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1.发明公开Isocyanate reactive mixture and the use thereof in the manufacture of flexible polyurethane foams 失效异氰酸酯反应混合物及其在柔性聚氨酯泡沫塑料制造中的应用
公开(公告)号：EP0421220A3
公开(公告)日：1991-05-15
申请号：EP90118263.4
申请日：1990-09-22
申请人： MILES INC.
发明人： Milliren, Charles M.
CPC分类号： C08G18/5027 , C08G18/482 , C08G18/5048 , C08G18/6685 , C08G2101/0008 , C08G2101/005
摘要： The present invention is directed to a reactive mixture for use in preparing a flexible polyurethane foam and to the foams produced therefrom. The reactive mixture broadly comprises an isocyanate reactive composition comprising:
A) from more than 0 up to 3 parts by weight per 100 parts by weight of components B) and C) of an amine of the formula:
H₂N - R - NH₂
where R is a C₃ to C₁₀ straight or branched alkylene group or a C₄ to C₁₅ alicyclic group, B) from more than 0 up to 40% by weight of a relatively high molecular weight compound containing at least two aromatically bound primary amine groups, and C) from 60 to less than 100% by weight of one or more polyether polyhydroxyl compounds having hydroxyl functionalities of from 2 to 3 and molecular weights of from about 1000 to about 10,000, the percents by weight of component B) and component C) totalling 100%.-
公开(公告)号：EP0293060A3
公开(公告)日：1990-02-14
申请号：EP88300087.9
申请日：1988-01-07
申请人： HITACHI, LTD.
发明人： Naka, Reishi , Kuroishi, Kazuyoshi
CPC分类号： C08G18/4812 , C08G18/482 , C08G18/5033 , C08G2101/0025 , C08G2101/005 , Y10T428/24355 , Y10T428/24372 , Y10T428/24388 , Y10T428/261 , Y10T428/31663
摘要： Rigid polyurethane foams produced by reacting a polyol component having a special composition with an isocyanate component in the presence of a blowing agent, a reaction catalyst and a foam stabilizer with a mold release time of as short as 5.5 minutes or less, have remarkably low thermal conductivity of 12.5 x 10⁻³ Kcal/m.hr.°C or less and a low density and are suitable as heat insulating materials for refrigerators and the like.
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3.发明公开Polyurethane foam prepared using high functionality cell openers and process for preparing the same 失效聚氨酯泡沫塑料，通过用高功能zellföffnender化合物，并涉及其制备方法制造。
公开(公告)号：EP0339369A1
公开(公告)日：1989-11-02
申请号：EP89106507.0
申请日：1989-04-12
发明人： Nichols, Jerram B. , Hunter, Douglas L. , Herrington, Ronald M. , Serratelli, John F. , Carey, David G.
CPC分类号： C08G18/4804 , C08G18/4018 , C08G18/4072 , C08G18/4837 , C08G2101/0008 , C08G2101/0041 , Y10S521/914
摘要： Flexible polyurethane foams are prepared using certain high molecular weight, high functionality poly-(oxyethylene) compounds as cell openers and softeners. These high functionality polyether polyols have been found to be very effective in opening the cells of the foam, even when used in making foams based on PIPA polyols, which are notoriously closed-celled. They are also quite effective in softening foams made using MDI-based polyisocyanates.
摘要翻译： 柔性聚氨酯泡沫是使用某些高分子量，高功能上的聚（氧乙烯）化合物作为泡孔扩张剂和软化剂来制备。 在聚醚多元醇这些高功能已被发现在打开泡沫细胞非常有效，即使在做基于PIPA多元醇的泡沫，这是众所周知的闭孔使用。 因此，他们是在软化泡沫相当有效使用基于MDI的多异氰酸酯制成。
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公开(公告)号：EP0121850B1
公开(公告)日：1989-08-30
申请号：EP84103295.6
申请日：1984-03-26
申请人： BAYER AG
CPC分类号： C08G18/3296 , C08G18/6535 , Y10S521/904
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公开(公告)号：EP0276927A3
公开(公告)日：1989-07-26
申请号：EP88300300.6
申请日：1988-01-14
发明人： Brasington, Robert David BP Chemicals Suisse S.A. , Lidy, Werner August BP Chemicals Suisse S.A.
CPC分类号： C08G18/632 , C08G18/10 , C08G18/7664
摘要： Storage stable prepolymers of pure or crude MDI are provided. The prepolymers are prepared by reacting the pure or crude MDI with a polymer polyol comprising (1) 50 to 99% by weight of a polyoxyalkylene polyol having an average functionality in the range 1,000 to 10,000 and comprising 1 to 80% by weight ethylene oxide and (2) 1 to 50% by weight of a polymer of one or more vinyl monomers. Cold cure flexible polyurethane foams produced from such prepolymers have a more open cellular structure relative to prior art materials.
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6.发明公开Rigid polyurethane foam and process for producing the same 失效Steifer Polyurethanschaumstoff und Verfahren zu seiner Herstellung。
公开(公告)号：EP0293060A2
公开(公告)日：1988-11-30
申请号：EP88300087.9
申请日：1988-01-07
申请人： HITACHI, LTD.
