摘要:
Provided is an additive for a positive electrode of a lithium secondary battery, the additive including a lithium transition metal oxide, Li 3 PO 4 , Li 5 AlO 4 and Li 3 BO 3 . The lithium transition metal oxide has an aluminum-doped form. The additive including Li 3 PO 4 , Li 5 AlO 4 and Li 3 BO 3 together with the lithium transition metal oxide has functionality of improving stability of a battery when used in a positive electrode of a lithium secondary battery. Specifically, a general lithium transition metal oxide causes a side reaction with an electrolyte liquid when used in a positive electrode of a lithium secondary battery causing a problem of decreasing stability such as generating gas in the battery, however, the Li 3 PO 4 , the Li 5 AlO 4 and the Li 3 BO 3 are evenly mixed with the lithium transition metal oxide or some thereof form a partial coating layer, or a portion of aluminum is doped to the lithium transition metal oxide to suppress the lithium transition metal oxide from causing a side reaction with an electrolyte liquid.
摘要:
The invention relates to a process for producing alpha lithium aluminate comprising the following steps: 1) preparing an aqueous dispersion comprising a fumed alumina, a lithium oxide precursor compound soluble in water and an alkali metal and/or an ammonium carbonate; 2) Spray drying of the dispersion prepared in step 1) to obtain a dried powder; 3) Calcining the dried powder obtained in step 2) at a temperature of from 450°C to 750°C. Lithium aluminate obtainable by this process can be used in lithium ion batteries.
摘要:
A comprehensive recycling method, economically optimized, simple to implement and with the simplest equipment. The alkaline wastes produced by Aluminum extrusion industries (coming from the alkaline washing of Aluminum dies, alkaline surface treatment of Aluminum, etc.), produced in any concentration are collected and stored, as well as the Alumina containing sludge (in the form of Aluminum hydroxide) that was formed at various stages of collection and processing as, also, the resulting Alumina sludge coming from Alumina- Soda recovery plants. Then, the solutions, in decreasing order of preference I) are mixed to appropriate concentrations of Al and NaOH, II) are reacted in open (atmospheric pressure) heated tanks with calculated amounts of Alumina sludge, III) are reacted in open (atmospheric pressure) tanks with calculated amounts of Aluminum metal scrap, of the same or other plants, and turns after clarification, filtration and packaging, in to all possible concentrations of sodium aluminate solution products for use as a suitable alkaline coagulant for acidic and hypo-acidic waste waters and as a concrete coagulation accelerator. The method is economically optimized and does not produce byproducts or wastes.
摘要:
This invention relates to a method for preparing an activated alumina lithium intercalate composition by contacting a three-dimensional structured porous activated alumina with a lithium salt under conditions sufficient to infuse lithium salts into three-dimensionally structured porous activated alumina, and the use of the activated alumina lithium intercalate composition for the selective extraction and recovery of lithium from lithium containing solutions, including brines.
摘要:
Die Erfindung betrifft ein Verfahren zur Herstellung sinterfähiger Pulver für binäre und multinäre, keramische Oxidwerkstoffe. Nach dem erfindungsgemäßen Verfahren lassen sich oxidkeramische Produkte gewinnen, die wegen ihres feinteiligen Charakters schon nach angemessen niedrigen Kalzinationstemperaturen zur pulvermetallurgischen Formgebung besonders geeignet sind. Im Verlaufe des Herstellungsverfahrens werden in alkoholischer Suspension aus den jeweiligen Hydroxidgemischen organische Phasen gebildet, die zum Teil erst bei höheren Temperaturen zerfallen. Hierdurch wird das Aufschmelzen der Hydroxide mit niedrigen Schmelzpunkten unterdrückt, wodurch das Aufmahlen der Pulver vermieden wird, ohne daß diese ihre Sinterfähigkeit einbüßen. Wie an einer Reihe von Beispielen gezeigt wurde, ist das vorgestellte Verfahren nicht nur auf die Herstellung einiger weniger Produkte beschränkt, sondern auf den gesamten Bereich der binären und multinären Oxidkeramik anzuwenden. Überdies zeichnet sich das Verfahren durch einfache, schadstofffreie Verfahrensschritte aus.