公开(公告)号：JP4994398B2

公开(公告)日：2012-08-08

申请号：JP2009002055

申请日：2009-01-07

申请人： 独立行政法人科学技術振興機構

发明人： 啓史 中川 ,  進 北川 ,  大輔 田中

IPC分类号： B01J20/22 ,  B01D53/04 ,  B01D53/46 ,  B01D53/48 ,  B01D53/50 ,  B01D53/52 ,  B01D53/54 ,  B01D53/62 ,  B01D53/72 ,  B01D53/81 ,  C07C63/24 ,  C07C63/38 ,  C07C63/72 ,  C07C65/21 ,  C07C65/34 ,  C07C205/54 ,  C07C229/62 ,  C07F3/06 ,  C07F3/08

CPC分类号： Y02A50/2341

摘要： PROBLEM TO BE SOLVED: To provide such a molding that its structure is changed according to the kind of gas in contact therewith to adsorb/separate the gas. SOLUTION: The molding for gas separation contains an organometallic complex which has a flexible, crystalline and mutually-fittable structure, and can have a first structure in the no presence of the gas having affinity and a second structure having high affinity to the gas in the presence of the gas having affinity, and is composed of a metal ion, an aromatic carboxylic acid polyvalent ligand and an aromatic bivalent ligand containing a nitrogen atom or a phosphorus atom. COPYRIGHT: (C)2010,JPO&INPIT