发明人： Naka, Reishi , Kuroishi, Kazuyoshi
CPC分类号： C08G18/4812 , C08G18/482 , C08G18/5033 , C08G2101/0025 , C08G2101/005 , Y10T428/24355 , Y10T428/24372 , Y10T428/24388 , Y10T428/261 , Y10T428/31663
摘要： Rigid polyurethane foams produced by reacting a polyol component having a special composition with an isocyanate component in the presence of a blowing agent, a reaction catalyst and a foam stabilizer with a mold release time of as short as 5.5 minutes or less, have remarkably low thermal conductivity of 12.5 x 10⁻³ Kcal/m.hr.°C or less and a low density and are suitable as heat insulating materials for refrigerators and the like.
摘要翻译： 在发泡剂，反应催化剂和脱泡时间短至5.5分钟以下的泡沫稳定剂存在下，使具有特殊成分的多元醇成分与异氰酸酯成分反应而制得的刚性聚氨酯泡沫具有显着低的热 电导率为12.5×10 -3 Kcal / m·hr。 ℃以下，密度低，适用于冰箱等的隔热材料。
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7.发明公开Polyurethane foams incorporating alkoxylated aromatic diamine and acetylenic glycol 失效含有烷氧基芳族二胺和乙酰甘氨酸的聚氨酯
公开(公告)号：EP0255930A3
公开(公告)日：1988-09-21
申请号：EP87111198
申请日：1987-08-03
CPC分类号： C08G18/30 , C08G18/6535 , C08G18/679 , C08G2105/02
摘要： This invention relates to crosslinker systems for polyurethane foams and a process for producing such foams. The polyurethanes are prepared by reacting an organic polyisocyanate with an organic compound having active Zerewitenoff hydrogen atoms, e.g., a polyol with an alkoxylated aromatic diamine crosslinker and an acetylenic glycol. Improved properties can be achieved, such as, higher load-bearing at equivalent foam density; higher tear; higher elongation and higher air flow.
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8.发明授权Verfahren zur Herstellung lagerstabiler Cyanamidlösungen in Polyolen, einphasig homogene Cyanamidlösungen und ihre Verwendung 失效多相稳定的CYANAMIDE解决方案的制备方法，单相均质的半胱氨酸解决方案及其使用
公开(公告)号：EP0160813B1
公开(公告)日：1988-08-31
申请号：EP85103097.3
申请日：1985-03-18
申请人： BAYER AG
CPC分类号： C08G18/6607 , C08G18/3838 , C08G2130/00 , C08K5/315 , C08L71/02
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9.发明公开Isocyanate terminated quasi-prepolymers useful for preparing polyurethane/polyisocyanurate foams having low thermal conductivity 失效对具有低导热率的聚氨酯 - 聚异氰脲泡沫的制备异氰酸酯端基的半预聚物。
公开(公告)号：EP0278412A2
公开(公告)日：1988-08-17
申请号：EP88101659.6
申请日：1988-02-05
申请人： BASF Corporation
CPC分类号： C08G18/4211 , C08G18/10 , C08G2101/0025 , Y10S521/902 , C08G18/022 , C08G18/092
摘要： Polyurethane/polyisocyanurate rigid foams having low thermal conductivity are prepared from isocyanate-terminated quasi-prepolymers prepared from polyester polyols derived from phthalic anhydride or from the transesterification of polyethylene terephthalate scrap.
摘要翻译： 具有低导热性的聚氨酯/聚异氰脲硬质泡沫体是由从由邻苯二甲酸酐或对苯二甲酸乙二醇酯废料的酯交换衍生的聚酯多元醇制备的异氰酸酯封端的准预聚物制备的。
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10.发明公开Polyurethane prepolymers from oleochemic polyols, their preparation and use 失效聚氨酯多元醇的聚氨酯预处理剂，其制备和使用
公开(公告)号：EP0256355A3
公开(公告)日：1988-08-10
申请号：EP87110750
申请日：1987-07-24
IPC分类号： C08G18/76 , C08G18/36 , C08G18/48 , C08G18/12 , C08G18/14 , C08G18/20 , C08K05/52 , C08L75/04 , C07C41/03 , C07C67/03
CPC分类号： C08G18/36 , C08G18/6629 , C08G2101/00
摘要： Die Erfindung betrifft Polyurethan-Prepolymere mit endständigen Isocyanatgruppen, enthaltend einen stö chiometrischen Überschuß an einem oder mehreren aro matischen Isocyanaten mit im Mittel zwei bis vier Iso cyanatgruppen pro Molekül als Isocyanatkomponente und ein aus oleochemischen, wenigstens partiell ungesät tigten Triglyceriden durch Epoxidation und anschlie ßende Ringöffnung mit einem Alkohol hergestelltes Polyol als Polyolkomponente, sowie Beschleuniger, Flammschutzzusätze, Treibmittel und gegebenenfalls Verflüssiger, Farbstoffe und/oder Stabilisatoren, wo bei sie als Polyolkomponente ein oder mehrere Ester polyole oleochemischer Herkunft enthalten, die keine freien Epoxidgruppen aufweisen, durch vollständige Ringöffnung von epoxidierten Triglyceriden eines we nigstens teilweise olefinisch ungesättigte Fettsäuren enthaltenden Fettsäuregemisches mit einem oder mehre ren Alkoholen mit 1 bis 12 C-Atomen sowie Umesterung der Triglyceridderivate zu Alkylesterpolyolen mit 1 bis 12 C-Atomen im Alkylrest hergestellt worden sind, ein Verfahren zur Herstellung derartiger Polyurethan- Prepolymere und ihre Verwendung als Ausgangsstoffe für die Herstellung von Polyurethanschäumen.
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