Epoxidation catalyst, method for preparing catalyst, and method for producing olefin oxide, 1,2-diol, 1,2-diolether, 1,2-carbonate or alkanolamine
    92.
    发明专利
    Epoxidation catalyst, method for preparing catalyst, and method for producing olefin oxide, 1,2-diol, 1,2-diolether, 1,2-carbonate or alkanolamine 有权
    环氧化催化剂,制备催化剂的方法和生产氧化烯,1,2-二醇,1,2-二醇,1,2-碳酸酯或烷醇胺的方法

    公开(公告)号:JP2014159028A

    公开(公告)日:2014-09-04

    申请号:JP2014048422

    申请日:2014-03-12

    Inventor: MATUSZ MAREK

    Abstract: PROBLEM TO BE SOLVED: To provide a catalyst for epoxidizing olefins with an improved selectivity of olefin oxides, a method for preparing catalysts, and a method for preparing olefin oxides.SOLUTION: There is provided a catalyst for epoxidizing olefins comprising a carrier as well as silver, a rhenium promoter, a first co-promoter, and a second co-promoter that are deposited on the carrier, wherein a mole ratio of the first co-promoter to the second co-promoter is more than 1. The first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; and the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof. A method for preparing the catalyst, and a method for preparing olefin oxides by reacting a feedstock including olefin and oxygen in the presence of catalysts are also provided. The present invention includes converting the olefin oxides into a 1,2-diol, a 1,2-diolether, a 1,2-carbonate, or an alkanolamine.

    Abstract translation: 要解决的问题:提供烯烃氧化物选择性提高的烯烃环氧化催化剂,制备催化剂的方法和制备烯烃氧化物的方法。溶剂:提供了一种用于环氧化烯烃的催化剂,其包括载体以及 银,铼助催化剂,第一共助催化剂和第二共助催化剂,其中第一共助催化剂与第二助催化剂的摩尔比大于1.第一共助催化剂和第二共助催化剂, 助催化剂选自硫,磷,硼及其混合物; 第二共助催化剂选自钨,钼,铬及其混合物。 还提供了一种制备催化剂的方法,以及在催化剂存在下使包括烯烃和氧在内的原料反应制备烯烃氧化物的方法。 本发明包括将烯烃氧化物转化为1,2-二醇,1,2-二油醚,1,2-碳酸酯或链烷醇胺。

    Method for producing conjugated diene compound
    94.
    发明专利
    Method for producing conjugated diene compound 有权
    生产连结二烯化合物的方法

    公开(公告)号:JP2014156408A

    公开(公告)日:2014-08-28

    申请号:JP2013026917

    申请日:2013-02-14

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a corresponding conjugated diene compound from a α,β-unsaturated aldehyde using a selected metal catalyst with high conversion and high selectivity.SOLUTION: The method for producing a conjugated diene compound corresponding to a α,β-unsaturated aldehyde comprises supplying a mixed gas including an alcohol of at least an equal scale of mole of the α,β-unsaturated aldehyde in the coexistence of a catalyst carrying group (I) of at least one kind of metal selected from among Cr, Mn and Fe and/or a metal oxide thereof, and optionally, group (II) of at least one kind of metal selected from Co and Ni and/or a metal oxide thereof on a solid oxide carrier and performing hydrogen transfer reaction and dehydration reaction.

    Abstract translation: 要解决的问题:提供一种使用选择性的高转化率和高选择性的金属催化剂从α,β-不饱和醛制备相应的共轭二烯化合物的方法。溶液:对应于 α和β-不饱和醛包括在至少一种金属的催化剂负载基团(I)的共存下,供应包含至少相等摩尔量的α,β-不饱和醛的醇的混合气体 选自Cr,Mn和Fe和/或其金属氧化物,以及任选的选自Co和Ni中的至少一种金属和/或其金属氧化物的基团(II)在固体氧化物载体上并进行氢 转移反应和脱水反应。

Patent Agency Ranking