactor into contact with the metal oxide of the second converter to form water and metal bromide;
means for converting the metal bromides from the first and second converters to form the original metal oxides and bromine; and
means for recycling the metal oxides and the bromine.

公开(公告)号：EP1773736A2

公开(公告)日：2007-04-18

申请号：EP05712315.0

申请日：2005-02-02

申请人： GRT, Inc.

发明人： GROSSO, Philip ,  SHERMAN, Jeffrey, H. ,  MCFARLAND, Eric, W.

IPC分类号： C07C1/26

CPC分类号： C07C29/124 ,  C07C1/30 ,  Y02P20/125 ,  C07C11/02 ,  C07C31/04

摘要： In a method of converting alkanes to their corresponding alcohols, ethers, olefins, and other hydrocarbons, a vessel comprises a hollow, unsegregated interior defined first, second, and third zones. In a first embodiment of the invention oxygen reacts with metal halide in the first zone to provide gaseous halide; halide reacts with the alkane in the second zone to form alkyl halide; and the alkyl halide reacts with metal oxide in the third zone to form a hydrocarbon corresponding to the original alkane. Metal halide from the third zone is transported through the vessel to the first zone and metal oxide from the first zone is recycled to the third zone. A second embodiment of the invention differs from the first embodiment in that metal oxide is transported through the vessel from the first zone to the third zone and metal halide is recycled from the third zone to the first zone. In a third embodiment of the invention the flow of gases through the vessel is reversed to convert the metal oxide back to metal halide and to convert the metal halide back to the metal oxide.