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    ZUSAMMENSETZUNGEN ZUR HERSTELLUNG VON AMINOPLASTERZEUGNISSEN
    7.
    发明授权
    ZUSAMMENSETZUNGEN ZUR HERSTELLUNG VON AMINOPLASTERZEUGNISSEN 有权
    组合物用于制备氨基树脂

    公开(公告)号：EP1519972B1

    公开(公告)日：2006-10-25

    申请号：EP03759943.8

    申请日：2003-06-12

    申请人： AMI - Agrolinz Melamine International GmbH

    发明人： RÄTZSCH, Manfred ,  BUCKA, Hartmut ,  BURGER, Martin

    IPC分类号： C08G12/00 ,  C08G12/30 ,  C08G12/32 ,  C08G12/42 ,  C08L61/26 ,  C08L61/28 ,  D01F6/00

    CPC分类号： D01F6/76 ,  C08G12/32 ,  C08L61/28 ,  C08L2666/02

    摘要： Compositions for producing aminoplast products by means of melt processing consist of: A) 95 to 99.9 % by mass of solvent-free meltable polycondensates of melamine resins having molar masses ranging from 300 to 300000; A) 0.1 to 5 % by mass of weak acids serving as thermoinducible curing agents consisting of: acidifiers of the blocked sulfonic acid type; aliphatic C4-C18 carboxylic acids; aromatic C7-C18 carboxylic acids; alkali salts or ammonium salts of phosphoric acid; C1-C12 alkyl esters or C2-C8 hydroxyalkyl esters of C7-C14 aromatic carboxylic acids or of inorganic acids; salts of melamine or of guanamines having C1-C18 aliphatic carboxylic acids; anhydrides, half-esters or half-amides of C4-C20 dicarboxylic acids; half-esters or half-amines of copolymers consisting of ethylenically unsaturated C4-C20 dicarboxylic acid anhydrides and ethylenically unsaturated monomers of the C2-C20 olefin type and/or C8-C20 vinyl aromatic compounds; and/or salts of C1-C12 alkyl amines or alkanolamines having C1-C18 aliphatic, C7-C14 aromatic or alkylaromatic carboxylic acids and inorganic acids of the hydrochloric acid, sulfuric acid or phosphoric acid type, and; B) optionally up to 400 % by mass of fillers and or reinforcing fibers, up to 30 % by mass of additional reactive polymers of the ethylene copolymer, maleic anhydride copolymer, modified maleic anhydride copolymer, poly-(meth)acrylate, polyamide, polyester and/or polyurethane type, and up to 4 % by mass, each time with regard to the polycondensates of melamine resins, of stabilizers, UV absorbers and/or auxiliary agents. These inventive compositions can be processed by means of melt processing into products such as panels, coated supporting materials, profiled pieces, pipes, injection-molded articles, fibrous products and laminates.

    Amino resin composite particle and method of producing same
    9.
    发明公开
    Amino resin composite particle and method of producing same 有权
    氨基树脂复合粒子，以及它们的制备方法

    公开(公告)号：EP1288248A2

    公开(公告)日：2003-03-05

    申请号：EP02019306.6

    申请日：2002-08-28

    申请人： Nippon Shokubai Co., Ltd.

    发明人： Yamamoto, Yasuhiro ,  Shingai, Yasuhiro ,  Oishi, Hideki

    IPC分类号： C08J3/21 ,  C08J3/12 ,  C08L61/26

    CPC分类号： C08J3/21 ,  C08G8/30 ,  C08J2361/20 ,  C08L61/26 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2998

    摘要： The present invention provides an amino resin composite particle in which an inorganic compound is fixed (firmly adhered) on a surface of an amino resin particle, for example, an amino resin composite particle, in which a child particle made of the inorganic compound is fixed on a mother particle made of the amino resin particle, and a method of easily and inexpensively producing the amino resin composite particle. After an amino compound such as benzoguanamine is reacted with formaldehyde, so as to prepare a reaction mixture containing an amino resin precursor to be the mother particle, an emulsion of the reaction mixture and an aqueous solution of an emulsifier, and an aqueous dispersion of the inorganic compound, such as silica powder, to be the child particle are mixed with a shear force application, so as to emulsify them to have an emulsion thereof. The emulsion is hardened by adding a catalyst. The thus obtained amino resin composite particle has a firm-adhering ratio of the inorganic compound of 10% or more.